摘要
以呋喃甲醛、溴苯和2-甲基-8-羟基喹啉为原料,设计合成了配体2-(5'-苯基呋喃乙烯基)-8-羟基喹啉(HL,C_(21)H_(15)NO_2),通过元素分析、红外光谱、核磁共振氢谱和X-射线单晶衍射确定了该物质的结构.采用溶液法合成了2个配合物CuL_2和ZnL_2,用元素分析、红外光谱、热重分析和摩尔电导等方法对配合物的结构进行了表征.此外,在室温条件下测定了配体及配合物的固体荧光光谱.
A new 8-hydroxyquinoline derivative , 2-( ( 5′-phenylfuran ) vinyl )-8-hydroxy-quinoline ( HL, C21 H15 NO2 ) was synthesized from 2-methyl-8-hydroxyquinoline , furaldehyde and bromobenzene.The structure of the target product was confirmed by elemental analysis , infra-red spectrum , 1 H NMR spectroscopy and X-ray crystal structure.Two complexes of copper and zinc , CuL2 and ZnL2 were synthesized and characterized by elemental analysis , infra-red spectrum , molar conductance , thermogravimetric analysis.In addition , lumines-cent properties of the ligand and complexes were studied at room temperature.
出处
《浙江师范大学学报（自然科学版）》
CAS
2015年第4期410-414,共5页
Journal of Zhejiang Normal University:Natural Sciences
基金
浙江省自然科学基金资助项目(LY12B01003)
