Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,how...Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.展开更多
Background: The tricuspid annular plane systolic excursion (TAPSE) and pulmonary artery systolic pressure (PASP) is an indirect estimate of right ventricular-pulmonary arterial (RV-PA) coupling that has been shown to ...Background: The tricuspid annular plane systolic excursion (TAPSE) and pulmonary artery systolic pressure (PASP) is an indirect estimate of right ventricular-pulmonary arterial (RV-PA) coupling that has been shown to correlate with invasive measures. We aimed to assess the ability of the tricuspid annular plane systolic excursion/pulmonary systolic pressure ratio (TAPSE/PASP) as a measure for RV-PA coupling to predict the development of RV dysfunction after cardiac surgery. Methods: This prospective study was conducted on 100 patients with ischemic heart disease and undergoing cardiac surgery (coronary artery bypass graft (CABG)) with normal preoperative right ventricular function, classified according to RV function outcomes into 2 groups: Normal RV group (65 patients) and RV dysfunction group (35 patients). All cases underwent per and postoperative transthoracic echocardiography. Results: By using receiver operating characteristic curve analysis, pre-operative TAPSE/PASP ratio could significantly predict the RV dysfunction (P 0.58, with AUC of 94%, 88.6% sensitivity, and 89.2% specificity. Post-operative TAPSE/PASP Ratio could significantly predict the RV dysfunction (P 0.39, with AUC of 84%, 100% sensitivity, and 76.9% specificity. Pre-operative TAPSE/PASP ratio could significantly predict mortality (P Conclusion: The TAPSE/PASP ratio is an excellent tool for CABG patients for its ability to detect and predict the development of RV dysfunction after cardiac surgery, along with the prediction of mortality in post-operative CABG patients.展开更多
In recent years,the development of ultrafast transmission electron microscopy(UTEM)has created new opportunities for studying dynamic processes at the nanoscale with unprecedented temporal resolution.~([1–3])The sign...In recent years,the development of ultrafast transmission electron microscopy(UTEM)has created new opportunities for studying dynamic processes at the nanoscale with unprecedented temporal resolution.~([1–3])The significant advances in femtosecond and even attosecond temporal resolution are achieved through the integration of the pump-probe principle with transmission electron microscopy(TEM).展开更多
Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,sy...Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,synthesized via cation exchange and calcination oxidation.These catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and selectivities.These catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as precursors.The porous architecture and polymetallic composition of the NiCo_(2)O_(4)spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for phenol.Key innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT simulations.This work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.展开更多
We study the trimer state in a three-body system,where two of the atoms are subject to Rashba-type spin-orbit coupling and spin-dependent loss while interacting spin-selectively with the third atom.The short-time cond...We study the trimer state in a three-body system,where two of the atoms are subject to Rashba-type spin-orbit coupling and spin-dependent loss while interacting spin-selectively with the third atom.The short-time conditional dynamics of the three-body system is effectively governed by a non-Hermitian Hamiltonian with an imaginary Zeeman field.Remarkably,the interplay of non-Hermitian single particle dispersion and the spin-selective interaction results in a Borromean state and an enlarged trimer phase.The stability of trimer state can be reflected by the imaginary part of trimer energy and the momentum distribution of trimer wave function.We also show the phase diagram of the three-body system under both real and imaginary Zeeman fields.Our results illustrate the interesting consequence of non-Hermitian spectral symmetry on the few-body level,which may be readily observable in current cold-atom experiments.展开更多
Land–atmosphere coupling and sea surface temperature(SST)anomalies both have essential impacts on weather and climate extremes.Based on the ERA5 reanalysis dataset and the CESM1.2.2 model,this study investigates the ...Land–atmosphere coupling and sea surface temperature(SST)anomalies both have essential impacts on weather and climate extremes.Based on the ERA5 reanalysis dataset and the CESM1.2.2 model,this study investigates the influence of land–atmosphere coupling on summer extreme hot-humid events(EHHE)over southern Eurasia under different SST backgrounds.The results suggest that coupling causes near-surface air temperature increases that exceed 0.5℃.From 1961 to 2020,the frequency of EHHE has continuously increased,and is closely related to soil moisture anomalies in the northern Indian Peninsula(IDP)and the middle and lower reaches of the Yangtze River(YRB).Numerical simulations further demonstrate that land–atmosphere coupling raises the risk of EHHE by 25.4%.In a typical El Niño SST background state,intensified land–atmosphere coupling tends to produce notable increases in the frequency of EHHE.The dominant processes that land–atmosphere coupling affects the EHHE variations are evidently different between these two regions.Land surface thermal anomalies predominate in the IDP,while moisture conditions are more critical in the YRB.When warm SST anomalies exist,dry soil anomalies in the IDP are prominent,and evaporation is constrained,increasing sensible heat flux.Positive geopotential height anomalies are significant,combined with adiabatic warming induced by descending motion and a noticeable warm center in the near-surface atmosphere.The southward shift of the westerly jet enhances divergence over YRB.The anticyclonic circulation anomalies over the western Pacific are conducive to guiding moisture transport to the YRB,providing a favorable circulation background for the development of summer EHHE.展开更多
Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to re...Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to reinforce GRS. The effects of cement content and SiO_(2)/Na2O ratio of the alkaline solution on the static and dynamic strengths of GRS were discussed. Microscopically, the reinforcement mechanism and coupling effect were examined using X-ray diffraction (XRD), micro-computed tomography (micro-CT), and scanning electron microscopy (SEM). The results indicated that the addition of 2% cement and an alkaline solution with an SiO_(2)/Na2O ratio of 0.5 led to the densest matrix, lowest porosity, and highest static compressive strength, which was 4994 kPa with a dynamic impact resistance of 75.4 kN after adding glass fiber. The compressive strength and dynamic impact resistance were a result of the coupling effect of cement hydration, a pozzolanic reaction of clay minerals in the GRS, and the alkali activation of clay minerals. Excessive cement addition or an excessively high SiO_(2)/Na2O ratio in the alkaline solution can have negative effects, such as the destruction of C-(A)-S-H gels by the alkaline solution and hindering the production of N-A-S-H gels. This can result in damage to the matrix of reinforced GRS, leading to a decrease in both static and dynamic strengths. This study suggests that further research is required to gain a more precise understanding of the effects of this mixture in terms of reducing our carbon footprint and optimizing its properties. The findings indicate that cement and alkaline solution are appropriate for GRS and that the reinforced GRS can be used for high-strength foundation and embankment construction. The study provides an analysis of strategies for mitigating and managing GRS slope failures, as well as enhancing roadbed performance.展开更多
The Kuye River Basin has experienced a rapid depletion of groundwater due to the increased coal production.In this study,by introducing the empirical equations derived from the three zone theory in the coal mining ind...The Kuye River Basin has experienced a rapid depletion of groundwater due to the increased coal production.In this study,by introducing the empirical equations derived from the three zone theory in the coal mining industry in China as a boundary condition,a calculation model was developed by coupling the soil and water assessment tool and visual modular three-dimensional finite-difference ground-water flow model(SWAT-VISUAL MODFLOW).The model was applied to several coal mines in the basin to quantify the groundwater impact of underground mining.For illustration purposes,two underground water observation stations and one water level station were selected for groundwater change simulation in 2009,producing the results that agreed well with the observed data.We found that groundwater level was closely related to the height of the fractured water-conducting zone caused by underground mining,and a higher height led to a lower groundwater level.This finding was further supported by the calculation that underground mining was responsible for 23.20mm aquifer breakages in 2009.Thus,preventing surface subsidence due to underground mining can help protecting the basin's groundwater.展开更多
In Earth system modeling,the land surface is coupled with the atmosphere through surface turbulent fluxes.These fluxes are computed using mean meteorological variables between the surface and a reference height in the...In Earth system modeling,the land surface is coupled with the atmosphere through surface turbulent fluxes.These fluxes are computed using mean meteorological variables between the surface and a reference height in the atmosphere.However,the dependence of flux computation on the reference height,which is usually set as the lowest level in the atmosphere in Earth system models,has not received much attention.Based on high-resolution large-eddy simulation(LES)data under unstable conditions,we find the setting of reference height is not trivial within the framework of current surface layer theory.With a reasonable prescription of aerodynamic roughness length(following the setting in LESs),reference heights near the top of the surface layer tend to provide the best estimate of surface fluxes,especially for the momentum flux.Furthermore,this conclusion for the sensible heat flux is insensitive to the ratio of roughness length for momentum versus heat.These results are robust,whether using the classical or revised surface layer theory.They provide a potential guide for setting the proper reference heights for Earth system modeling and can be further tested in the near future using observational data from land–atmosphere feedback observatories.展开更多
Periodic metal nanoarrays serving as cavities can support directional-tunable amplified spontaneous emission that goes beyond the diffraction limit due to the hybrid states of surface plasmons and Bloch surface waves....Periodic metal nanoarrays serving as cavities can support directional-tunable amplified spontaneous emission that goes beyond the diffraction limit due to the hybrid states of surface plasmons and Bloch surface waves.Most of these modes'interactions remain within the weak coupling regime,yet strong coupling is also anticipated to occur.In this work,we present an intriguing case of amplified spontaneous emission(ASE),amplified by the splitting upper polariton mode within a strong coupling system,stemming from a square lattice of plasmonic cone lattices(PCLs).The PCLs are fabricated using an anodized aluminum oxide membrane(AAO),which facilitates strong coupling between surface plasmons and Bloch surface wave modes,with the maximum Rabi splitting observed at 0.258 eV for the sample with an aspect ratio of 0.33.A 13.5-fold increase in amplified spontaneous emission is recorded when the emission from Nile Red coincides with this flat energy branch of upper polariton,which exhibits a high photon density of states.Reduced group velocity can prolong photon lifetime and boost the probability of light-matter interaction.The observed ASE phenomenon in this strong coupling plasmonic system widens the scope for applications in nanolasing and polariton lasing.展开更多
The vehicle-road coupling dynamics problem is a prominent issue in transportation,drawing significant attention in recent years.These dynamic equations are characterized by high-dimensionality,coupling,and time-varyin...The vehicle-road coupling dynamics problem is a prominent issue in transportation,drawing significant attention in recent years.These dynamic equations are characterized by high-dimensionality,coupling,and time-varying dynamics,making the exact solutions challenging to obtain.As a result,numerical integration methods are typically employed.However,conventional methods often suffer from low computational efficiency.To address this,this paper explores the application of the parameter freezing precise exponential integrator to vehicle-road coupling models.The model accounts for road roughness irregularities,incorporating all terms unrelated to the linear part into the algorithm's inhomogeneous vector.The general construction process of the algorithm is detailed.The validity of numerical results is verified through approximate analytical solutions(AASs),and the advantages of this method over traditional numerical integration methods are demonstrated.Multiple parameter freezing precise exponential integrator schemes are constructed based on the Runge-Kutta framework,with the fourth-order four-stage scheme identified as the optimal one.The study indicates that this method can quickly and accurately capture the dynamic system's vibration response,offering a new,efficient approach for numerical studies of high-dimensional vehicle-road coupling systems.展开更多
