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Controllable Crystallization Optimizes Thermal Stability of A Novel Red-emitting Phosphor in Self-reduction System
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作者 LU Shiwei DONG Rui +5 位作者 BAI Yuxing DU Haihong ZHENG Lirong WU Li KONG Yongfa XU Jingjun 《发光学报》 北大核心 2025年第2期285-295,共11页
Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significan... Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significance for the high-quality illumination of phosphor-converted WLEDs.Here,a novel red-emitting phosphor K_(2)Zn(PO_(3))_(4)∶Mn^(2+)is synthesized by standard high temperature solid state reaction in ambient atmosphere,which is a new member of self-reduction system.An effective synthesis strategy is proposed to optimize its photoluminescent performances.Combined with X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy,oxygen vacancy defects introduced by Mn doping are proved to play an important role in the transition of Mn^(4+)→Mn^(2+).Thermoluminescence analysis reveals that the distribution of trap levels,especially the deep ones,is effectively regulated by the controllable crystallization and significantly affect the thermal stability of phosphors.Then a defect-assisted model is proposed to address the inner mechanism of the phenomenon.The carriers trapped by deep trap levels can be released under the high-temperature stimulus,which return back to the luminescent centers and participate in the radiative recombination to improve thermal stability.This study provides a new crystallographic idea and theoretical support for obtaining luminescent materials with high thermal stability. 展开更多
关键词 photoluminescence lattice defects self-reduction thermal stability
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Impact of Single-Phase Automatic Recloser of Critical Transmission Line on the Stability of the Power Transmission Network
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作者 Chuulan Natsagdorj Ganbat Gantamir Erdenebileg Doljinsuren 《Journal of Power and Energy Engineering》 2025年第2期43-56,共14页
In order to increase the stability of the Mongolia power system, a single-phase automatic reclosing device (SPAR) was introduced on double-circuit power lines built with a size of 330 kV, operating on a voltage of 220... In order to increase the stability of the Mongolia power system, a single-phase automatic reclosing device (SPAR) was introduced on double-circuit power lines built with a size of 330 kV, operating on a voltage of 220 kV and a length of 250 km. These overhead power lines (L-213, L-214) connect the 220/110/35 kV “Songino” substation with the “Mandal” substation and form system networks. This paper presents the challenges encountered when implementing single-phase automatic reclosing (SPAR) devices and compares the changes in power system parameters before and after SPAR deployment for a long 220 kV line. Simulations and analyses were carried out using DIgSILENT PowerFactory software, focusing on rotor angle stability, and the overall impact on the power system during short-circuit faults. The evaluation also utilized measurement data from the Wide Area Monitoring System (WAMS) to compare system behavior pre- and post-implementation of SPAR. The findings reveal that SPAR significantly enhances system reliability and stability, effectively mitigating the risk of oscillations and stability loss triggered by short circuits. This improvement contributes to a more resilient power system, reducing the potential for disturbances caused by faults. 展开更多
关键词 Automatic Reclosing Single-Phase Automatic Reclosing Relay Protection Overhead Power Lines System stability Rotor Angle stability
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Advancing Material Stability Prediction: Leveraging Machine Learning and High-Dimensional Data for Improved Accuracy
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作者 Aasim Ayaz Wani 《Materials Sciences and Applications》 2025年第2期79-105,共27页
