摘要
A new complex with mixed￡-quadriliga ndCe ￡¨CH ￡2 ￡1/2C(CH￡3￡(c)￡-COO￡(c)￡2￡¨NO￡3￡(c)￡¨phen￡(c)2 has been synthesized in aqueous solution of slight acidity a nd characterized by elementary analysis￡?IR and TGA￡(r)The crystal structu re determination shows that the comple x belongs to triclinic￡?space groupP￡±￡?a￡1/2￡1￡(r)￡?￡±￡′|!￡?b￡1/2￡±￡°￡(r)￡°￡′￡*|!￡?c￡1/2￡±￡±￡(r)￡?￡2￡±|!￡?Z ￡1/2￡2￡?|á￡1/2￡±￡°￡°￡(r)￡?￡?￡¨￡3￡(c)??￡?|?￡1/2106￡(r)￡2￡1￡¨￡3￡(c)??￡?|?￡1/2￡1￡*￡(r)￡1￡3￡¨￡2￡(c)??￡?V￡1/2￡±￡°￡μ￡′￡¨￡μ￡(c)?3,Dc￡1/2￡±￡(r)741g·cm-￡3￡?F￡¨￡°￡°￡°￡(c)￡1/2￡μ￡′￡?￡(r)￡°￡°￡?|ì￡¨Mo K|á￡(c)￡1/2￡2￡2￡(r)06cm-￡± ￡(r)And the crystal is consisted of a bin uclear molecule￡(r)The coordina-tion of Ce 3? is nine￡(r)
A new complex with mixed￡-quadriliga ndCe ￡¨CH ￡2 ￡1/2C(CH￡3￡(c)￡-COO￡(c)￡2￡¨NO￡3￡(c)￡¨phen￡(c)2 has been synthesized in aqueous solution of slight acidity a nd characterized by elementary analysis￡?IR and TGA￡(r)The crystal structu re determination shows that the comple x belongs to triclinic￡?space groupP￡±￡?a￡1/2￡1￡(r)￡?￡±￡′|!￡?b￡1/2￡±￡°￡(r)￡°￡′￡*|!￡?c￡1/2￡±￡±￡(r)￡?￡2￡±|!￡?Z ￡1/2￡2￡?|á￡1/2￡±￡°￡°￡(r)￡?￡?￡¨￡3￡(c)??￡?|?￡1/2106￡(r)￡2￡1￡¨￡3￡(c)??￡?|?￡1/2￡1￡*￡(r)￡1￡3￡¨￡2￡(c)??￡?V￡1/2￡±￡°￡μ￡′￡¨￡μ￡(c)?3,Dc￡1/2￡±￡(r)741g·cm-￡3￡?F￡¨￡°￡°￡°￡(c)￡1/2￡μ￡′￡?￡(r)￡°￡°￡?|ì￡¨Mo K|á￡(c)￡1/2￡2￡2￡(r)06cm-￡± ￡(r)And the crystal is consisted of a bin uclear molecule￡(r)The coordina-tion of Ce 3? is nine￡(r)
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2002年第6期639-642,共4页
Chinese Journal of Inorganic Chemistry
基金
上海市青年基金资助项目(No.2000QN34)。