Photoelectrocatalytic coupling CO_(2)and volatile organic compounds (VOCs) is a promising green strategy for the synergistic conversion of the two carbon-containing resources to C2products.The catalytic efficiency is ...Photoelectrocatalytic coupling CO_(2)and volatile organic compounds (VOCs) is a promising green strategy for the synergistic conversion of the two carbon-containing resources to C2products.The catalytic efficiency is always at the mercy of chemical inertness of CO_(2)and the competitive hydrogen evolution of H2O.Herein,a modified g-C_(3)N_(4)/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely constructed.The Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol g^(-1)h^(-1).As revealed by in-situ characterizations and density functional theory calculations,CO_(2)and HCHO were absorbed at Zn site and N site,respectively.Then,*CO generated from CO_(2)and HCHO was converted to*CH_(3)O and*CHO on the dual-active-site heterojunction.The detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH_(3)O in electrocatalysis process.Apart from the“*CO+*CH_(3)O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic process.The selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO_(2)and HCHO simultaneously driven by light and electricity.展开更多
The electromagnetic wave propagations and their coupling characteristics in magnetized plasma near the antenna of ion cyclotron range of frequencies(ICRF)is studied based on self-developed 3DFEM-IA code.This code effe...The electromagnetic wave propagations and their coupling characteristics in magnetized plasma near the antenna of ion cyclotron range of frequencies(ICRF)is studied based on self-developed 3DFEM-IA code.This code effectively resolves the three-dimensional(3D)geometry and the electromagnetic field using the finite element method.Our findings reveal that the distributions of electromagnetic fields and energy flow density significantly depend on the antenna phases,surface current density on the antenna straps,and background plasma density.Notably,the non-uniform surface current density on the antenna straps,resulting from the presence of induced currents,contributes to a reduction in coupling power within the edge plasma.Furthermore,the calculated coupling impedance increases with plasma density,corroborating well with experimental measurements.展开更多
Dual atomic catalysts(DAC),particularly copper(Cu_(2))-based nitrogen(N)doped graphene,show great potential to effectively convert CO_(2)and nitrate(NO_(3)-)into important industrial chemicals such as ethylene,glycol,...Dual atomic catalysts(DAC),particularly copper(Cu_(2))-based nitrogen(N)doped graphene,show great potential to effectively convert CO_(2)and nitrate(NO_(3)-)into important industrial chemicals such as ethylene,glycol,acetamide,and urea through an efficient catalytical process that involves C–C and C–N coupling.However,the origin of the coupling activity remained unclear,which substantially hinders the rational design of Cu-based catalysts for the N-integrated CO_(2)reduction reaction(CO_(2)RR).To address this challenge,this work performed advanced density functional theory calculations incorporating explicit solvation based on a Cu_(2)-based N-doped carbon(Cu_(2)N_(6)C_(10))catalyst for CO_(2)RR.These calculations are aimed to gain insight into the reaction mechanisms for the synthesis of ethylene,acetamide,and urea via coupling in the interfacial reaction micro-environment.Due to the sluggishness of CO_(2),the formation of a solvation electric layer by anions(F^(-),Cl^(-),Br^(-),and I^(-))and cations(Na+,Mg^(2+),K+,and Ca^(2+))leads to electron transfer towards the Cu surface.This process significantly accelerates the reduction of CO_(2).These results reveal that*CO intermediates play a pivotal role in N-integrated CO_(2)RR.Remarkably,the Cu_(2)-based N-doped carbon catalyst examined in this study has demonstrated the most potential for C–N coupling to date.Our findings reveal that through the process of a condensation reaction between*CO and NH_(2)OH for urea synthesis,*NO_(3)-is reduced to*NH_(3),and*CO_(2)to*CCO at dual Cu atom sites.This dual-site reduction facilitates the synthesis of acetamide through a nucleophilic reaction between NH_(3)and the ketene intermediate.Furthermore,we found that the I-and Mg^(2+)ions,influenced by pH,were highly effective for acetamide and ammonia synthesis,except when F-and Ca^(2+)were present.Furthermore,the mechanisms of C–N bond formation were investigated via ab-initio molecular dynamics simulations,and we found that adjusting the micro-environment can change the dominant side reaction,shifting from hydrogen production in acidic conditions to water reduction in alkaline ones.This study introduces a novel approach using ion-H_(2)O cages to significantly enhance the efficiency of C–N coupling reactions.展开更多
To address the challenges associated with existing separated zone oil production technologies,such as incompatibility with pump inspection operations,short effective working life,and poor communication reliability,an ...To address the challenges associated with existing separated zone oil production technologies,such as incompatibility with pump inspection operations,short effective working life,and poor communication reliability,an innovative electromagnetic coupling intelligent zonal oil production technology has been proposed.The core and accessory tools have been developed and applied in field tests.This technology employs a pipe string structure incorporation a release sub,which separates the production and allocation pipe strings.When the two strings are docked downhole,electromagnetic coupling enables close-range wireless transmission of electrical power and signals between the strings,powering multiple downhole intelligent production allocators(IPAs)and enabling two-way communication.Core tools adapted to the complex working conditions downhole were developed,including downhole electricity&signal transmission equipment based on electromagnetic coupling(EST),IPAs,and ground communication controllers(GCCs).Accessory tools,including large-diameter release sub anchor and cable-crossing packers,have also been technically finalized.Field tests conducted on ten wells in Daqing Oilfield demonstrated that the downhole docking of the two strings was convenient and reliable,and the EST worked stably.Real-time monitoring of flow rate,pressure and temperature in separate layers and regulation of zonal fluid production were also achieved.This technology has enhanced reservoir understanding and achieved practical production results of increased oil output with reduced water cut.展开更多
