摘要
介绍了一个综合实验,在合成四氮杂大环配合物[NiL](ClO_(4))_(2)基础上,构建一个以四氮杂大环配合物[NiL](ClO_(4))_(2)催化的Briggs-Rauscher非线性化学振荡体系,并用此体系来实现对对羟基苯乙酮的定量检测。其中,配合物[NiL](ClO_(4))_(2)中的配体L为5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四烷-4,11-二烯。该综合实验囊括了无机化学,分析化学,有机化学,物理化学的有关知识,使用数字化仪器和电脑软件,使得操作简便,结果精确。
A comprehensive experiment is introduced in this paper.Based on the synthesis of[NiL](ClO_(4))_(2),a Briggs-Rauscher chemical oscillation system using[NiL](ClO_(4))_(2) as catalyst was studied,and Briggs-Rauscher system was used for quantitative detection of p-hydroxyacetophenone.The L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene.This comprehensive experiment includes inorganic chemistry,analytical chemistry,organic chemistry,physical chemistry.The digital instruments and computer software were used in comprehensive experiment,making the operation simple,results accurate.
作者
王俊
李白
陈卓
潘亚男
胡刚
Wang Jun;Li Bai;Chen Zhuo;Pan Yanan;Hu Gang(College of Chemistry and Chemical Engineering,Anhui University,Hefei 230601,China)
出处
《山东化工》
CAS
2023年第6期123-125,130,共4页
Shandong Chemical Industry
基金
国家自然科学基金项目(21171002)
安徽大学化学化工学院教研项目专项基金(2020-9)。
