摘要
采用差示扫描量热法(DSC)和X射线衍射法(XRD),研究了含能增塑剂双(2,2-二硝基丙基)缩甲(乙)醛(BDNPF/A)与6种高能炸药[1-氧-2,6-二氨基-3,5-二硝基吡嗪(LLM-105)、三氨基三硝基苯(TATB)、2,6-二氨基-3,5-二硝基吡啶-1-氧化物(ANPy O)、奥克托今(HMX)、六硝基六氮杂异伍兹烷(CL-20)和3-硝基-1,2,4-三唑-5-酮(NTO)]的相容性。DSC结果表明:BDNPF/A与TATB混合体系相容,与LLM-105混合体系轻微敏感,与ANPy O和HMX混合体系敏感,与CL-20和NTO混合体系危险。XRD结果表明:BDNPF/A与HMX、CL-20和NTO之间存在相互作用。上述试验研究表明,BDNPF/A与CL-20和NTO相容性差,不推荐一起使用。
Differential scanning calorimetry(DSC)and X-ray diffractometry(XRD)were used to examine compa-tibility of energetic plasticizer bis(2,2-dinitropropyl)for^mal(acetal)(BDNPF/A)with six high explosives,including2,6-diamino-3,5-dinitropyrazine-1-oxide(LLM-105),2,4,6-triamino-1,3,5-trinitrobenzene(TATB),2,6-diamino-3,5-di-nitropyridine-1-oxide(ANPyO),cyclotetramethylenete tranitroamine(HMX),2,4,6,8,10,12-hexanitrohcxaazaiso-wartzi-tane(CL-20)and3-nitro-1,2,4-triazol-5-one(NTO).DSC measurements show that BDNPF/A is compatible with TATB,slightly sensitive with LLM-105,sensitive with ANPyO or HMX,and dangerous with CL-20or NTO.XRD measurements show that there are interactions between BDNPF/A and HMX,or CL-20and NTO.Results above indicate that BDNPF/A is incompatible with CL-20or NTO,and is not recommended to be used with either one of them.
作者
马泽文
李席
韩志伟
王伯良
MA Zewen;LI Xi;HAN Zhiwei;WANG Boliang(School of Chemical Engineering,Nanjing University of Science and Technology (Jiangsu Nanjing,210094))
出处
《爆破器材》
CAS
2017年第6期11-16,共6页
Explosive Materials
基金
江苏省自然科学基金--青年基金项目(BK20150780)
江苏高校优势学科建设工程资助项目
关键词
含能增塑剂
差示扫描量热法
X射线衍射法
相容性
energetic plasticizer
differential scanning calorimetry
X-ray diffractometry
compatibility
