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Effect of two-step solid solution on microstructure andδphase precipitation of Inconel 718 alloy
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作者 Enyu Liu Qingshuang Ma +5 位作者 Xintong Li Aoxue Gao Jing Bai Liming Yu Qiuzhi Gao Huijun Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第10期2199-2207,共9页
Inconel 718 is the most popular nickel-based superalloy and is extensively used in aerospace,automotive,and energy indus-tries owing to its extraordinary thermomechanical properties.The effects of different two-step s... Inconel 718 is the most popular nickel-based superalloy and is extensively used in aerospace,automotive,and energy indus-tries owing to its extraordinary thermomechanical properties.The effects of different two-step solid solution treatments on microstructure andδphase precipitation of Inconel 718 alloy were studied,and the transformation mechanism fromγ″metastable phase toδphase was clarified.The precipitates were statistically analyzed by X-ray diffractometry.The results show that theδphase content firstly increased,and then decreased with the temperature of the second-step solid solution.The changes in microstructure andδphase were studied by scanning electron microscopy and transmission electron microscopy.An intragranularδphase formed in Inconel 718 alloy at the second-[100]_(δ)[011]γ step solid solution temperature of 925℃,and its orientation relationship withγmatrix was determined as//and(010)_(δ)//(111)γ.Furthermore,the Vickers hardness of different heat treatment samples was measured,and the sample treated by second-step solid solution at 1010℃ reached the maximum hardness of HV 446.84. 展开更多
关键词 Inconel 718 alloy two-step solid solution treatment δphase γ″-δtransformation
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Kangfuxin solution alleviates esophageal stenosis after endoscopic submucosal dissection:A natural ingredient strategy
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作者 Xin Zhou Dan Ma +7 位作者 Yi-Xiang He Jing Jin Hong-Lian Wang Yun-Feng Wang Fan Yang Jian-Qin Liu Jie Chen Zhi Li 《World Journal of Gastroenterology》 SCIE CAS 2025年第1期110-125,共16页
BACKGROUND Esophageal stricture ranks among the most significant complications following endoscopic submucosal dissection(ESD).Excessive fibrotic repair is a typical pathological feature leading to stenosis after ESD.... BACKGROUND Esophageal stricture ranks among the most significant complications following endoscopic submucosal dissection(ESD).Excessive fibrotic repair is a typical pathological feature leading to stenosis after ESD.AIM To examine the effectiveness and underlying mechanism of Kangfuxin solution(KFX)in mitigating excessive fibrotic repair of the esophagus post-ESD.METHODS Pigs received KFX at 0.74 mL/kg/d for 21 days after esophageal full circumferential ESD.Endoscopic examinations occurred on days 7 and 21 post-ESD.In vitro,recombinant transforming growth factor(TGF)-β1(5 ng/mL)induced a fibrotic microenvironment in primary esophageal fibroblasts(pEsF).After 24 hours of KFX treatment(at 1.5%,1%,and 0.5%),expression ofα-smooth muscle actin-2(ACTA2),fibronectin(FN),and type collagen I was assessed.Profibrotic signaling was analyzed,including TGF-β1,Smad2/3,and phosphor-smad2/3(p-Smad2/3).RESULTS Compared to the Control group,the groups treated with KFX and prednisolone exhibited reduced esophageal stenosis,lower weight loss rates,and improved food tolerance 21 d after ESD.After treatment,Masson staining revealed thinner and less dense collagen fibers in the submucosal layer.Additionally,the expression of fibrotic effector molecules was notably inhibited.Mechanistically,KFX downregulated the transduction levels of fibrotic functional molecules such as TGF-β1,Smad2/3,and p-Smad2/3.In vitro,pEsF exposed to TGF-β1-induced fibrotic microenvironment displayed increased fibrotic activity,which was reversed by KFX treatment,leading to reduced activation of ACTA2,FN,and collagen I.The 1.5%KFX treatment group showed decreased expression of p-Smad 2/3 in TGF-β1-activated pEsF.CONCLUSION KFX showed promise as a therapeutic option for post-full circumferential esophageal ESD strictures,potentially by suppressing fibroblast fibrotic activity through modulation of the TGF-β1/Smads signaling pathway. 展开更多
关键词 Kangfuxin solution Natural component Endoscopic submucosal dissection Esophagus stricture Fibrosis
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Normalized Solutions of Nonlinear Choquard Equations with Nonconstant Potential
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作者 LI Nan XU Liping 《应用数学》 北大核心 2025年第1期14-29,共16页
