摘要
通过向家蚕饲料中添加少量含氢硅油的方法制备有机硅改性蚕丝,并采用扫描电子显微镜、X射线能谱仪、傅里叶变换红外光谱仪、元素分析仪、热重分析仪对添食硅油前后蚕丝的形貌、结构及性能进行表征。结果表明:添食硅油后蚕丝中成功引入了硅元素;蚕丝的微观形貌变化不大,但表面更粗糙;蚕丝的结构发生了改变,导致红外光谱中酰胺振动谱带发生移动;硫元素质量分数略微升高;与普通蚕丝相比,热质量损失过程整体趋势相同,但热稳定性略高。
The silicone modified silk fiber was prepared by feeding silkworm with a small amount of hydrogen-containing silicone oil. The morphology,structure and properties of the silk fiber before and after adding silicone oil were characterized by the scanning electron microscope,X-ray energy spectrometer,Fourier transform infrared spectrometer,elemental analyzer,and thermogravimetric analyzer. The results show that Si is successfully introduced into the silk fiber after adding silicone oil;the microscopic morphology of the silk fiber changes little,but its surface is rougher causing the amide vibration band to shift in the infrared spectrum;and the mass fraction of the Si element slightly increases. Compared with ordinary silk,the trend of the thermal mass loss process keeps the same,but its thermal stability is slightly higher.
作者
杨雪敏
徐鹤薇
杨科芳
李莉
YANG Xue-min;XU He-wei;YANG Ke-fang;LI Li(Key Laboratory of Organosilicon Chemistry and Materials Technology,Ministry of Education,Hangzhou Normal University,Hangzhou 311121,Zhejiang;Hangzhou Guancheng Experimental School,Hangzhou 310004,Zhejiang;School of Materials and Chemistry and Chemical Engineering,Hangzhou Normal University,Hangzhou 311121,Zhejiang)
出处
《有机硅材料》
CAS
2020年第1期30-34,共5页
Silicone Material
关键词
有机硅
改性
结构
喂食法
蚕丝
silicone
modification
structure
feeding method
silk
