摘要
针对当前评价氯氧镁水泥(MOC)抗水性方法的实验时间长(28d)和实验设备昂贵等不利于产品质量检测的因素,提出了以Arrhenius关系为理论基础的MOC抗水性快速评价方法。首先讨论了MOC在水中的侵蚀厚度与浸水时间的关系、建立了关联高温和低温侵蚀速率的Arrhenius方程,明确了强度保留率与相对侵蚀厚度的关系,并根据强度退化速率将MOC在水中的强度退化过程划分为4个阶段(稳定期、快速下降期、缓慢下降期和残余强度期)。在此基础上提出了基于测量高温侵蚀厚度的MOC抗水性快速评价方法,同时结合实例分析了评价结果的准确度和误差来源。结果表明:新方法定性评价MOC抗水性的实验时间仅为10h,半定量和定量评价的实验时间可缩短到24h;预测MOC试件所处的强度退化阶段与实验结果完全相符,预测试件强度保留率的最大相对误差为-17.37%。
The paper presents a water resistance rapid assessment system （WRRAS） for magnesium oxychloride cement （MOC） based on the Arrhenius equation in order to improve the time-consuming operation （28 d） and the existing equipment used. The relationships between the erosion thickness and leaching time and between the strength retention ratio and relative erosion thickness for MOC in water were discussed. The four strength degradation stages （i. e. stabilization stage, rapid decline stage, slow decline stage and residual strength stage） were analyzed. The process of WRRAS was introduced according to high-tem- perature erosion thickness in water. The accuracy and error sources of the evaluation results were analyzed. The results show that the experimental time of qualitative evaluation for water resistance is only 10 h, and the semi-quantitative and quantitative evaluation time is 24 h. The predicted strength degradation stage of MOC in water consists with the experimental process, and the maximum relative error of predicted strength retention ratio is --17.37 %.
出处
《硅酸盐学报》
EI
CAS
CSCD
北大核心
2014年第8期1047-1054,共8页
Journal of The Chinese Ceramic Society
基金
国家自然科学基金面上项目(21276264)
青海省科技厅高新技术研究与发展计划(2013-G-208)
中国科学院青海盐湖研究所青年引导基金资助
关键词
氯氧镁水泥
抗水性
评价方法
强度保留率
侵蚀速率
侵蚀厚度
强度退化阶段
软化系数
magnesium oxychloride cement
water resistance
evaluation method
, strength retention ratiol erosion rate
ero-sion thickness
strength degradation stage
softening coefficient