Predicting the material stability is essential for accelerating the discovery of advanced materials in renewable energy, aerospace, and catalysis. Traditional approaches, such as Density Functional Theory (DFT), are a... Predicting the material stability is essential for accelerating the discovery of advanced materials in renewable energy, aerospace, and catalysis. Traditional approaches, such as Density Functional Theory (DFT), are accurate but computationally expensive and unsuitable for high-throughput screening. This study introduces a machine learning (ML) framework trained on high-dimensional data from the Open Quantum Materials Database (OQMD) to predict formation energy, a key stability metric. Among the evaluated models, deep learning outperformed Gradient Boosting Machines and Random Forest, achieving up to 0.88 R2 prediction accuracy. Feature importance analysis identified thermodynamic, electronic, and structural properties as the primary drivers of stability, offering interpretable insights into material behavior. Compared to DFT, the proposed ML framework significantly reduces computational costs, enabling the rapid screening of thousands of compounds. These results highlight ML’s transformative potential in materials discovery, with direct applications in energy storage, semiconductors, and catalysis. 展开更多
关键词 High-Throughput Screening for Material Discovery Machine Learning Data-Driven Structural stability Analysis AI for Chemical Space Exploration Interpretable ML Models for Material stability Thermodynamic Property Prediction Using AI
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Full Use of Hydrogeological-Geomechanical Parameters for 3d Stability Analysis in an Open-Pit Iron Mine with Complex Geometry
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作者 Vidal Félix Navarro Torres 《Journal of Geoscience and Environment Protection》 2025年第2期136-160,共25页
This study presents a novel method to evaluate the safety of open-pit slopes by means of three-dimensional numerical modeling with the finite difference method. The method presented here uses a block model as a vehicl... This study presents a novel method to evaluate the safety of open-pit slopes by means of three-dimensional numerical modeling with the finite difference method. The method presented here uses a block model as a vehicle to carry relevant information from the rock mass and automatically construct the numerical model. The results suggest that the method is promising because of its capacity to accurately incorporate a large amount of high-complexity rock data by considering spatial location and material behavior. It is expected that the innovations in this method will make the design, construction, and operation of open-pit iron mines safer and more economical. 展开更多
关键词 Open-Pit Mine HYDROGEOLOGY GEOMECHANICS Numerical Modeling Finite Difference Method 3D Slope stability
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Stability Analysis of a Floating Multirobot Coordinated Towing System Based on the Stability Cone Method
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作者 Xiangtang Zhao Zhigang Zhao +1 位作者 Cheng Su Jiadong Meng 《哈尔滨工程大学学报(英文版)》 2025年第2期449-457,共9页
Currently,the cranes used at sea do not have enough flexibility,efficiency,and safety.Thus,this study proposed a floating multirobot coordinated towing system to meet the demands for offshore towing.Because of the fle... Currently,the cranes used at sea do not have enough flexibility,efficiency,and safety.Thus,this study proposed a floating multirobot coordinated towing system to meet the demands for offshore towing.Because of the flexibility of rope-driven robots,the one-way pulling characteristics of the rope,and the floating characteristics of the base,towing robots are easily overturned.First,the spatial configuration of the towing system was established according to the towing task,and the kinematic model of the towing system was established using the coordinate transformation.Then,the dynamic model of the towing system was established according to the rigid-body dynamics and hydrodynamic theory.Finally,the stability of the towing system was analyzed using the stability cone method.The simulation experiments provide a reference for the practical application of the floating multirobot coordinated towing system,which can improve the stability of towing systems by changing the configuration of the towing robot. 展开更多
关键词 Offshore towing Kinematic model Dynamic model stability cone method stability
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Effect of external and internal cues on core muscle activation during the Sahrmann five-level core stability test
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作者 Skyla Stifter Jessie McCaffrey +2 位作者 Tyler Nichols Ayse Ozcan Edeer Justine Ward 《World Journal of Methodology》 2025年第1期95-104,共10页