In this paper,we mainly focus on a type of nonlinear Choquard equations with nonconstant potential.Under appropriate hypotheses on potential function and nonlinear terms,we prove that the above Choquard equation with ... In this paper,we mainly focus on a type of nonlinear Choquard equations with nonconstant potential.Under appropriate hypotheses on potential function and nonlinear terms,we prove that the above Choquard equation with prescribed 2-norm has some normalized solutions by introducing variational methods. 展开更多
关键词 Nonlinear Choquard equation Potential function Variational method Normalized solution
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General Solutions’ Laws of Nonlinear Partial Differential Equations
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作者 Honglai Zhu 《Journal of Applied Mathematics and Physics》 2025年第1期166-208,共43页
In previous papers, we proposed the important Ztransformations and obtained general solutions to a large number of linear and quasi-linear partial differential equations for the first time. In this paper, we will use ... In previous papers, we proposed the important Ztransformations and obtained general solutions to a large number of linear and quasi-linear partial differential equations for the first time. In this paper, we will use the Z1transformation to get the general solutions of some nonlinear partial differential equations for the first time, and use the general solutions to obtain the exact solutions of some typical definite solution problems. 展开更多
关键词 TRANSFORMATION Nonlinear Partial Differential Equations Analytical solution General solution Definite solution Problems
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N-Fold Darboux Transformation and Various Solutions for the Coupled mKdV Equations
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作者 Chunmei Fang 《Journal of Applied Mathematics and Physics》 2025年第2期381-391,共11页
In this paper, we get the N-fold Darboux transformation with multi-parameters for the coupled mKdV equations with the help of a guage transformation of the spectral problem. As an application, some new multi-soliton s... In this paper, we get the N-fold Darboux transformation with multi-parameters for the coupled mKdV equations with the help of a guage transformation of the spectral problem. As an application, some new multi-soliton solutions and complexiton solutions are obtained from choosing the appropriate seed solution. All obtained solutions and N-fold Darboux transformations are expressed using the Vandermonde-like determinants. 展开更多
关键词 The N-fold Darboux Transformation The Coupled mKdV Equations Multi-Soliton solutions Complexiton solutions
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Conservation Laws and Particular Solutions for a Keller-Segel Model
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作者 Luyun Chen Jie Lou 《Advances in Pure Mathematics》 2025年第2期107-118,共12页
This work focuses on a Keller-Segel chemotaxis model, with an emphasis on its conservation laws. Through a new approach combined with the multiplier method, called the mixed method, we obtain conservation vectors that... This work focuses on a Keller-Segel chemotaxis model, with an emphasis on its conservation laws. Through a new approach combined with the multiplier method, called the mixed method, we obtain conservation vectors that are related and unrelated to symmetric information. In addition, some exact solutions with particular forms are obtained according to the method of conservation laws. These particular solutions are different from the group-invariant solutions. 展开更多
关键词 Keller-Segel Model Conservation Laws Mixed Method Exact solutions
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The N-periodic wave solutions to the N=1 supersymmetric Sawada–Kotera–Ramani equation
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作者 Pengcheng Xin Zhonglong Zhao Yu Wang 《Chinese Physics B》 2025年第2期207-213,共7页
The N-periodic wave solvability problem for the N=1 supersymmetric Sawada–Kotera–Ramani equation is considered by combining the Hirota's bilinear method and the super Riemann theta function. The constraint equat... The N-periodic wave solvability problem for the N=1 supersymmetric Sawada–Kotera–Ramani equation is considered by combining the Hirota's bilinear method and the super Riemann theta function. The constraint equations and unknown parameters are redefined, and the numerical calculation process of the N-periodic wave solutions is derived. It has been verified that under certain conditions, the asymptotic relations between N-periodic wave solutions and N-soliton solutions can be established. Some numerical solutions of three-periodic wave are presented. Under the influence of the Grassmann variable, the three-periodic wave solutions will generate an influence band in the middle region, and the amplitude becomes bigger as the distance from the influence band increases. 展开更多
