摘要
通过无晶种碳分法制备了易溶氢氧化铝。研究了反应温度、通气速度、二氧化碳体积分数、铝酸钠溶液苛性比(氧化钠与氧化铝物质的量比)等条件对氢氧化铝酸溶率的影响。适宜工艺条件:反应温度为65-75℃、通气速度为400L/h、二氧化碳体积分数为30%-38%、铝酸钠溶液苛性比为1.48。在此条件下制得氢氧化铝酸溶率大于95%。X射线衍射(XRD)和扫描电镜(SEM)表征表明,物相组成是影响氢氧化铝产品酸溶性的主要原因。
The easily soluble aluminum hydroxide was prepared by carbonation decomposition.The effects of decomposition temperature, gas passing velocity, volume fraction of CO2, and caustic molar ratio (amount-of-substance ratio of sodium oxide to alumina) of sodium aluminate solution etc.on the aluminum hydroxide's acid solubility were investigated.Results showed that the optimum conditions : the carbonation decomposition temperature was 65-75 ~C, gas passing velocity was 400 L/h, the volume fraction of CO2 was 30%~38% ,and the caustic molar ratio of sodium aluminate solution was 1.48.The acid soluble rate of the product was more than 95% under those conditions.The product was characterized by XRD and SEM, and the re- sults showed the acid solubility mainly depended on the phase composition of aluminum hydroxide.
出处
《无机盐工业》
CAS
北大核心
2015年第6期47-49,共3页
Inorganic Chemicals Industry
关键词
易溶氢氧化铝
碳分
二氧化碳
酸溶率
晶体结构
easing soluble aluminum hydroxide
carbonation decomposition
C02
acid solubility
crystal structure