BACKGROUND Pain in the back or pelvis or fear of back pain may affect the timing or cocontraction of the core muscles.In both static and dynamic movements,the Sahrmann core stability test provides an assessment of cor... BACKGROUND Pain in the back or pelvis or fear of back pain may affect the timing or cocontraction of the core muscles.In both static and dynamic movements,the Sahrmann core stability test provides an assessment of core muscle activation and a person's ability to stabilize the lumbopelvic complex.Preparatory cues and images can be used to increase the activation of these muscles.To attain optimal movement patterns,it will be necessary to determine what cueing will give the most effective results for core stability.AIM To investigate the effects of external and internal cues on core muscle activation during the Sahrmann five-level core stability test.METHODS Total 68 participants(21.83±3.47 years)were randomly allocated to an external(n=35)or internal cue group(n=33).Participants performed the Sahrmann fivelevel core stability test without a cue as baseline and the five-level stability exercises with an internal or external cue.External cue group received a pressure biofeedback unit(PBU),and the internal cue group received an audio cue.A Delsys Trigno^(TM)surface electromyography unit was used for muscle activation from the rectus abdominis,external oblique,and transverse abdominis/internal oblique muscles.RESULTS Linear mixed effects model analysis showed that cueing had a significant effect on core muscle activation(P=0.001);however,there was no significant difference between cue types(internal or external)(P=0.130).CONCLUSION Both external and internal cueing have significant effects on core muscle activation during the Sahrmann five-level core stability test and the PBU does not create higher muscle activation than internal cueing. 展开更多
关键词 External cue Internal cue Muscle activation Core muscles Lumbopelvic stability Pressure biofeedback unit
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Correction: Silencing of the long non-coding RNA LINC00265triggers autophagy and apoptosis in lung cancer by reducingprotein stability of SIN3A oncogene
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作者 XIAOBI HUANG CHUNYUAN CHEN +9 位作者 YONGYANG CHEN HONGLIAN ZHOU YONGHUA CHEN ZHONG HUANG YULIU XIE BAIYANG LIU YUDONG GUO ZHIXIONG YANG GUANGHUA CHEN WENMEI SU 《Oncology Research》 2025年第5期1249-1250,共2页
In the article“Silencing of the long non-coding RNA LINC00265 triggers autophagy and apoptosis in lung cancer by reducing protein stability of SIN3A oncogene”(Oncology Research.2024,Vol.32,No.7,pp.1185–1195.doi:10.... In the article“Silencing of the long non-coding RNA LINC00265 triggers autophagy and apoptosis in lung cancer by reducing protein stability of SIN3A oncogene”(Oncology Research.2024,Vol.32,No.7,pp.1185–1195.doi:10.32604/or.2023.030771,https://www.techscience.com/or/v32n7/57163),an inadvertent error occurred during the compilation of Fig.3H.This needed corrections to ensure the accuracy and integrity of the data presented. 展开更多
关键词 lung cancer long non coding RNA reducing protein stability sin oncogene oncology AUTOPHAGY protein stability APOPTOSIS accuracy integrity SILENCING
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Recent progress on stability and applications of flexible perovskite photodetectors
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作者 Ying Hu Qianpeng Zhang +9 位作者 Junchao Han Xinxin Lian Hualiang Lv Yu Pei Siqing Shen Yongli Liang Hao Hu Meng Chen Xiaoliang Mo Junhao Chu 《Journal of Semiconductors》 2025年第1期5-19,共15页
Flexible photodetectors have garnered significant attention by virtue of their potential applications in environmental monitoring,wearable healthcare,imaging sensing,and portable optical communications.Perovskites sta... Flexible photodetectors have garnered significant attention by virtue of their potential applications in environmental monitoring,wearable healthcare,imaging sensing,and portable optical communications.Perovskites stand out as particularly promising materials for photodetectors,offering exceptional optoelectronic properties,tunable band gaps,low-temperature solution processing,and notable mechanical flexibility.In this review,we explore the latest progress in flexible perovskite photodetectors,emphasizing the strategies developed for photoactive materials and device structures to enhance optoelectronic performance and stability.Additionally,we discuss typical applications of these devices and offer insights into future directions and potential applications. 展开更多
关键词 PEROVSKITE flexible photodetector stability versatile applications
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Relationship between plant diversity and community stability in alpine mining areas