关键词 SUPERSYMMETRY N-periodic wave solutions asymptotic relations
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Colorectal cancer early screening:Dilemmas and solutions
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作者 Di Wu Qi-Ying Song +4 位作者 Bai-Shu Dai Jie Li Xin-Xin Wang Jia-Yu Liu Tian-Yu Xie 《World Journal of Gastroenterology》 2025年第9期154-160,共7页
Colorectal cancer(CRC)is a prevalent malignancy worldwide,posing a significant public health concern.Mounting evidence has confirmed that timely early screening facilitates the detection of incipient CRC,thereby enhan... Colorectal cancer(CRC)is a prevalent malignancy worldwide,posing a significant public health concern.Mounting evidence has confirmed that timely early screening facilitates the detection of incipient CRC,thereby enhancing patient prognosis.Obviously,non-participation of asymptomatic individuals in screening programs hampers early diagnosis and may adversely affect long-term outcomes for CRC patients.In this letter,we provide a comprehensive overview of the current status of early screening practices,while also thoroughly examine the dilemmas and potential solutions associated with early screening for CRC.In response to these issues,we proffer a set of recommendations directed at governmental authorities and the general public,which focus on augmenting financial investment,establishing standardized screening protocols,advancing technological capabilities,and bolstering public awareness campaigns.The importance of collaborative efforts from various stakeholders cannot be overstated in the quest to enhance early detection rates and alleviate the societal burden of CRC. 展开更多
关键词 Colorectal cancer Early screening Asymptomatic candidates DILEMMAS solutionS
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In-Plane Static Analysis of Curved Nanobeams Using Exact-Solution-Based Finite Element Formulation
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作者 Omer Ekim Genel Hilal Koc Ekrem Tufekci 《Computers, Materials & Continua》 2025年第2期2043-2059,共17页
Due to their superior properties, the interest in nanostructures is increasing today in engineering. This study presents a new two-noded curved finite element for analyzing the in-plane static behaviors of curved nano... Due to their superior properties, the interest in nanostructures is increasing today in engineering. This study presents a new two-noded curved finite element for analyzing the in-plane static behaviors of curved nanobeams. Opposite to traditional curved finite elements developed by using approximate interpolation functions, the proposed curved finite element is developed by using exact analytical solutions. Although this approach was first introduced for analyzing the mechanical behaviors of macro-scale curved beams by adopting the local theory of elasticity, the exact analytical expressions used in this study were obtained from the solutions of governing equations that were expressed via the differential form of the nonlocal theory of elasticity. Therefore, the effects of shear strain and axial extension included in the analytical formulation are also inherited by the curved finite element developed here. The rigidity matrix and the consistent force vector are developed for a circular finite element. To demonstrate the applicability of the method, static analyses of various curved nanobeams subjected to different boundary conditions and loading scenarios are performed, and the obtained results are compared with the exact analytical ones. The presented study provides an accurate and low computational cost method for researchers to investigate the in-plane static behavior of curved nanobeams. 展开更多
关键词 Nonlocal elasticity finite element exact solution static analysis nanobeam curved
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POSITIVE GROUND STATE SOLUTIONS FOR A QUASILINEAR SCHRODINGER EQUATION
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作者 JIN Qing-fei 《数学杂志》 2025年第2期95-110,共16页
This paper is concerned with the positive ground state solutions for a quasilinear Schrodinger equation with a Hardy-type term.We obtain positive ground state solutions for the given quasilinear Schrodinger equation b... This paper is concerned with the positive ground state solutions for a quasilinear Schrodinger equation with a Hardy-type term.We obtain positive ground state solutions for the given quasilinear Schrodinger equation by using a change of variables and variational method. 展开更多
关键词 Quasilinear equation schrodinger equation positive ground state solutions variational methods
