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铁基软磁非晶/纳米晶合金研究进展及应用前景 被引量:51

Research progress and application prospect of Fe-based soft magnetic amorphous/nanocrystalline alloys
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摘要 非晶合金通常是将熔融的金属快速冷却、通过抑制结晶而获得的原子呈长程无序排列的金属材料.由于具有这种特殊结构,铁基软磁非晶合金具有各向同性特征、很小的结构关联尺寸和磁各向异性常数,因而具有很小的矫顽力H_c,但可和晶态材料一样具有高的饱和磁感强度B_s.优异的软磁性能促进了铁基软磁非晶合金的应用研究.目前,铁基软磁非晶/纳米晶合金带材已实现大规模工业化生产和应用,成为重要的高性能软磁材料.本文回顾了软磁非晶合金的发现和发展历程,结合成分、结构、工艺对铁基非晶/纳米晶合金软磁性能的影响,介绍了相关基础研究成果和工艺技术进步对铁基软磁非晶/纳米晶合金研发和工业化应用的重要贡献.并根据结构、性能特征将铁基软磁非晶合金研发与应用分为三个阶段,指出了目前铁基软磁非晶合金研发与应用中面临的挑战和发展方向. Amorphous alloy is a kind of metallic materials prepared by rapidly cooling the alloy melt through hindering crystallization in cooling process. Due to the unique structure of atomic random packing, Fe-based amorphous alloys exhibit not only structural and property isotropy, but also small structural correlation length, small magnetic anisotropic constant, and then small coercivity Hc. Like crystalline Fe-based alloys, Fe-based amorphous alloys also possess high saturation induction Bs. As a result, research on engineering applications of Fe-based amorphous alloys has been promoted by their excellent soft magnetic properties. Now Fe-based soft magnetic amorphous/nanocrystalline alloys have been produced and applied to various areas on a large scale. Here in this paper, the processes of discovery, development and application of Fe-based soft magnetic amorphous alloys are reviewed, and the effects of chemical composition,structure and preparation technology on the soft magnetic properties are introduced and discussed. The obtained theoretic results and the technological innovation show that the great contributions have been made to the development and application of Fe-based soft magnetic amorphous/crystalline alloys. Based on the progress of structure and soft magnetic property and our understanding, the development process of the fundamental research and the application progress of Fe-based soft magnetic amorphous alloys could be divided into three periods. In addition, the present challenge topics in their researches and applications are proposed.
出处 《物理学报》 SCIE EI CAS CSCD 北大核心 2018年第1期1-8,共8页 Acta Physica Sinica
基金 国家重点基础研究发展计划(批准号:2016YB0300500) 国家自然科学基金(批准号:51571127)资助的课题~~
关键词 非晶合金 软磁性能 纳米晶合金 amorphous alloys, soft magnetic property, nanocrystalline alloys
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