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作者 LIU Qingqing SHI Jianjun +5 位作者 MA Yushou WANG Yanlong WANG Xiaoli LYU Liangyu HE Miaohua CAI Zongcheng 《Journal of Mountain Science》 2025年第3期901-912,共12页
Plant diversity plays a crucial role in maintaining the stability of ecological function.Based on field investigations and experimental analyses,artificial grassland plots with varying sowing times,adjacent natural gr... Plant diversity plays a crucial role in maintaining the stability of ecological function.Based on field investigations and experimental analyses,artificial grassland plots with varying sowing times,adjacent natural grassland(CK),and open-pit coal mine dumps in the Muli mining area of Qinghai Province were selected as research subjects for this study.The characteristics of plant diversity and community stability were measured and analyzed,and the relationships between these factors and their influencing variables were evaluated.The results indicated significant differences in the vegetation community characteristics and plant diversity among the various grasslands.Coverage,aboveground biomass,belowground biomass,soil total nitrogen,and soil total carbon were the highest when the growth period was three years.Plant diversity and community stability in the natural grassland were significantly greater than that in the artificial grassland and open-pit coal mine dumps.A significant positive correlation was observed between plant diversity and community stability,suggesting that plant diversity can serve as an index of community stability.The order of stability,from highest to lowest,was CK>11a>10a>8a>9a>6a>7a>3a>2a>1a>0a.Years were identified as the primary factors affecting plant diversity and community stability by altering the soil pH.These results elucidate the relationships and driving mechanisms between plant diversity and community stability in grasslands,providing a scientific basis for maintaining community stability in artificial grassland ecosystems in alpine mining areas. 展开更多
关键词 ALPINE Muli Plant diversity Community stability RESTORATION
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3D Computational Modeling and Stability Analysis of Highway Slope:A Case Study from the X104 Section in Ganxian County
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作者 Fujie Dai Yiwen Jin +1 位作者 Yongliang Wang Jiajun Li 《Journal of Electronic Research and Application》 2025年第2期65-68,共4页
Highway planning requires geological surveys and stability analysis of the surrounding area.In the early stage of the survey,the modeling and stability analysis of the survey area can be carried out by using GIS softw... Highway planning requires geological surveys and stability analysis of the surrounding area.In the early stage of the survey,the modeling and stability analysis of the survey area can be carried out by using GIS software to intuitively understand the topography of the study area.The use of DEM to extract terrain factors can be used for simple stability analysis and the source data is easy to obtain,simple to operate,fast to analyze,and reliable analysis results.In this paper,taking the X104 road section in Ganxian County as an example,the ArcGIS platform is used to carry out 3D modeling visualization and stability analysis,and the stability evaluation map of the study area is obtained. 展开更多
关键词 3D modeling stability GIS Highway planning
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STABILITY OF THE ISOPERIMETRIC INEQUALITY IN HYPERBOLIC PLANE
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作者 Haizhong LI Yao WAN 《Acta Mathematica Scientia》 2025年第1期215-227,共13页
In this paper,we establish a stability estimate for the isoperimetric inequality of horospherically convex domains in hyperbolic plane.This estimate involves a relationship between the Hausdorff distance to a geodesic... In this paper,we establish a stability estimate for the isoperimetric inequality of horospherically convex domains in hyperbolic plane.This estimate involves a relationship between the Hausdorff distance to a geodesic ball and the deficit in the isoperimetric inequality,where the coefficient of the deficit is a universal constant. 展开更多
关键词 stability isoperimetric inequality hyperbolic plane Hausdorff distance
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A transient stability assessment method for power systems incorporating residual networks and BiGRU-attention
