期刊文献+

新型分子筛SBA-15固载手性Salen Mn(Ⅲ)配合物的合成及其催化性能的研究 被引量:7

Chiral Salen Manganese Complexes Immobilized on SBA-15 Catalyzed Asymmetric Epoxidation of Alkenes
原文传递
导出
摘要 Jacobsen’s catalyst was immobilized onto SBA-15 by multi-step grafting, and this new heterogenized catalyst exhibited comparable catalytic performance with the corresponding homogeneous counterpart for the epoxidation of alkenes.When NH4OAc were used as cocatalyst both yields and ee’s were higher than that of without co catalyst. Jacobsen's catalyst was immobilized onto SBA-15 by multi-step grafting, and this new heterogenized catalyst exhibited comparable catalytic performance with the corresponding homogeneous counterpart for the epoxidation of alkenes.When NH_4OAc were used as cocatalyst both yields and ee's were higher than that of without co catalyst.
出处 《分子催化》 EI CAS CSCD 北大核心 2003年第6期461-464,共4页 Journal of Molecular Catalysis(China)
关键词 SBA-15 手性SALEN Mn(Ⅲ)配合物 烯烃 不对称环氧化 SBA-15 Chiral salen Mn(Ⅲ) complex Alkenes Asymmetric epoxidation
  • 相关文献

参考文献10

  • 1MorrisonJD.AsymmetricSynthesis[]..1983
  • 2.Reviewsonmetalloporphyrin-catalyzedoxidation[].MetalloporphyrinsInCatalyticOxida-tions.1994
  • 3BanfiS,MaiocchiA,MontanariF,QuiciS. GazzChimItal . 1990
  • 4.Reviewsonmetalloporphyrin-catalyzedoxidation[].MeunierBChemRev.1992
  • 5AnelliPL,BanfiS,MontanariF,QuiciS. JChemSocChemComm . 1989
  • 6JacobsenEN,ZhangWJ.OrgChem[]..1991
  • 7Ogunwumi S B,Bein T. Chemical Communications . 1997
  • 8Das B K,Clark J H. Chemical Communications . 2000
  • 9KimGJ,ShinJH.Tetrahedronlett[]..1999
  • 10Zhao D. Feng J. Huo Q. et al. Science . 1998

同被引文献145

引证文献7

二级引证文献21

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部