期刊文献+

硅氧烷在环境中的迁移转化及其对生物气应用的影响 被引量:2

Distribution,migration and transformation of siloxanes in environment and its impact on biogas application
原文传递
导出
摘要 近年来大量使用含有机硅氧烷材料造成硅氧烷作为污染物进入环境,数量逐年增加.在垃圾填埋场和污水处理厂消化产生的生物气(沼气)中出现的硅氧烷会在燃烧过程中结垢,十分不利于生物气的利用,必须清除.本文综述了硅氧烷的理化性质、在环境中的迁移转化规律与生物降解性能、在生物气中的浓度分布以及去除技术,并对生物气应用中的硅氧烷的控制对策研究作出展望.作者强调,需进一步深入研究硅氧烷的生物降解的机理. Siloxane has become an environmental concern as poly-dimethylsiloxanes are extensively applied. Siloxanes in biogas generated from landfill and anaerobic digestion at wastewater treatment plants must be removed before the biogas is used for electricity generation in case of production of silicon precipitates inside an engine. This paper reviews the updated research results on siloxanes including physical-chemical properties,contaminant sources,migration and transformation in environment,biodegradability,concentration profile in biogas,and current technologies for siloxane removal. The topics of future study are discussed,focusing on mechanism of biodegradation and microbiology.
出处 《环境科学学报》 CAS CSCD 北大核心 2015年第10期3050-3056,共7页 Acta Scientiae Circumstantiae
基金 “十二五”国家科技支撑计划(No.2014BAC28B00)~~
关键词 硅氧烷 生物气 迁移转化 浓度分布 去除技术 siloxane biogas migration and transformation concentration profile removal technology
  • 相关文献

参考文献44

  • 1Accettola F, Gaehitz G M, Schoeftner R. 2008. Siloxane removal from biogas by biofiltration: biodegradation studies [ J ]. Clean Technologies and Environmental Policy, 10(2) : 211-218.
  • 2Ajhar M, Travesset M, Ytice S, et al. 2010a. Siloxane removal from landfill and digester gas-A technology overview [ J ]. Bioresource Technology, 101 (9) : 2913-2923.
  • 3Ajhar M, Wens B, Stollenwerk K H, et cd. 2010b. Suitability of Tedlar~ gas sampling bags for siloxane quantification in landfill gas [J]. Talanta, 82(I) : 92-98.
  • 4Ajhar M, Bannwarth S, Stollenwerk K H, et al. 2012. Siloxane removal using silicone-rubber membranes [ J I. Separation and Purification Technology, 89 : 234-244.
  • 5Arnold M, Kajolinna T. 2010. Development of on-line measurement techniques for siloxanes and other trace compounds in biogas [ J ]. Waste Management, 30(6) : 1011-1017.
  • 6Basu S, Khan A L, Cano-Odena A, et al. 2010. Membrane-based technologies for biogas separations [ J ]. Chemical Society Reviews, 39(2) : 750-768.
  • 7Bletsou A A, Asimakopoulos A G, Stasinakis A S, et al. 2013. Mass loading and fate of linear and cyclic siloxanes in a wastewater treatment plant in Greece [ J 1. Environmental Science & Technology, 47(4) : 1824-1832.
  • 8Brooke D N, Crookes M J, Gray D, et al. 2009a. Environmental Risk Assessment Report: Decamethyleyclopentasiloxane [ M ]. Bristol: Environment Agency of England and Wales Brooke D N, Crookes M J, Gray D, et al. 2009b.
  • 9Environmental Risk Assessment Report: Octamethylcyclotetrasiloxane [ M ]. Bristol: Environment Agency of England and Wales Brooke D N, Crookes M J, Gray D, et al. 2009c.
  • 10Environmental Risk Assessment Report : Dodecamethylcyclohexasiloxane [ M ]. Bristol: Environment Agency of England and Wales Chainet F, Lienemann C P, Courtiade M, et al. 2011.

二级参考文献67

  • 1ED WHELESS, JEFFREY PIERCE. Siloxanes in landfill and digester gas update[A]. Swana 27th LFG conference[C].San Antonio: The organizer of SWANA 27th LFG Conference, 2004.22-25.
  • 2MARTIN SCHWEIGKOFLER, REINHARD NIESSNER. Determination of siloxanes and VOC in landfill gas and sewage gas by canister sampling and GC-MS/AES analysis[J].Environ.Sci.Technol, 1999,33 : 3680-3685.
  • 3CARSTEN LASSEN, CHARLOTTE LIBAK HANSEN, SONJA HAGEN MIKKELSEN, et al. Siloxanes - consumption, toxicity and alternatives[A]. Danish Ministry of the Enviromnent [C].Copenhagen: Danish Environmental Protection Agency, 2005.1-5.
  • 4RAF DEWIL, LISE APPELS, JAN BAEYENS. Energy use of biogas hampered by the presence of siloxanes[J]. Energy Conversion and Management,2006,47 : 1711-1172.
  • 5D GRAIVER, K W FARMINER, R NARAYAN. A review of the fate and effects of silicones in the environment[J].Journal of Polymers and the Environment, 2003,11(4): 129-136.
  • 6MARTIN SCHWEIGKOFLER, REINHARD NIESSNER. Removal of siloxanes in bio gases [J].Journal of Hazardous Materials,2001,83 : 183-196.
  • 7EDWARD, A MCBEAN. Siloxanes in biogases from landfills and wastewater digesters [J].Can.J.Civ.Eng., 2008,35 : 431-435.
  • 8RAF DEWIL, LISE APPELS, JAN BAEYENS, et al. The analysis of volatile siloxanes in waste activated sludge[J].Talanta,2007,74:14-19.
  • 9Ohannessian A, Desjardin V, Chatain V, et al. Volatile organic silicon compounds: the most undesirable contaminants in biogases [ J ]. Water Science and Technology, 2008,58 : 1775 - 1781.
  • 10Ajhar M, Travesset M, Yuce S, et al. Siloxane removal from landfill and digester gas - A technology overview [ J ]. Bioresource Technology,2010,101:2913 - 2923.

共引文献6

同被引文献15

引证文献2

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部