This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker...This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker electron-phonon coupling in perovskite has been achieved by introducing the structurally soft cyclohexane methylamine(CMA^(+))cation,which could serve as a damper to alleviate the mechanical stress caused by lattice oscillations,compared to the rigid phenethyl methylamine(PEA^(+))analog.It demonstrates a significantly lower non-radiative recombination rate,even though the two types of bulky cations have similar chemical passivation effects on perovskite,which might be explained by the suppressed carrier capture process and improved lattice geometry relaxation.The resulting PSCs achieve an exceptional power conversion efficiency(PCE)of 25.5%with a record-high opencircuit voltage(V_(OC))of 1.20 V for narrow bandgap perovskite(FAPbI_(3)).The established correlations between electron-phonon coupling and non-radiative decay provide design and screening criteria for more effective passivators for highly efficient PSCs approaching the Shockley-Queisser limit.展开更多
This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation i...This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation in wall pressure of the blasting holes.Using DDNP explosive as the explosive load,blasting tests were conducted on red sandstone specimens with four different water coupling coefficients:1.20,1.33,1.50,and 2.00.The study examines the morphologies of the rock specimens after blasting under these different water coupling coefficients.Additionally,the fractal dimensions of the surface cracks resulting from the blasting were calculated to provide a quantitative evaluation of the extent of rock damage.CT scanning and 3D reconstruction were performed on the post-blasting specimens to visually depict the extent of damage and fractures within the rock.Additionally,the volume fractal dimension and damage degree of the post-blasting specimens are calculated.The findings are then combined with numerical simulation to facilitate auxiliary analysis.The results demonstrate that an increase in the water coupling coefficient leads to a reduction in the peak pressure on the hole wall and the crushing zone,enabling more of the explosion energy to be utilized for crack propagation following the explosion.The specimens exhibited distinct failure patterns,resulting in corresponding changes in fractal dimensions.The simulated pore wall pressure–time curve validated the derived theoretical results,whereas the stress cloud map and explosion energy-time curve demonstrated the buffering effect of the water medium.As the water coupling coefficient increases,the buffering effect of the water medium becomes increasingly prominent.展开更多
Strong coupling between resonantly matched surface plasmons of metals and excitons of quantum emitters results in the formation of new plasmon-exciton hybridized energy states.In plasmon-exciton strong coupling,plasmo...Strong coupling between resonantly matched surface plasmons of metals and excitons of quantum emitters results in the formation of new plasmon-exciton hybridized energy states.In plasmon-exciton strong coupling,plasmonic nanocavities play a significant role due to their ability to confine light in an ultrasmall volume.Additionally,two-dimensional transition metal dichalcogenides(TMDCs) have a significant exciton binding energy and remain stable at ambient conditions,making them an excellent alternative for investigating light-matter interactions.As a result,strong plasmon-exciton coupling has been reported by introducing a single metallic cavity.However,single nanoparticles have lower spatial confinement of electromagnetic fields and limited tunability to match the excitonic resonance.Here,we introduce the concept of catenary-shaped optical fields induced by plasmonic metamaterial cavities to scale the strength of plasmon-exciton coupling.The demonstrated plasmon modes of metallic metamaterial cavities offer high confinement and tunability and can match with the excitons of TMDCs to exhibit a strong coupling regime by tuning either the size of the cavity gap or thickness.The calculated Rabi splitting of Au-MoSe_2 and Au-WSe_2 heterostructures strongly depends on the catenary-like field enhancement induced by the Au cavity,resulting in room-temperature Rabi splitting ranging between 77.86 and 320 me V.These plasmonic metamaterial cavities can pave the way for manipulating excitons in TMDCs and operating active nanophotonic devices at ambient temperature.展开更多
Metal–organic gel(MOG)derived composites are promising multi-functional materials due to their alterable composition,identifiable chemical homogeneity,tunable shape,and porous structure.Herein,stable metal–organic h...Metal–organic gel(MOG)derived composites are promising multi-functional materials due to their alterable composition,identifiable chemical homogeneity,tunable shape,and porous structure.Herein,stable metal–organic hydrogels are prepared by regulating the complexation effect,solution polarity and curing speed.Meanwhile,collagen peptide is used to facilitate the fabrication of a porous aerogel with excellent physical properties as well as the homogeneous dispersion of magnetic particles during calcination.Subsequently,two kinds of heterometallic magnetic coupling systems are obtained through the application of Kirkendall effect.FeCo/nitrogen-doped carbon(NC)aerogel demonstrates an ultra-strong microwave absorption of−85 dB at an ultra-low loading of 5%.After reducing the time taken by atom shifting,a FeCo/Fe3O4/NC aerogel containing virus-shaped particles is obtained,which achieves an ultra-broad absorption of 7.44 GHz at an ultra-thin thickness of 1.59 mm due to the coupling effect offered by dual-soft-magnetic particles.Furthermore,both aerogels show excellent thermal insulation property,and their outstanding radar stealth performances in J-20 aircraft are confirmed by computer simulation technology.The formation mechanism of MOG is also discussed along with the thermal insulation and electromagnetic wave absorption mechanism of the aerogels,which will enable the development and application of novel and lightweight stealth coatings.展开更多
To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study invest...To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study investigates the features of P and F in PG,and explores the decomposition of PF using hydrofluoric acid(HF)in the sulfuric acid system for K leaching and leaching of P and F in PG.The impact factors such as sulfuric acid concentration,reaction temperature,reaction time,material ratio(PG/PF),liquid–solid ratio,PF particle size,and PF calcination temperature on the leaching of P and K is systematically investigated in this paper.The results show that under optimal conditions,the leaching rate of K and P reach more than 93%and 96%,respectively.Kinetics study using shrinking core model(SCM)indicates two significant stages with internal diffusion predominantly controlling the leaching of K.The apparent activation energies of these two stages are 11.92 kJ·mol^(-1)and 11.55 kJ·mol^(-1),respectively.展开更多
基金financially supported by the National Natural Science Foundation of China(Grants nos.62201411,62371378,22205168,52302150 and 62304171)the China Postdoctoral Science Foundation(2022M722500)+1 种基金the Fundamental Research Funds for the Central Universities(Grants nos.ZYTS2308 and 20103237929)Startup Foundation of Xidian University(10251220001).
文摘Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.
