期刊文献+

环境空气中短链氯化石蜡研究进展 被引量:2

Research Progress of Short Chain Chlorinated Paraffins in Environmental Air
在线阅读 下载PDF
导出
摘要 短链氯化石蜡(SCCPs)是碳链长度为10至13个碳原子的正构烷烃氯代衍生物。SCCPs具有持久性、生物累积性、长距离迁移能力、以及毒性作用。SCCPs已被《关于持久性有机污染物的斯德哥尔摩公约》增列为持久性有机污染物审查范围内,引起了全球关注。SCCPs在环境各介质及生物体内均有检出,近年来,在室内空气和灰尘中也检出了大量SCCPs,其已成为人体暴露的一个重要来源。本文就大气环境及室内空气与灰尘中氯化石蜡(CPs)的采样与分析方法、污染水平与来源,及人体暴露概况进行了综合阐释,以期为我国大气和室内环境中CPs的研究工作提供参考。 Short chain chlorinated paraffins(SCCPs), which are chlorinated derivatives of n-alkanes, are a complex mixtures that include 10 and 13 carbon atoms. SCCPs attract global attentions due to their persistence, bioaccumulation, long-distance transport ability, and toxicity. They have been listed as candidate persistent organic pollutants in the Stockholm Convention. SCCPs have been ubiquitously detected in various environmental matrices. In recent years, indoor air inhalation and dust ingestion have been demonstrated to act as an important source of human exposure to SCCPs. In this study, the current available methodologies on sampling and analytical techniques, contamination levels, possible sources, assessment for human exposure to chlorinated paraffins(CPs) in atmosphere and indoor environment are critically reviewed. It is hoped that the work can provide references for the further researches of CPs in environmental air in China.
出处 《生态毒理学报》 CAS CSCD 北大核心 2016年第2期80-88,共9页 Asian Journal of Ecotoxicology
基金 国家自然科学基金(21307128,21337002,21577009)
关键词 短链氯化石蜡 空气 灰尘 采样与分析方法 污染现状 人体暴露 short chain chlorinated paraffins air dust sampling and analytical techniques contamination levels human exposure
  • 相关文献

参考文献56

  • 1De Boer J,El-Sayed A T,Fiedler H,et al.Chlorinated paraffins[M]//The Handbook of Environmental Chemistry.Berlin:Springer,2010.
  • 2Bayen S,Obbard J P,Thomas G O.Chlorinated paraffins.A review of analysis and environmental occurrence[J].Environment International,2006,32(7):915-929.
  • 3王亚韡,王宝盛,傅建捷,阮挺,曲广波,汪畅,曾力希,刘倩,袁博,江桂斌.新型有机污染物研究进展[J].化学通报,2013,76(1):3-14. 被引量:25
  • 4United Nations Environmental Programme(UNEP).Shortchained Chlorinated Paraffins:Revised Draft Risk Profile UNEP/POP/PORC.8/6.[R].Geneva:UNEP,2012.
  • 5Muir D,Bennie D,Teixeira C,et al.Short Chain Chlorinated Paraffins:Are They Persistent and Bioaccumulative?[M]//Persistent,Bioaccumulative,and Toxic Chemicals II.Washington,DC:American Chemical Society,2000.
  • 6Stern G A,Tomy G T.An overview of the environmental levels and distribution of polychlorinated paraffins[J].Organohalogen Compounds,2000,47:135-138.
  • 7Sverko E,Tomy G T,Marvin C H,et al.Improving the quality of environmental measurements on short chain chlorinated paraffins to support global regulatory efforts[J].Environmental Science&Technology,2012,46:4697-4698.
  • 8徐淳,徐建华,张剑波.中国短链氯化石蜡排放清单和预测[J].北京大学学报(自然科学版),2014,50(2):369-378. 被引量:14
  • 9Breivik K,Sweetman A,Pacyna J M,et al.Towards a global historical emission inventory for selected PCB congeners-A mass balance approach.1.Global production and consumption[J].Science of the Total Environment,2002,290:181-198.
  • 10Coelhan M,Hilger B.Chlorinated paraffins in indoor dust samples:A review[J].Current Organic Chemistry,2014,18:2209-2217.

二级参考文献122

  • 1王璞,王亚韡,李英明,张庆华,江桂斌.青海湖湟鱼(Gymnocypris przewalskii)中PCBs和PCDD/Fs的分析[J].环境化学,2006,25(6):669-673. 被引量:8
  • 2王亚韡,张庆华,江桂斌,贺卿.大体积进样技术在气相色谱-质谱法测定二噁英类化合物中的应用[J].色谱,2007,25(1):21-24. 被引量:6
  • 3Zencak Z, Oehme M. Recent developments in the analysis of chlorinated paraffins[ J ]. Trends Anal Chem, 2006, 25 (4) :310-317.
  • 4Reth M, Zencak Z, Oehme M. First study of congener group patterns and concentrations of short-and medium-chain chlorinated paraffins in fish from the North and Baltic Sea[ J]. Chemosphere, 2005, 58:847-854.
  • 5Eljarrat E, Bareelo D. Quantitative analysis of polychlorinated n-alkanes in environmental samples[ J ]. Trends Anal Chem, 2006, 25 (4) : 421-434.
  • 6Muir D, Stem G A, Tomy G T. The Handbook of Environmental Chemistry[ M]. Berlin: Springer-Verlag, 2000, 3:203-236.
  • 7Koh I 0 Z, Rotard W, Thiemann W H P. Analysis of chlorinated paraffins in cutting fluids and sealing materials by carbon skeleton reaction gas chromatography[ J]. Chemosphere, 2002, 47:219-227.
  • 8Shojania S. The enumeration of isomeric structures for polychlorinated n-alkanes[ J]. Chemosphere, 1999, 38 (9) :2125-2141.
  • 9Reth M, Zdenek Z, Oehme M. New quantification procedure for the analysis of chlorinated paraffins using electron capture negative ionization mass spectrometry[ J ]. J Chromatogr A, 2005, 1081:225-231.
  • 10Koryt- P, Parera J, Leonards P E G, et al. Characterization of polychlorinated n-alkanes using comprehensive two-dimensional gas chromatography-electron-capture negative ionisation time-of-flight mass spectrometry[ J 1. J Chromatogr A, 2005, 1086:7 l-g2.

共引文献69

同被引文献8

引证文献2

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部