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作者 Shan Cheng Qiping Xu +3 位作者 Haidong Wang Zihao Yu Rui Wang Tao Ran 《Global Energy Interconnection》 2025年第1期143-159,共17页
The traditional transient stability assessment(TSA)model for power systems has three disadvantages:capturing critical information during faults is difficult,aperiodic and oscillatory unstable conditions are not distin... The traditional transient stability assessment(TSA)model for power systems has three disadvantages:capturing critical information during faults is difficult,aperiodic and oscillatory unstable conditions are not distinguished,and poor generalizability is exhibited by systems with high renewable energy penetration.To address these issues,a novel ResGRU architecture for TSA is proposed in this study.First,a residual neural network(ResNet)is used for deep feature extraction of transient information.Second,a bidirectional gated recurrent unit combined with a multi-attention mechanism(BiGRU-Attention)is used to establish temporal feature dependencies.Their combination constitutes a TSA framework based on the ResGRU architecture.This method predicts three transient conditions:oscillatory instability,aperiodic instability,and stability.The model was trained offline using stochastic gradient descent with a thermal restart(SGDR)optimization algorithm in the offline training phase.This significantly improves the generalizability of the model.Finally,simulation tests on IEEE 145-bus and 39-bus systems confirmed that the proposed method has higher adaptability,accuracy,scalability,and rapidity than the conventional TSA approach.The proposed model also has superior robustness for PMU incomplete configurations,PMU noisy data,and packet loss. 展开更多
关键词 Transient stability assessment Aperiodic instability Oscillatory instability ResGRU SGDR
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Research Progress on the Process Optimization and Stability Improvement of Third-generation Cephalosporins
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作者 Hao LIU Yanxi LAI +1 位作者 Shengjiu GU Kaimei ZHU 《Medicinal Plant》 2025年第1期23-26,共4页
The latest progress in the process optimization and stability improvement of third-generation cephalosporins in recent years was reviewed.The introduction of green chemistry,enzyme catalysis,nanotechnology,lyophilizat... The latest progress in the process optimization and stability improvement of third-generation cephalosporins in recent years was reviewed.The introduction of green chemistry,enzyme catalysis,nanotechnology,lyophilization,and nitrogen-filled packaging technologies can only improve production efficiency and reduce the generation of by-products,but also significantly extend the shelf life of drugs.In the future,process automation and intelligent technology will further optimize the large-scale production process,and the combination of nanotechnology and precision drug delivery will promote the improvement of effect in clinical applications. 展开更多
关键词 Third-generation cephalosporins Process optimization NANOTECHNOLOGY Green chemistry Drug stability
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Assessing ground stability of a vertical backfilled stope considering creep behaviors of surrounding rocks
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作者 Ruofan Wang Lang Liu +4 位作者 Mengbo Zhu Huafu Qiu Bingbing Tu Huisheng Qu Hao Cui 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第1期187-199,共13页
Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the st... Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the stress development within the backfill material,leaving the influence of stope backfilling on stress distribution in surrounding rock mass and ground stability largely unexplored.Therefore,this paper presents numerical models in FLAC3D to investigate,for the first time,the time-dependent stress redistribution around a vertical backfilled stope and its implications on ground stability,considering the creep of surrounding rock mass.Using the Soft Soil constitutive model,the compressibility of backfill under large pressure was captured.It is found that the creep deformation of rock mass exercises compression on backfill and results in a less void ratio and increased modulus for fill material.The compacted backfill conversely influenced the stress distribution and ground stability of rock mass which was a combined effect of wall creep and compressibility of backfill.With the increase of time or/and creep deformation,the minimum principal stress in the rocks surrounding the backfilled stope increased towards the pre-mining stress state,while the deviatoric stress reduces leading to an increased factor of safety and improved ground stability.This improvement effect of backfill on ground stability increased with the increase of mine depth and stope height,while it is also more pronounced for the narrow stope,the backfill with a smaller compression index,and the soft rocks with a smaller viscosity coefficient.Furthermore,the results emphasize the importance of minimizing empty time and backfilling extracted stope as soon as possible for ground control.Reduction of filling gap height enhances the local stability around the roof of stope. 展开更多