文摘Background: The tricuspid annular plane systolic excursion (TAPSE) and pulmonary artery systolic pressure (PASP) is an indirect estimate of right ventricular-pulmonary arterial (RV-PA) coupling that has been shown to correlate with invasive measures. We aimed to assess the ability of the tricuspid annular plane systolic excursion/pulmonary systolic pressure ratio (TAPSE/PASP) as a measure for RV-PA coupling to predict the development of RV dysfunction after cardiac surgery. Methods: This prospective study was conducted on 100 patients with ischemic heart disease and undergoing cardiac surgery (coronary artery bypass graft (CABG)) with normal preoperative right ventricular function, classified according to RV function outcomes into 2 groups: Normal RV group (65 patients) and RV dysfunction group (35 patients). All cases underwent per and postoperative transthoracic echocardiography. Results: By using receiver operating characteristic curve analysis, pre-operative TAPSE/PASP ratio could significantly predict the RV dysfunction (P 0.58, with AUC of 94%, 88.6% sensitivity, and 89.2% specificity. Post-operative TAPSE/PASP Ratio could significantly predict the RV dysfunction (P 0.39, with AUC of 84%, 100% sensitivity, and 76.9% specificity. Pre-operative TAPSE/PASP ratio could significantly predict mortality (P Conclusion: The TAPSE/PASP ratio is an excellent tool for CABG patients for its ability to detect and predict the development of RV dysfunction after cardiac surgery, along with the prediction of mortality in post-operative CABG patients.
文摘In recent years,the development of ultrafast transmission electron microscopy(UTEM)has created new opportunities for studying dynamic processes at the nanoscale with unprecedented temporal resolution.~([1–3])The significant advances in femtosecond and even attosecond temporal resolution are achieved through the integration of the pump-probe principle with transmission electron microscopy(TEM).
基金National Natural Science Foundation of China (U23A6005 and 22078069)Project funded by China Postdoctoral Science Foundation (GZB20230172 and 2023M740748)。
文摘Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,synthesized via cation exchange and calcination oxidation.These catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and selectivities.These catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as precursors.The porous architecture and polymetallic composition of the NiCo_(2)O_(4)spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for phenol.Key innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT simulations.This work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.
基金supported by the National Natural Science Foundation of China(Grant No.11974331)。
文摘We study the trimer state in a three-body system,where two of the atoms are subject to Rashba-type spin-orbit coupling and spin-dependent loss while interacting spin-selectively with the third atom.The short-time conditional dynamics of the three-body system is effectively governed by a non-Hermitian Hamiltonian with an imaginary Zeeman field.Remarkably,the interplay of non-Hermitian single particle dispersion and the spin-selective interaction results in a Borromean state and an enlarged trimer phase.The stability of trimer state can be reflected by the imaginary part of trimer energy and the momentum distribution of trimer wave function.We also show the phase diagram of the three-body system under both real and imaginary Zeeman fields.Our results illustrate the interesting consequence of non-Hermitian spectral symmetry on the few-body level,which may be readily observable in current cold-atom experiments.
基金supported by the National Science Foundation of China(Grant Nos.42088101 and 42275172).
文摘Land–atmosphere coupling and sea surface temperature(SST)anomalies both have essential impacts on weather and climate extremes.Based on the ERA5 reanalysis dataset and the CESM1.2.2 model,this study investigates the influence of land–atmosphere coupling on summer extreme hot-humid events(EHHE)over southern Eurasia under different SST backgrounds.The results suggest that coupling causes near-surface air temperature increases that exceed 0.5℃.From 1961 to 2020,the frequency of EHHE has continuously increased,and is closely related to soil moisture anomalies in the northern Indian Peninsula(IDP)and the middle and lower reaches of the Yangtze River(YRB).Numerical simulations further demonstrate that land–atmosphere coupling raises the risk of EHHE by 25.4%.In a typical El Niño SST background state,intensified land–atmosphere coupling tends to produce notable increases in the frequency of EHHE.The dominant processes that land–atmosphere coupling affects the EHHE variations are evidently different between these two regions.Land surface thermal anomalies predominate in the IDP,while moisture conditions are more critical in the YRB.When warm SST anomalies exist,dry soil anomalies in the IDP are prominent,and evaporation is constrained,increasing sensible heat flux.Positive geopotential height anomalies are significant,combined with adiabatic warming induced by descending motion and a noticeable warm center in the near-surface atmosphere.The southward shift of the westerly jet enhances divergence over YRB.The anticyclonic circulation anomalies over the western Pacific are conducive to guiding moisture transport to the YRB,providing a favorable circulation background for the development of summer EHHE.
基金the support provided by the National Natural Science Foundation of China(Grant Nos.52278336 and 42302032)Guangdong Basic and Applied Research Foundation(Grant Nos.2023B1515020061).
文摘Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to reinforce GRS. The effects of cement content and SiO_(2)/Na2O ratio of the alkaline solution on the static and dynamic strengths of GRS were discussed. Microscopically, the reinforcement mechanism and coupling effect were examined using X-ray diffraction (XRD), micro-computed tomography (micro-CT), and scanning electron microscopy (SEM). The results indicated that the addition of 2% cement and an alkaline solution with an SiO_(2)/Na2O ratio of 0.5 led to the densest matrix, lowest porosity, and highest static compressive strength, which was 4994 kPa with a dynamic impact resistance of 75.4 kN after adding glass fiber. The compressive strength and dynamic impact resistance were a result of the coupling effect of cement hydration, a pozzolanic reaction of clay minerals in the GRS, and the alkali activation of clay minerals. Excessive cement addition or an excessively high SiO_(2)/Na2O ratio in the alkaline solution can have negative effects, such as the destruction of C-(A)-S-H gels by the alkaline solution and hindering the production of N-A-S-H gels. This can result in damage to the matrix of reinforced GRS, leading to a decrease in both static and dynamic strengths. This study suggests that further research is required to gain a more precise understanding of the effects of this mixture in terms of reducing our carbon footprint and optimizing its properties. The findings indicate that cement and alkaline solution are appropriate for GRS and that the reinforced GRS can be used for high-strength foundation and embankment construction. The study provides an analysis of strategies for mitigating and managing GRS slope failures, as well as enhancing roadbed performance.
