摘要
介绍了超临界流体的概念和超临界流体独特的性质。从化学动力学和热力学的角度,阐述了超临界反应对化学反应的影响。重点对超临界反应在烷基化、异构化、氧化、加氢及F-T合成等非均相催化方面的应用进行综述。
The supercritical fluids and the supercritical reactions were introduced in this paper. The influence of SCF on the chemical reactions was introduced in term of chemical kinetics and thermodynamics. Heterogeneous catalytic reactions in supercritical fluids such as alkylation, isomerization, oxidation, hydrogenation and Fischer-Tropsch synthesis were paid much attention in this review.
出处
《化学与粘合》
CAS
2003年第2期81-85,共5页
Chemistry and Adhesion
基金
黑龙江省科学院重点基金项目
关键词
超临界流体
超临界反应
非均相催化
supercritical fluid
supercritical reaction
heterogeneous catalytic reaction