关键词 Ground stability Time dependency CREEP Surrounding rocks Backfilled stope
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Review of Research on Underwater Explosions Related to Ship Damage and Stability
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作者 Ruiyao Zhang Wei Xiao +1 位作者 Xiongliang Yao Xiaochao Zou 《哈尔滨工程大学学报(英文版)》 2025年第2期285-300,共16页
Researchers have achieved notable advancements over the years in exploring ship damage and stability resulting from underwater explosions(UNDEX).However,numerous challenges and open questions remain in this field.In t... Researchers have achieved notable advancements over the years in exploring ship damage and stability resulting from underwater explosions(UNDEX).However,numerous challenges and open questions remain in this field.In this study,the research progress of UNDEX load is first reviewed,which covers the explosion load during the shock wave and bubble pulsation stages.Subsequently,the research progress of ship damage caused by UNDEX is reviewed from two aspects:contact explosion and noncontact explosion.Finally,the research progress of ship navigation stability caused by UNDEX is reviewed from three aspects:natural factors,ship’s internal factors,and explosion factors.Analysis reveals that most existing research has focused on the damage to displacement ships caused by UNDEX.Meanwhile,less attention has been paid to the damage and stability of non-displacement ships caused by UNDEX,which are worthy of discussion. 展开更多
关键词 Underwater explosion Load characteristics Structural damage stability Non-displacement ships
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Improve Strategy for Transient Power Angle Stability Control of VSG Combining Frequency Difference Feedback and Virtual Impedance
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作者 Dianlang Wang Qi Yin +3 位作者 Haifeng Wang Jing Chen Hong Miao Yihan Chen 《Energy Engineering》 2025年第2期651-666,共16页
As the penetration rate of distributed energy increases,the transient power angle stability problem of the virtual synchronous generator(VSG)has gradually become prominent.In view of the situation that the grid impeda... As the penetration rate of distributed energy increases,the transient power angle stability problem of the virtual synchronous generator(VSG)has gradually become prominent.In view of the situation that the grid impedance ratio(R/X)is high and affects the transient power angle stability of VSG,this paper proposes a VSG transient power angle stability control strategy based on the combination of frequency difference feedback and virtual impedance.To improve the transient power angle stability of the VSG,a virtual impedance is adopted in the voltage loop to adjust the impedance ratio R/X;and the PI control feedback of the VSG frequency difference is introduced in the reactive powervoltage link of theVSGto enhance the damping effect.Thesecond-orderVSGdynamic nonlinearmodel considering the reactive power-voltage loop is established and the influence of different proportional integral(PI)control parameters on the system balance stability is analyzed.Moreover,the impact of the impedance ratio R/X on the transient power angle stability is presented using the equal area criterion.In the simulations,during the voltage dips with the reduction of R/X from 1.6 to 0.8,Δδ_(1)is reduced from 0.194 rad to 0.072 rad,Δf_(1)is reduced from 0.170 to 0.093 Hz,which shows better transient power angle stability.Simulation results verify that compared with traditional VSG,the proposedmethod can effectively improve the transient power angle stability of the system. 展开更多
关键词 Transient synchronous stability virtual synchronous generator impedance ratio
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Study on Preparation and Storage Stability of Camellia Oil-based Gel Oil