基金National Key Research and Development Program of China,Grant/Award Number:2021YFC3201103-01Project Funds of Administration for Market Regulation Henan Province,Grant/Award Number:20241110011+1 种基金Special Funding for Basic Research Expenses for Central Government Departmentaffiliated Institutes,Grant/Award Number:HKYJBYW-2024-06The Open Foundation of the Yellow River Institute of Hydraulic Research,Grant/Award Number:LYBEPR202206。
文摘The Kuye River Basin has experienced a rapid depletion of groundwater due to the increased coal production.In this study,by introducing the empirical equations derived from the three zone theory in the coal mining industry in China as a boundary condition,a calculation model was developed by coupling the soil and water assessment tool and visual modular three-dimensional finite-difference ground-water flow model(SWAT-VISUAL MODFLOW).The model was applied to several coal mines in the basin to quantify the groundwater impact of underground mining.For illustration purposes,two underground water observation stations and one water level station were selected for groundwater change simulation in 2009,producing the results that agreed well with the observed data.We found that groundwater level was closely related to the height of the fractured water-conducting zone caused by underground mining,and a higher height led to a lower groundwater level.This finding was further supported by the calculation that underground mining was responsible for 23.20mm aquifer breakages in 2009.Thus,preventing surface subsidence due to underground mining can help protecting the basin's groundwater.
基金supported by the Natural Science Foundation of China(Grant Nos.42088101 and 42375163)the Guangdong Major Project of Basic and Applied Basic Research(Grant No.2021B0301030007)the specific research fund of The Innovation Platform for Academicians of Hainan Province(Grant No.YSPTZX202143)。
文摘In Earth system modeling,the land surface is coupled with the atmosphere through surface turbulent fluxes.These fluxes are computed using mean meteorological variables between the surface and a reference height in the atmosphere.However,the dependence of flux computation on the reference height,which is usually set as the lowest level in the atmosphere in Earth system models,has not received much attention.Based on high-resolution large-eddy simulation(LES)data under unstable conditions,we find the setting of reference height is not trivial within the framework of current surface layer theory.With a reasonable prescription of aerodynamic roughness length(following the setting in LESs),reference heights near the top of the surface layer tend to provide the best estimate of surface fluxes,especially for the momentum flux.Furthermore,this conclusion for the sensible heat flux is insensitive to the ratio of roughness length for momentum versus heat.These results are robust,whether using the classical or revised surface layer theory.They provide a potential guide for setting the proper reference heights for Earth system modeling and can be further tested in the near future using observational data from land–atmosphere feedback observatories.
基金financial supports from National Natural Science Foundation of China(No.61905051)Natural Science Foundation of Heilongjiang Province(No.LH2020F027).
文摘Periodic metal nanoarrays serving as cavities can support directional-tunable amplified spontaneous emission that goes beyond the diffraction limit due to the hybrid states of surface plasmons and Bloch surface waves.Most of these modes'interactions remain within the weak coupling regime,yet strong coupling is also anticipated to occur.In this work,we present an intriguing case of amplified spontaneous emission(ASE),amplified by the splitting upper polariton mode within a strong coupling system,stemming from a square lattice of plasmonic cone lattices(PCLs).The PCLs are fabricated using an anodized aluminum oxide membrane(AAO),which facilitates strong coupling between surface plasmons and Bloch surface wave modes,with the maximum Rabi splitting observed at 0.258 eV for the sample with an aspect ratio of 0.33.A 13.5-fold increase in amplified spontaneous emission is recorded when the emission from Nile Red coincides with this flat energy branch of upper polariton,which exhibits a high photon density of states.Reduced group velocity can prolong photon lifetime and boost the probability of light-matter interaction.The observed ASE phenomenon in this strong coupling plasmonic system widens the scope for applications in nanolasing and polariton lasing.
基金Supported by the National Natural Science Foundation of China(No.U22A20246)the Key Project of Natural Science Foundation of Hebei Province of China(Basic Research Base Project)(No.A2023210064)the Science and Technology Program of Hebei Province of China(Nos.246Z1904G and 225676162GH)。
文摘The vehicle-road coupling dynamics problem is a prominent issue in transportation,drawing significant attention in recent years.These dynamic equations are characterized by high-dimensionality,coupling,and time-varying dynamics,making the exact solutions challenging to obtain.As a result,numerical integration methods are typically employed.However,conventional methods often suffer from low computational efficiency.To address this,this paper explores the application of the parameter freezing precise exponential integrator to vehicle-road coupling models.The model accounts for road roughness irregularities,incorporating all terms unrelated to the linear part into the algorithm's inhomogeneous vector.The general construction process of the algorithm is detailed.The validity of numerical results is verified through approximate analytical solutions(AASs),and the advantages of this method over traditional numerical integration methods are demonstrated.Multiple parameter freezing precise exponential integrator schemes are constructed based on the Runge-Kutta framework,with the fourth-order four-stage scheme identified as the optimal one.The study indicates that this method can quickly and accurately capture the dynamic system's vibration response,offering a new,efficient approach for numerical studies of high-dimensional vehicle-road coupling systems.
基金Natural Science Foundation of Shanxi Province,China (Grant No. 20210302123001)DNL Cooperation Fund,CAS (DNL202004),ICC CAS (Grant No. SCJCWRW-2023-21)Key Research and Development Program of Shanxi Province (202202090301020)。
文摘Photoelectrocatalytic coupling CO_(2)and volatile organic compounds (VOCs) is a promising green strategy for the synergistic conversion of the two carbon-containing resources to C2products.The catalytic efficiency is always at the mercy of chemical inertness of CO_(2)and the competitive hydrogen evolution of H2O.Herein,a modified g-C_(3)N_(4)/ZnAl-LDH Z-scheme heterojunction catalyst with dual reaction site was rationally designed and precisely constructed.The Faraday efficiency of ethanol reached 68.67%with a corresponding formation rate of 227.3μmol g^(-1)h^(-1).As revealed by in-situ characterizations and density functional theory calculations,CO_(2)and HCHO were absorbed at Zn site and N site,respectively.Then,*CO generated from CO_(2)and HCHO was converted to*CH_(3)O and*CHO on the dual-active-site heterojunction.The detailed reaction mechanism experiments indicated that C–C coupling only occurred between*CO and*CH_(3)O in electrocatalysis process.Apart from the“*CO+*CH_(3)O”path,another“*CO+*CHO”coupling path was also detected in photoelectrocatalytic process.The selectivity of ethanol was significantly enhanced due to the synthesis of dual-site catalyst and the dual-path coupling path between CO_(2)and HCHO simultaneously driven by light and electricity.
