摘要
综述了可用于TS-1分子筛催化剂修饰改性的方法,主要包含:硅烷化改性、酸改性、碱改性、盐改性、金属及其化合物改性.其中硅烷化改性减少了外表面钛含量,从而减少了副反应的发生;酸改性、碱改性、盐改性不同程度地提高了骨架钛的含量.通过对比分析不同修饰改性方法的优缺点,有针对性地根据自己的需求,采取恰当的改性方法进一步改进TS-1分子筛催化剂的催化活性,从而更广泛地应用于工业化生产.
In this paper the data can be used in the modified molecular sieve catalyst modification method of TS-1. It mainly includes silicon alkylation modification, acid modification, alkali modification, salt modification, metal or their compounds modification. We found that the silicon alkylation modification reduced the external surface of titanium content, reducing side reaction; the acid modification, alkali modification, salt modification increase the content of framework titanium with different degree. By analyzing the advantages and disadvantages of the different modification methods, we can take appropriate modification to further improve the TS-1 zeolite catalytic performance according to their needs, and to enhance its activity, thus it will be more widely used in industrial production.
出处
《河南大学学报（自然科学版）》
CAS
北大核心
2014年第6期649-653,共5页
Journal of Henan University:Natural Science
基金
科技部中小企业创业基金(12C26214204453)
湖北省教育厅产学研重大项目(CXY2009A010)
湖北省自然基金重点项目(2010CDA020)
关键词
钛硅分子筛
TS-1
改性
催化剂
titanium silicon molecular sieve
TS-1
modified
catalyst
