摘要
共价有机框架材料(COFs)因其结构单元多样性、拓扑结构、有序孔道结构等特点在气体吸附、催化、光电等领域得到广泛的应用。近些年来,基于COFs材料的有序孔道和易于功能化修饰的特性,COFs材料在固态电解质领域展现出巨大的潜力。本文主要总结了近十年来COFs型固态电解质的研究进展,包括聚合物链段-COFs型、离子基团-COFs型固态电解质的应用和锂离子传导性能。对COFs型固态电解质设计思路及未来发展方向进行总结与展望,以期为固态电解质材料的发展提供新思路。
Covalent organic frameworks(COFs)have been widely used in gas adsorption,catalysis,optoelectronics,and other fields due to their diverse building blocks,topological structures,and ordered pore structures.In recent years,based on the ordered pores and easy functionalization of COFs,which have shown great potentials in the field of solid-state electrolytes.This article mainly summarizes the research progress of COFs based solid electrolytes in the past decade,including the application and lithium ion conductivity of polymer-COFs and ionic group-COFs solid electrolytes.Furthermore,we also summarize and prospect the design and future development directions of COFs based solid electrolytes,which can provide new ideas for the development of solid electrolyte materials.
作者
汪灿
王英姑
耿亚芸
杨志伟
李震
Wang Can;Wang Yinggu;Geng Yayun;Yang Zhiwei;Li Zhen(School of Materials Science and Engineering,East China Jiaotong University,Jiangxi,330013;Institute of Architectural Engineering,Nanchang Institute of Technology,Jiangxi,330044)
出处
《当代化工研究》
CAS
2024年第3期21-23,共3页
Modern Chemical Research
基金
2022年国家自然科学基金项目“缺陷型共价有机框架材料功能化修饰及其性能研究”(项目编号:52103205)
2020年江西省自然科学基金项目“基于三维一体化骨架和填料的固态复合聚合物电解质构建及协同增强机制研究”(项目编号:20202ACBL214007)。
关键词
共价有机框架
固态电解质
锂离子传导
covalent organic frameworks
solid electrolyte
lithium ion conduction