基金Project supported by the National MCF Energy Research and Development Program(Grant No.2022YFE03190100)the National Natural Science Foundation of China(Grant Nos.12422513,12105035,and U21A20438)the Xiaomi Young Talents Program。
文摘The electromagnetic wave propagations and their coupling characteristics in magnetized plasma near the antenna of ion cyclotron range of frequencies(ICRF)is studied based on self-developed 3DFEM-IA code.This code effectively resolves the three-dimensional(3D)geometry and the electromagnetic field using the finite element method.Our findings reveal that the distributions of electromagnetic fields and energy flow density significantly depend on the antenna phases,surface current density on the antenna straps,and background plasma density.Notably,the non-uniform surface current density on the antenna straps,resulting from the presence of induced currents,contributes to a reduction in coupling power within the edge plasma.Furthermore,the calculated coupling impedance increases with plasma density,corroborating well with experimental measurements.
基金National Natural Science Foundation of China(U22B20149,22308376)Outstanding Young Scholars Foundation of China University of Petroleum(Beijing)(2462023BJRC015)Foundation of United Institute for Carbon Neutrality(CNIF20230209)。
文摘Dual atomic catalysts(DAC),particularly copper(Cu_(2))-based nitrogen(N)doped graphene,show great potential to effectively convert CO_(2)and nitrate(NO_(3)-)into important industrial chemicals such as ethylene,glycol,acetamide,and urea through an efficient catalytical process that involves C–C and C–N coupling.However,the origin of the coupling activity remained unclear,which substantially hinders the rational design of Cu-based catalysts for the N-integrated CO_(2)reduction reaction(CO_(2)RR).To address this challenge,this work performed advanced density functional theory calculations incorporating explicit solvation based on a Cu_(2)-based N-doped carbon(Cu_(2)N_(6)C_(10))catalyst for CO_(2)RR.These calculations are aimed to gain insight into the reaction mechanisms for the synthesis of ethylene,acetamide,and urea via coupling in the interfacial reaction micro-environment.Due to the sluggishness of CO_(2),the formation of a solvation electric layer by anions(F^(-),Cl^(-),Br^(-),and I^(-))and cations(Na+,Mg^(2+),K+,and Ca^(2+))leads to electron transfer towards the Cu surface.This process significantly accelerates the reduction of CO_(2).These results reveal that*CO intermediates play a pivotal role in N-integrated CO_(2)RR.Remarkably,the Cu_(2)-based N-doped carbon catalyst examined in this study has demonstrated the most potential for C–N coupling to date.Our findings reveal that through the process of a condensation reaction between*CO and NH_(2)OH for urea synthesis,*NO_(3)-is reduced to*NH_(3),and*CO_(2)to*CCO at dual Cu atom sites.This dual-site reduction facilitates the synthesis of acetamide through a nucleophilic reaction between NH_(3)and the ketene intermediate.Furthermore,we found that the I-and Mg^(2+)ions,influenced by pH,were highly effective for acetamide and ammonia synthesis,except when F-and Ca^(2+)were present.Furthermore,the mechanisms of C–N bond formation were investigated via ab-initio molecular dynamics simulations,and we found that adjusting the micro-environment can change the dominant side reaction,shifting from hydrogen production in acidic conditions to water reduction in alkaline ones.This study introduces a novel approach using ion-H_(2)O cages to significantly enhance the efficiency of C–N coupling reactions.
基金Supported by the National Natural Science Foundation of China(52374067)PetroChina Scientific Research and Technology Development Project(2021ZG12)PetroChina Technology Project(2023ZZ09).
文摘To address the challenges associated with existing separated zone oil production technologies,such as incompatibility with pump inspection operations,short effective working life,and poor communication reliability,an innovative electromagnetic coupling intelligent zonal oil production technology has been proposed.The core and accessory tools have been developed and applied in field tests.This technology employs a pipe string structure incorporation a release sub,which separates the production and allocation pipe strings.When the two strings are docked downhole,electromagnetic coupling enables close-range wireless transmission of electrical power and signals between the strings,powering multiple downhole intelligent production allocators(IPAs)and enabling two-way communication.Core tools adapted to the complex working conditions downhole were developed,including downhole electricity&signal transmission equipment based on electromagnetic coupling(EST),IPAs,and ground communication controllers(GCCs).Accessory tools,including large-diameter release sub anchor and cable-crossing packers,have also been technically finalized.Field tests conducted on ten wells in Daqing Oilfield demonstrated that the downhole docking of the two strings was convenient and reliable,and the EST worked stably.Real-time monitoring of flow rate,pressure and temperature in separate layers and regulation of zonal fluid production were also achieved.This technology has enhanced reservoir understanding and achieved practical production results of increased oil output with reduced water cut.
基金supported by the National Natural Science Foundation of China(U21A20331,81903743,22005322,22279151,and 22275004)National Science Fund for Distinguished Young Scholars(21925506).
文摘This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker electron-phonon coupling in perovskite has been achieved by introducing the structurally soft cyclohexane methylamine(CMA^(+))cation,which could serve as a damper to alleviate the mechanical stress caused by lattice oscillations,compared to the rigid phenethyl methylamine(PEA^(+))analog.It demonstrates a significantly lower non-radiative recombination rate,even though the two types of bulky cations have similar chemical passivation effects on perovskite,which might be explained by the suppressed carrier capture process and improved lattice geometry relaxation.The resulting PSCs achieve an exceptional power conversion efficiency(PCE)of 25.5%with a record-high opencircuit voltage(V_(OC))of 1.20 V for narrow bandgap perovskite(FAPbI_(3)).The established correlations between electron-phonon coupling and non-radiative decay provide design and screening criteria for more effective passivators for highly efficient PSCs approaching the Shockley-Queisser limit.
