摘要
共轭微孔聚合物是一类具有扩展共轭体系的骨架材料,具有比表面积大、稳定性高、微孔大小和体积可精确调控等特点。由于其独特的结构特点,共轭微孔聚合物在各方面展现出巨大的应用潜力,本文综述了共轭微孔聚合物及复合材料的制备方法,以及共轭微孔聚合物在气体吸附和储存、污染物的富集、非均相催化、光发射、化学传感器、光捕集、电能存储等方面的应用。
Conjugated microporous polymers( CMPs) are a class of skeleton materials with extension of conjugated system and possess large surface area,excellent stability,accurately tunable micropore size and volume.CMPs have shown great application potential in many fields because of its unique structural characteristics. In this paper,the synthetic methods of CMP and CMP composite materials are summarized,and the application of CMPs in gas adsorption and storage,pollutant enrichment,heterogeneous catalysis,light emitters,chemosensors,lightharvesting and energy storage are reviewed.
出处
《化学通报》
CAS
CSCD
北大核心
2016年第8期699-706,713,共9页
Chemistry
基金
国家重大科学仪器设备开发专项(2011YQ0301240901)
国家自然科学基金项目(21575168
21277176和21475153)
广东省自然科学基金项目(2015A030311020)
广东省公益研究与能力建设专项(2015A030401036)资助
关键词
共轭微孔聚合物
复合材料
制备
应用
Conjugate microporous polymers
Composite materials
Synthesis
Application