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Analytical solution for estimating the minimum required strength of sill mat by considering failure due to rock wall closure
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作者 Chuan Fan Li Li +3 位作者 Guangsheng Liu Xiaocong Yang Lijie Guo Jing Tang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第2期996-1007,共12页
Underhand cut-and-fill mining has been widely used in underground mining operations,especially when the rock mass or orebody is of poor quality or prone to rockburst due to high stress.In such cases,mining workers sho... Underhand cut-and-fill mining has been widely used in underground mining operations,especially when the rock mass or orebody is of poor quality or prone to rockburst due to high stress.In such cases,mining workers should carry out all production activities under the cemented backfill roof or sill mat instead of a highly fractured and unstable rock roof or a strong rock roof with a high potential of rockburst.Therefore,the stability and required strength of the sill mat are critical issues for mining engineers.In 1991,Mitchell considered that sill mat could fail by caving,sliding,rotation,and flexure.Mitchell also proposed an analytical solution to determine the minimum required strength of the sill mat for each type of failure based on two stiff or immobile rock walls.However,recent publications using numerical modeling and field measurements indicate that the compressive stresses in the sill mat induced by rock wall closure due to a stope excavation beneath the sill mat can be significant.It is thus highly necessary to investigate the required strength of the sill mat by considering rock wall closure.In this study,the crushing failure of sill mat due to rock wall closure generated by underground excavation and a new failure mode called"crushing and caving”is revealed by numerical modeling.An analytical solution corresponding to each failure mode is then developed to estimate the minimum required cohesion(cmin)of the sill mat.A criterion is also proposed to determine if the sill mat fails by crushing or crushing-and-caving failure.The proposed analytical solution does not involve any correction coefficients.The validity of the proposed analytical solution is demonstrated by numerical modeling.The proposed analytical solution can thus be employed to predict the cmin of sill mat subjected to wall closure generated by underlying stope excavation. 展开更多
关键词 Underhand cut-and-fill mining Cemented backfill Wall closure CRUSHING Required strength Analytical solution
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Analytical solution for determining wall closure associated with stope excavation underneath sill mat constructed by cemented backfill
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作者 Chuan Fan Li Li +3 位作者 Xiaocong Yang Guangsheng Liu Lijie Guo Jing Tang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第2期983-995,共13页
In the underhand cut-and-fill mining method,a sill mat(i.e.an artificial horizontal pillar)constructed by cemented backfill is essential to prevent mine workers from being directly exposed under problematic rock roofs... In the underhand cut-and-fill mining method,a sill mat(i.e.an artificial horizontal pillar)constructed by cemented backfill is essential to prevent mine workers from being directly exposed under problematic rock roofs.A critical issue is to determine the minimum required strength of the sill mat to ensure a safe and cost-effective design.Until now,Mitchell’s analytical solution is the only available option,considering two stiff and immobile rock walls.Unavoidable rock wall closure associated with stope excavation below the sill mat was neglected.This,along with other undefined parameters,explains why Mitchell’s solution is rarely used in sill mat design.A new analytical solution for determining the minimum required strength of the sill mat accounting for wall closure is necessary.In this study,a closed-form analytical solution for estimating rock wall closure generated by stope excavation below a sill mat is developed by using Salamon’s and Flamant’s models.The proposed analytical solution does not contain any coefficients of correction or calibration.Despite several assumptions(or somewhat of oversimplifications)necessary to render a simple analytical solution possible,good agreements are obtained between the rock wall closures predicted by applying the proposed analytical solution and those obtained numerically with FLAC3D for many cases with arbitrarily chosen geometrical and material parameters.The proposed analytical solution is therefore validated and can be used to evaluate the rock wall closure generated by stope excavation below a sill mat. 展开更多