基金National Key Research and Development Program of China(2021YFC2902103)National Natural Science Foundation of China(51934001)Fundamental Research Funds for the Central Universities(2023JCCXLJ02).
文摘This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation in wall pressure of the blasting holes.Using DDNP explosive as the explosive load,blasting tests were conducted on red sandstone specimens with four different water coupling coefficients:1.20,1.33,1.50,and 2.00.The study examines the morphologies of the rock specimens after blasting under these different water coupling coefficients.Additionally,the fractal dimensions of the surface cracks resulting from the blasting were calculated to provide a quantitative evaluation of the extent of rock damage.CT scanning and 3D reconstruction were performed on the post-blasting specimens to visually depict the extent of damage and fractures within the rock.Additionally,the volume fractal dimension and damage degree of the post-blasting specimens are calculated.The findings are then combined with numerical simulation to facilitate auxiliary analysis.The results demonstrate that an increase in the water coupling coefficient leads to a reduction in the peak pressure on the hole wall and the crushing zone,enabling more of the explosion energy to be utilized for crack propagation following the explosion.The specimens exhibited distinct failure patterns,resulting in corresponding changes in fractal dimensions.The simulated pore wall pressure–time curve validated the derived theoretical results,whereas the stress cloud map and explosion energy-time curve demonstrated the buffering effect of the water medium.As the water coupling coefficient increases,the buffering effect of the water medium becomes increasingly prominent.
基金supported by the Australian Research Council (DP200101353)。
文摘Strong coupling between resonantly matched surface plasmons of metals and excitons of quantum emitters results in the formation of new plasmon-exciton hybridized energy states.In plasmon-exciton strong coupling,plasmonic nanocavities play a significant role due to their ability to confine light in an ultrasmall volume.Additionally,two-dimensional transition metal dichalcogenides(TMDCs) have a significant exciton binding energy and remain stable at ambient conditions,making them an excellent alternative for investigating light-matter interactions.As a result,strong plasmon-exciton coupling has been reported by introducing a single metallic cavity.However,single nanoparticles have lower spatial confinement of electromagnetic fields and limited tunability to match the excitonic resonance.Here,we introduce the concept of catenary-shaped optical fields induced by plasmonic metamaterial cavities to scale the strength of plasmon-exciton coupling.The demonstrated plasmon modes of metallic metamaterial cavities offer high confinement and tunability and can match with the excitons of TMDCs to exhibit a strong coupling regime by tuning either the size of the cavity gap or thickness.The calculated Rabi splitting of Au-MoSe_2 and Au-WSe_2 heterostructures strongly depends on the catenary-like field enhancement induced by the Au cavity,resulting in room-temperature Rabi splitting ranging between 77.86 and 320 me V.These plasmonic metamaterial cavities can pave the way for manipulating excitons in TMDCs and operating active nanophotonic devices at ambient temperature.
基金the National Natural Science Foundation of China(22265021)the Aeronautical Science Foundation of China(2020Z056056003).
文摘Metal–organic gel(MOG)derived composites are promising multi-functional materials due to their alterable composition,identifiable chemical homogeneity,tunable shape,and porous structure.Herein,stable metal–organic hydrogels are prepared by regulating the complexation effect,solution polarity and curing speed.Meanwhile,collagen peptide is used to facilitate the fabrication of a porous aerogel with excellent physical properties as well as the homogeneous dispersion of magnetic particles during calcination.Subsequently,two kinds of heterometallic magnetic coupling systems are obtained through the application of Kirkendall effect.FeCo/nitrogen-doped carbon(NC)aerogel demonstrates an ultra-strong microwave absorption of−85 dB at an ultra-low loading of 5%.After reducing the time taken by atom shifting,a FeCo/Fe3O4/NC aerogel containing virus-shaped particles is obtained,which achieves an ultra-broad absorption of 7.44 GHz at an ultra-thin thickness of 1.59 mm due to the coupling effect offered by dual-soft-magnetic particles.Furthermore,both aerogels show excellent thermal insulation property,and their outstanding radar stealth performances in J-20 aircraft are confirmed by computer simulation technology.The formation mechanism of MOG is also discussed along with the thermal insulation and electromagnetic wave absorption mechanism of the aerogels,which will enable the development and application of novel and lightweight stealth coatings.
基金jointly supported by the National Key Research and Development Program of China (2019YFC1905800)the National Key Research & Development Program of China (2018YFC1903500)+4 种基金the commercial project by Beijing Zhong Dian Hua Yuan Environment Protection Technology Co., Ltd. (E01211200005)the Regional key projects of the science and technology service network program (STS program) of the Chinese Academy of Sciences (KFJ-STS-QYZD-153)the Ningbo Science and Technology Innovation Key Projects (2020Z099, 2022Z028)the Ningbo Municipal Commonweal Key Program (2019C10033)the support of Mineral Resources Analytical and Testing Center, Institute of Process Engineering, Chinese Academy of Science
文摘To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study investigates the features of P and F in PG,and explores the decomposition of PF using hydrofluoric acid(HF)in the sulfuric acid system for K leaching and leaching of P and F in PG.The impact factors such as sulfuric acid concentration,reaction temperature,reaction time,material ratio(PG/PF),liquid–solid ratio,PF particle size,and PF calcination temperature on the leaching of P and K is systematically investigated in this paper.The results show that under optimal conditions,the leaching rate of K and P reach more than 93%and 96%,respectively.Kinetics study using shrinking core model(SCM)indicates two significant stages with internal diffusion predominantly controlling the leaching of K.The apparent activation energies of these two stages are 11.92 kJ·mol^(-1)and 11.55 kJ·mol^(-1),respectively.
