摘要
四乙酰基二苄基六氮杂异伍兹烷(TADBIW)是六苄基六氮杂异伍兹烷(HBIW)的氢解脱苄产物。在不同酸性体系中氢解TADBIW将得到不同的脱苄产物。以丙酸和正丁酸为氢解介质,采用自制的Pd系催化剂氢解TADBIW制得了四乙酰基六氮杂异伍兹烷(TAIW),并对其反应过程做了初步的探讨。
Tetraacetyldibenzylhexaazaisowurtzitane(TADBIW)is a product of hydrogenolysis debenzylation of hexabenzylhexaazaisowurtzitane(HBIW). Various products can be formed from hydrogenolysis debenzylation of TADBIW in different media using Pd catalyst prepared at the lab. Tetraacetylhexaazaisowurtzitane(TAIW)is obtained by hydrogenolysis of TADBIW in propionic acid and n-butyric acid. The related reaction mechanism is also discussed.
出处
《火炸药学报》
EI
CAS
CSCD
2004年第2期10-12,共3页
Chinese Journal of Explosives & Propellants
基金
总装备部预研基金资助(12060451867)。