关键词 Underhand cut-and-fill mining BACKFILL Wall closure Analytical solution FLAC3D Flamant model
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PSEUDO S-ASYMPTOTICALLY PERIODIC SOLUTIONS OF PARTIAL NEUTRAL DIFFERENTIAL EQUATIONS
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作者 LIU Jing-huai ZHANG Li-tao 《数学杂志》 2025年第2期140-150,共11页
In this paper,we study the existence of pseudo S-asymptotically ω-periodic mild solutions of abstract partial neutral differential equations in Banach spaces.By using the principle of Banach contractive mapping,the e... In this paper,we study the existence of pseudo S-asymptotically ω-periodic mild solutions of abstract partial neutral differential equations in Banach spaces.By using the principle of Banach contractive mapping,the existence and uniqueness of pseudo S-asymptotically ω-periodic mild solutions of abstract partial neutral differential equations are obtained.To illustrate the ab-stract result,a concrete example is given. 展开更多
关键词 pseudo S-asymptotically!-periodic function mild solution partial neutral differential equations
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High Energy Normalized Solutions for the Schrodinger Equations with Exponential Critical Growth
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作者 ZHANG Xiao-cang XULi-ping 《Chinese Quarterly Journal of Mathematics》 2025年第1期1-19,共19页
In this paper,we study high energy normalized solutions for the following Schr?dinger equation{-Δu+V(x)u+λu=f(u),in R^(2),∫_(R^(2))|u|^(2)dx=c,where c>0,λ∈R will appear as a Lagrange multiplier,V(x)=ω|x|2 rep... In this paper,we study high energy normalized solutions for the following Schr?dinger equation{-Δu+V(x)u+λu=f(u),in R^(2),∫_(R^(2))|u|^(2)dx=c,where c>0,λ∈R will appear as a Lagrange multiplier,V(x)=ω|x|2 represents a trapping potential,and f has an exponential critical growth.Under the appropriate assumptions of f,we have obtained the existence of normalized solutions to the above Schr?dinger equation by introducing a variational method.And these solutions are also high energy solutions with positive energy. 展开更多
关键词 High energy normalized solutions Schrodinger equation Trapping potential Exponential critical growth Variational method
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Abundant invariant solutions of(3+1)-dimensional combined pKP-BKP equation
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作者 Hengchun Hu Xu Xu 《Chinese Physics B》 2025年第3期291-299,共9页
Lie symmetry analysis is applied to a(3+1)-dimensional combined potential Kadomtsev-Petviashvili equation with B-type Kadomtsev-Petviashvili equation(pKP-BKP equation)and the corresponding similarity reduction equatio... Lie symmetry analysis is applied to a(3+1)-dimensional combined potential Kadomtsev-Petviashvili equation with B-type Kadomtsev-Petviashvili equation(pKP-BKP equation)and the corresponding similarity reduction equations are obtained with the different infinitesimal generators.Invariant solutions with arbitrary functions and constants for the(3+1)-dimensional pKP-BKP equation,including the lump solution,the periodic-lump solution,the two-kink solution,the breather solution and the lump-two-kink solution,have been studied analytically and graphically. 展开更多
关键词 (3+1)-dimensional combined pKP-BKP equation Lie symmetry invariant solutions
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New analytical solutions for free vibration of embedded magneto-electro-elastic cylindrical shells with step-wise thickness variations
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作者 Jufang JIA Huilin YIN +3 位作者 Qinyu YU Jiabin SUN Xinsheng XU Zhenhuan ZHOU 《Applied Mathematics and Mechanics(English Edition)》 2025年第3期447-466,共20页
In recent years,magneto-electro-elastic(MEE)cylindrical shells with step-wise thicknesses have shown significant potential in the field of vibration energy harvesting.To aid the design of such energy harvesting device... In recent years,magneto-electro-elastic(MEE)cylindrical shells with step-wise thicknesses have shown significant potential in the field of vibration energy harvesting.To aid the design of such energy harvesting devices,an accurate free vibration analysis of embedded MEE cylindrical shells with step-wise thicknesses is performed within the framework of symplectic mechanics.By using the Legendre transformation,a new known vector is defined to transform the higher-order partial differential governing equations into a set of lower-order ordinary differential equations.Therefore,the original vibration analysis is regarded as an eigen problem in the symplectic space,and analytical solutions can be represented by the symplectic series.In numerical examples,the new analytical solutions are compared with the existing results,and good agreement is observed.Furthermore,the effects of critical design parameters on free vibration characteristics are thoroughly investigated.All numerical results can serve as benchmarks for the development of other approximate or numerical methods. 展开更多
