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硒插入C—Zn键及其生成物与环氧、α,β-不饱和酯(腈)的反应 被引量：5

Reaction of Epoxide or α,β-Unsaturated Esters (Nitriles) with Selenium Insertion Adduct of Arylzinc Halides
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摘要 硒插入芳基锌的C—Zn键产生对应的芳基硒化锌 ,它与环氧或α ,β 不饱和酯 (腈 )在温和的条件反应生成对应的不对称的硒醚 . Aryl zinc selenoates were formed through selenium insertion into the zinc carbon bond of aryl zinc halides. Reaction of the insertion adducts with epoxides and α,β unsaturated esters (nitriles) in THF HMPA afforded the corresponding unsymmetrical selenides, respectively.
作者 刘文奇 黄荣新 许新华
机构地区 郴州高等师范专科学校化学系 湖南大学化学化工学院
出处 《有机化学》 SCIE CAS CSCD 北大核心 2003年第3期286-287,共2页 Chinese Journal of Organic Chemistry
关键词 芳基硒化锌 环氧化合物 α β不饱和酯 不对称硒醚 C-Zn 碳锌键 有机硒化合物 selenium, epoxide, α,β unsaturated esters (nitriles), unsymmetrical selenide
分类号 O621.25 [理学—有机化学]
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有机化学
2003年 第3期

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