摘要
在旋转蒸发仪中,研究了二氯四氨合钯(Ⅱ)的制备方法,并探索了不同反应条件下二氯四氨合钯(Ⅱ)产品的钯含量。结果表明,四氯合钯酸在85℃下与氨水反应80 min为相对最优制备条件;在70℃下重结晶25 min为二氯四氨合钯(Ⅱ)最佳后续处理条件。
The method of preparing tetraamminepalladium（Ⅱ） chloride was studied in a rotary evaporator. The different conditions were explored to correlate with the palladium content of final products. Experimental results show that the optimum setting of preparing tetrachloropalladate acid is reaction with ammonia at 85 for 80 min; the optimum setting for subsequent p℃ rocessing is recrystallization at 70 for ℃25 min.
出处
《贵金属》
CAS
CSCD
北大核心
2014年第A01期122-125,共4页
Precious Metals
关键词
无机化学
二氯四氨合钯(Ⅱ)
制备
钯含量
重结晶
inorganic chemistry
tetraamminepalladium（Ⅱ） chloride
preparing
palladium content
recrystallization
