期刊文献+

不同退火条件下Al-Eu合金粉末的组织结构与氧化性能 被引量:1

Microstructure and oxidation behavior of Al-Eu alloy powders under different annealing conditions
在线阅读 下载PDF
导出
摘要 通过紧耦合气雾化法制备得到了一系列Al-Eu二元合金粉末,并通过XRD、SEM/EDS以及TG-DTA等手段对其进行了测试表征,探索了将稀土Eu应用于金属燃料的可行性。结果表明,Al-3Eu合金粉末在1300℃时氧化增重达到了61.1%,氧化放热焓高达8108.2μV·s·mg^(-1)。Al-3Eu合金粉末在400℃下退火0.5h后,氧化放热焓达到了9243.4μV·s·mg^(-1),退火2h后,氧化增重达到了78.8%,两者均高于未经热处理的Al-3Eu合金粉末。 A series of Al - Eu alloy powders were designed and prepared successfully by the close - coupled gas atomization ( CCGA). These powders were characterized through X - ray powder diffraction, SEM/EDS, and TG - DTA to explore the feasibility of application of Eu in metal fuel. The results show that, the oxidation weight increase ratio of the Al - 3Eu alloy powder is 61.1% and the oxidation exothermic enthalpy of the Al - 3 Eu alloy powder is as high as 8108.2μV·s·mg^-1. The oxidation exothermic enthalpy of the Al - 3Eu alloy powder under 0. 5h - annealing treatment and 400℃ reached 9243.4μV·s·mg^-1, and the oxidation weight increase ratio of the Al - 3Eu alloy powder under 2h - annealing treatment reached 78. 8%.
作者 付豪 邹辉
出处 《轻金属》 CSCD 北大核心 2016年第6期53-58,共6页 Light Metals
基金 国家自然科学联合基金项目:新型铝基稀土合金的结构与能量释放的构效关系研究 编号:U1530127
关键词 Al-Eu 合金 紧耦合气雾化法 氧化性能 金属燃料 Al - Eu alloy CCGA oxidation behavior metal fuels
  • 相关文献

参考文献14

  • 1Hu D, Sun Z. Study of the fast reaction characteristics of aluminized PETN explosive powders[ J]. Combustion and Flame, 1996, 105 (3) : 428 - 430.
  • 2Price E W, Sigman R K. Combustion of Aluminized Solid Propel- lants, Solid Propellant Chemistry, Combustion and Motor Interior ballistics, Chapter 2. 18 [ M]. Progress in Astronautics and Aero- nautics, Vol. 185, 1999.
  • 3Bashung B, Grune D, Licht H H, Samirant M. Combustion phenom- ena of a solid propellant based on aluminum powder [ C ]. 5th Inter- national Symposium on Special Topics in Chemical Propulsion (5 - ISICP), Stresa, Italy, 2000.
  • 4Ermakov V A, Razdobreev A A, Skorik A I, Pozdeev V , Smolya- kov S S. Temperature of aluminum particles at the time of ignition and combustion [ J ]. Combustion Explosion and Shock Waves. 1982, 18(2) : 256 -257.
  • 5Dreizin E L. Experimental study of stages in aluminum particle com- bustion in air [J]. Combust and Flame, 1996, 105 (4) : 541 - 556.
  • 6Llyin A, Gromov A, An V, Fanbert F, Lzarra C D, Espagnacq A, Brunet A. Characterization of aluminum powders I. Parameters of re- activity of aluminum powders [ J ]. Propellants, Explosives, Pyro- technics, 2002, 27(6): 361 -364.
  • 7Hasani S, Panjepour M, Shamanian M. The oxidation mechanism of pure aluminum powder particles [J]. Oxidation of Metals, 2012, 78 (3 -4) : 179 -195.
  • 8Kulp B A. Military uses of misch metal [ C]. 10th Rare Earth Res. Conference, Arizona, America, 1973. 56 - 62.
  • 9Hillstrom W W. Thresholds for the initiation of pyrophoric sparking [ C]. 4th Int. Pyrotechnic Seminar, Colorado, America, 19/4. 21.
  • 10刘成文,罗来涛,赵旭.Ce_(1-x)Eu_xO_y固溶体的制备及甲烷燃烧催化性能研究[J].中国稀土学报,2006,24(4):429-433. 被引量:6

二级参考文献22

  • 1冯长根,张江山,王亚军.铈锆氧化物纳米粉的合成及催化性能研究[J].中国稀土学报,2004,22(4):551-556. 被引量:15
  • 2楼翰一,唐幼军,孙晓峰,管恒荣.K17F高温合金溅射微晶层的抗高温氧化行为[J].金属学报,1994,30(3). 被引量:13
  • 3叶长江,李铁藩,周龙江.晶粒尺寸对含Zr的Ni_3Al合金氧化行为的影响[J].金属学报,1995,31(3). 被引量:8
  • 4Joo H, David L, Trimm. Catalytic combustion of methane [J ].Fuel Process Technol., 1995, 42: 339.
  • 5Marcusf F M, Zwinkels, Seven G Jaras, et al. Catalytic material for high-temperature combustion [J]. Catal. Rev. Sci. Eng.,1993, 35(3): 319.
  • 6Eleseo Ranzi, Angelo Sogaro, Paolo Gaffari, et al. A wide range modeling study of methane oxidation [ J ]. Combust Sci.Tech. , 1994, 96(4 - 6) : 279.
  • 7Palmqvist A E C, Johansson E M, Jaras S G, et al. Total oxidation of methane oven:loped nanophase cerium oxides [J]. Catalysis Letters, 1998, 56(1) : 69.
  • 8Luo M F, Chen J, Chen L S. Structure and redox properties of CexTi1-xO2 solid solution [J]. Chem. Mater., 2001, 13: 197.
  • 9Rodriguez J A, Hanson J C, Kim J Y. Properties of CeO2 and Ce1-xZrxO2 nanoparticles: X-ray absorption near-edge spectroscopy, density functional, and time-resolved X-ray diffraction studies [J]. J.Phys. Chem. B., 2003, 107: 3535.
  • 10Shuk P, Greenblatt M, Crft M J. Hydrothrmal synthesis and properties of Ce1-x Eu, O2-δ solid solutions [J ]. Alloys Compd.,2000, 465: 303.

共引文献57

同被引文献10

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部