摘要
纳米碳化聚合物作为一种新型的碳纳米材料引起了人们广泛的关注。纳米碳化聚合物具有独特的核壳结构(sp^(2)/sp^(3)组成碳核,聚合物链、官能团构成壳),学者们通过调控反应条件以获得预期的纳米碳化聚合物结构,并将其广泛应用于生物成像、传感器、催化、发光二极管、铜基复合材料等领域。本文分析讨论了纳米碳化聚合物的结构、合成方法、形成机理、主要性质及应用,介绍了该同素异构体在材料、尤其是粉末冶金材料中的最新研究成果,最后对纳米碳化聚合物未来的发展进行展望。
As a new type of carbon nanomaterials,the nano-carbonized polymers have attracted the extensive attention.The nano-carbonized polymers show the unique core-shell structure(carbon core formed by sp^(2)/sp^(3),shell formed by functional groups and polymer chains)which have been widely used in biological imaging,sensors,catalysis,light-emitting diode,copper matrix composites,and other fields.The ideal nano-carbonized polymers can be obtained by controlling the reaction conditions.The structure,synthesis method,formation mechanism,main properties,and applications of the nano-carbonized polymers were discussed and analyzed in this paper,and the latest research about the isomer in material field,especially in the powder metallurgy materials,was introduced.Finally,the future development outlook of the nano-carbonized polymers was prospected.
作者
易健宏
赵文敏
何衍
鲍瑞
YI Jian-hong;ZHAO Wen-min;HE Yan;BAO Rui(Faculty of Materials Science and Engineering,Kunming University of Science and Technology,Kunming 650093,China)
出处
《粉末冶金技术》
CAS
CSCD
北大核心
2022年第5期401-412,共12页
Powder Metallurgy Technology
基金
国家自然科学基金资助项目(52064032,52174345)
云南省科技厅重大科技专项(202002AB080001)。
关键词
纳米碳化聚合物
碳点
光致发光
量子产率
复合材料
nano-carbonized polymer
carbon dots
photoluminescence
quantum yield
composites