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作者 Benyin YAO Xinyu LU +5 位作者 Lina WU Haiping ZHAO Guifang CHEN Wenjing DONG Jianfeng ZHAN Weixin WANG 《Agricultural Biotechnology》 2025年第1期19-24,共6页
[Objectives]This study was conducted to investigate the optimal preparation conditions and storage stability of camellia oil-based gel oil.[Methods]With camellia oil as the base oil,rice bran wax and monoglyceride as ... [Objectives]This study was conducted to investigate the optimal preparation conditions and storage stability of camellia oil-based gel oil.[Methods]With camellia oil as the base oil,rice bran wax and monoglyceride as gelling agents,a kind of composite gel oil was prepared by the direct gel method.The effects of different mass ratios of rice bran wax to monoglyceride,amounts of gelling agent,heating time and temperatures on the oil precipitation rate and hardness of gel oil were investigated.The optimal preparation conditions were determined by a response surface optimization experiment,and the storage stability of the prepared gel oil was studied with peroxide value and acid value as evaluation indexes.[Results]The results showed that the optimal preparation process of gel oil was as follows:mass ratio of rice bran wax to monoglyceride 2:8,addition amount of rice bran wax and monoglyceride 10%,heating temperature 95℃,and heating time 49 min.The peroxide value and acid value of composite gel oil stored at 4℃and room temperature for 5 weeks both showed an upward trend,and the acid value of gel oil differed significantly at different storage temperatures,which showed that the cold storage environment was more suitable for the gel oil.Compared with the gel oil prepared by single gelling agent,the camellia oil-based gel oil prepared by compounding rice bran wax and monoglyceride had lower oil precipitation rate and moderate hardness.[Conclusions]This study lays a theoretical foundation for developing new gel oil and expanding the application scope of camellia oil. 展开更多
关键词 Rice bran wax MONOGLYCERIDE Camellia oil Response surface Storage stability
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A novel carbon-induced-porosity mechanism for improved cycling stability of magnesium hydride
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作者 Shuaijun Ding Yuqing Qiao +7 位作者 Xuecheng Cai Hongchao Wang Xun Shen Lidong Xu Yixuan Wen Fenglong Jiang Wei Zhou Tongde Shen 《Journal of Magnesium and Alloys》 2025年第3期1341-1352,共12页
MgH2 has been extensively studied as one of the most ideal solid hydrogen storage materials.Nevertheless,rapid capacity decay and sluggish hydrogen storage kinetics hamper its practical application.Herein,a Ni/C nano-... MgH2 has been extensively studied as one of the most ideal solid hydrogen storage materials.Nevertheless,rapid capacity decay and sluggish hydrogen storage kinetics hamper its practical application.Herein,a Ni/C nano-catalyst doped MgH2(MgH2–Ni/C)shows an improved hydrogen absorption kinetics with largely reduced activation energy.Particularly,the MgH2–Ni/C displays remarkable cycling stability,which maintains a high capacity of 6.01 wt.%(98.8%of initial capacity)even after 50 full hydrogen ab/desorption cycles,while the undoped MgH2 counterpart retains only 85.2%of its initial capacity.Detailed microstructure characterizations clearly reveal that particle sintering/growth accounts primarily for the deterioration of cycling performance of undoped MgH2.By comparison,MgH2–Ni/C can maintain a stable particle size with a growing porous structure during long-term cycling,which effectively increases the specific surface of the particles.A novel carbon-induced-porosity stabilization mechanism is proposed,which can stabilize the proportion of rapid hydrogen absorption process,thus dominating the excellent cycling performance of MgH2–Ni/C.This study provides new insights into the cycling stability mechanism of carbon-containing Mg-based hydrogen storage materials,thus promoting their practical applications. 展开更多
关键词 Hydrogen storage materials Magnesium hydride Cycling properties Particle stability Carbon-induced-porosity
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Heavy metal stress strengthens the stability and complexity of microbial molecular ecological networks in Sanyang wetland sediments
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作者 Shengwei WU Huixi ZOU +2 位作者 Nan LI Xiufeng YAN Wen LIU 《Journal of Oceanology and Limnology》 2025年第1期103-118,共16页
