摘要
功能性框架材料包括金属有机框架(Metal organic frameworks,MOFs)和共价有机框架(Covalent organic frameworks,COFs),前者是一类金属离子与有机配体配位连接的聚合物,后者是一类无金属共价连接的有机聚合物,具有比表面积大、结构可调性等特点,是近年来功能性材料研究热点。功能性框架材料自身的结构优势决定其在载酶光催化转化CO_(2)方面具有良好的应用潜力,简要总结了近年来酶/功能性框架材料光催化转化CO_(2)的研究进展,介绍了MOFs材料与COFs材料在酶光催化转化CO_(2)中的应用、优势、存在问题及未来的发展机遇。
Functional framework materials include metal-organic frameworks(MOFs)and covalent organic frameworks(COFs).The former is a kind of polymer coordinated by metal ions and organic ligands,and the latter is a kind of organic polymer without a metal covalent connection.With large specific surface areas,adjustable structures,and other characteristics,these functional materials have been a research hotspot in recent years.The structural advantages of functional framework materials determined their good application potential in the field of photocatalytic conversion of CO_(2)with enzymes.The research progress of enzyme/functional framework materials for photocatalytic conversion of CO_(2)in recent years was briefly summarized.The application,advantages,existing problems,and future development opportunities of MOFs and COFs in enzymatic photocatalytic conversion of CO_(2)were reviewed.
作者
仇逸楠
王宜峰
王燕飞
胡嘉欢
罗希
尹丰伟
付永前
QIU Yi-nan;WANG Yi-feng;WANG Yan-fei;HU Jia-huan;LUO Xi;YIN Feng-wei;FU Yong-qian(College of Life and Medicine,Zhejiang Sci-Tech University,Hangzhou 310018,China;Taizhou Key Laboratory of Biomass Functional Materials Development and Application,Taizhou University,Taizhou 318000,China;College of Food and Pharmaceutical Engineering,Nanjing Normal University,Nanjing 210023,China;Taizhou Institute of Product Quality and Safety Inspection,Taizhou 318000,China)
出处
《化学试剂》
CAS
北大核心
2023年第10期21-30,共10页
Chemical Reagents
基金
浙江省基础公益研究计划项目(LGG20B060001)
浙江省重点研发计划项目(2020C02049)。
关键词
金属有机框架
共价有机框架
酶
催化
二氧化碳
metal organic frameworks
covalent organic frameworks
enzyme
catalysis
carbon dioxide