Pollution from heavy metals(HMs)(Cd,As,Cr,and Ni,etc.)has become a serious environmental issue in urban wetland ecosystems with more and more attention.Previous studies conducted in agricultural soils,rivers,and lakes... Pollution from heavy metals(HMs)(Cd,As,Cr,and Ni,etc.)has become a serious environmental issue in urban wetland ecosystems with more and more attention.Previous studies conducted in agricultural soils,rivers,and lakes demonstrated that microbial communities exhibit a response to HM pollution.Yet,little is known about the response of microbial communities to HM pollution in urban wetland ecosystems.We examined how heavy metals affect the stability of the microbial networks in the sediments of Sanyang wetland,Wenzhou,China.Key environmental parameters,including HMs,TC(total carbon),TN(total nitrogen),TP(total phosphorus),S,and pH,varied profoundly between moderately and heavily polluted areas in shaping microbial communities.Specifically,the microbial community composition in moderately polluted sites correlated significantly(P<0.05)with Ni,Cu,Cd and TP,whereas in heavily polluted sites,they correlated significantly with Cd,TN,TP,and S.Results show that the heavily polluted sites demonstrated more intricate and more stable microbial networks than those of the moderately polluted area.The heavily polluted sites exhibited higher values for various network parameters including total nodes,total links,average degree,average clustering coefficient,connectance,relative modularity,robustness,and cohesion.Moreover,the structural equation modeling analysis demonstrated a positive correlation between the stability of microbial networks and Cd,TN,TP,and S in heavily polluted sites.Conversely,in moderately polluted sites,the correlation was positively linked to Cd,Ni,and sediment pH.It implies that Cd could potentially play a crucial role in affecting the stability of microbial networks.This study shall enhance our comprehension of microbial co-occurrence patterns in urban wetland ecosystems and offer insights into the ways in which microbial communities respond to environmental factors in varying levels of HM pollution. 展开更多
关键词 heavy metal(HM) urban wetland microbial networks network stability
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Inhibiting irreversible Zn^(2+)/H^(+)co-insertion chemistry in aqueous zinc-MoO_(x)batteries for enhanced capacity stability
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作者 Chen Zheng Xinwei Guan +5 位作者 Zihang Huang Shuai Mao Xu Han Xiaoguang Duan Hui Li Tianyi Ma 《Journal of Energy Chemistry》 2025年第3期98-106,共9页
Rechargeable aqueous Zn-MoO_(x)batteries are promising energy storage devices with high theoretical specific capacity and low cost.However,MoO_(3)cathodes suffer drastic capacity decay during the initial discharging/c... Rechargeable aqueous Zn-MoO_(x)batteries are promising energy storage devices with high theoretical specific capacity and low cost.However,MoO_(3)cathodes suffer drastic capacity decay during the initial discharging/charging process in conventional electrolytes,resulting in a short cycle life and challenging the development of Zn-MoO_(x)batteries.Here we comprehensively investigate the dissolution mechanism of MoO_(3)cathodes and innovatively introduce a polymer to inhibit the irreversible processes.Our findings reveal that this capacity decay originates from the irreversible Zn^(2+)/H^(+)co-intercalation/extraction process in aqueous electrolytes.Even worse,during Zn^(2+)intercalation,the formed Zn_(x)MoO_(3-x)intermediate phase with lower valence states(Mo^(5+)/Mo^(4+))experiences severe dissolution in aqueous environments.To address these challenges,we developed a first instance of coating a polyaniline(PANI)shell around the MoO_(3)nanorod effectively inhibiting these irreversible processes and protecting structural integrity during long-term cycling.Detailed structural analysis and theoretical calculations indicate that=N-groups in PANI@MoO_(3-x)simultaneously weaken H+adsorption and enhance Zn^(2+)adsorption,which endowed the PANI@MoO_(3-x)cathode with reversible Zn^(2+)/H^(+)intercalation/extraction.Consequently,the obtained PANI@MoO_(3-x)cathode delivers an excellent discharge capacity of 316.86 mA h g^(-1)at 0.1 A g^(-1)and prolonged cycling stability of 75.49%capacity retention after 1000 cycles at 5 A g^(-1).This work addresses the critical issues associated with MoO_(3)cathodes and significantly advances the understanding of competitive multi-ion energy storage mechanisms in aqueous Zn-MoO_(3)batteries. 展开更多
关键词 Co-insertion chemistry Surface modification engineering Molybdenum oxide Cycling stability Aqueous zincbattery
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