关键词 analytical solution free vibration magneto-electro-elastic(MEE)material cylindrical shell with variable thickness symplectic method
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Influence of high-temperature and short-time solution treatment on microstructure and properties of Al−Mg−Zn−Ag alloy
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作者 Cheng GUO Yi-fei CHEN +6 位作者 Yu-qin GUO Huan WANG Hai-tao ZHANG Jing-qi CHEN Zi-bin WU Xin-gang LIU Hiromi NAGAUMI 《Transactions of Nonferrous Metals Society of China》 2025年第2期362-376,共15页
High-temperature and short-time(HTST)solution heat treatment combined with non-isothermal aging(NIA)was employed to regulate the microstructure and properties of Al−4.5Mg−2.0Zn−0.3Ag alloy.Results indicate that HTST s... High-temperature and short-time(HTST)solution heat treatment combined with non-isothermal aging(NIA)was employed to regulate the microstructure and properties of Al−4.5Mg−2.0Zn−0.3Ag alloy.Results indicate that HTST solution heat treatment can not only retain partial deformation dislocations,but inhibit the recrystallization behavior and increase the proportion of low-angle grain boundaries(LAGBs).In the subsequent NIA process,HTST solution heat treatment combined with NIA is instrumental in restraining the degradation of dislocations and promoting precipitation of nano-scale T'-Mg_(32)(Al,Zn,Ag)49 phase,which improves the strength of the alloy greatly.In addition,a higher fraction of LAGBs and the discontinuous distribution of grain boundary precipitates caused by this novel technology meliorate the corrosion resistance of Al−4.5Mg−2.0Zn−0.3Ag alloy. 展开更多
关键词 Al−Mg−Zn−Ag alloy solution treatment non-isothermal aging microstructure mechanical properties corrosion resistance
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Achieving the high phase purity of CH_3NH_3PbI_3 film by two-step solution processable crystal engineering
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作者 Yan Li Bin Ding +2 位作者 Guan-Jun Yang Chang-Jiu Li Cheng-Xin Li 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2018年第8期1405-1411,共7页
To date, it is still a great challenge for highly efficient perovskite devices to realize the high quality per- ovskite films with high purity, high coverage ratio and good crystallization by two-step scalable solutio... To date, it is still a great challenge for highly efficient perovskite devices to realize the high quality per- ovskite films with high purity, high coverage ratio and good crystallization by two-step scalable solution method. In this study, a series PbI2 films with tunable micro-architecture of Pbl2 crystals are prepared via solution processable crystal engineering. The perovskite film, prepared by optimized pit spacing in gas pumped PbI2 film at 1000 Pa, shows the highest film quality, including no residual Pbl2 phase, compact morphology, and improved photoluminescence intensity. A transformation kinetics shows that the pit spacing strongly influences both the mass transfer and the sequential intercalation reaction between CH3NH31 and PbI2 crystals, which ultimately determines the full reaction state of the perovskite film. The perovskite solar cells assembled by the perovskite film show both high power-conversion efficiency and good reproducibility of photovoltaic performance due to the restrained charge recombination arising from the high quality perovskite film. 展开更多
关键词 High phase purity CHHNH3PbI3 film two-step solution method Perovskite solar cells
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Hamiltonian system for the inhomogeneous plane elasticity of dodecagonal quasicrystal plates and its analytical solutions 被引量:1
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作者 孙志强 侯国林 +1 位作者 乔艳芬 刘金存 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期581-590,共10页
A Hamiltonian system is derived for the plane elasticity problem of two-dimensional dodecagonal quasicrystals by introducing the simple state function. By using symplectic elasticity approach, the analytic solutions o... A Hamiltonian system is derived for the plane elasticity problem of two-dimensional dodecagonal quasicrystals by introducing the simple state function. By using symplectic elasticity approach, the analytic solutions of the phonon and phason displacements are obtained further for the quasicrystal plates. In addition, the effectiveness of the approach is verified by comparison with the data of the finite integral transformation method. 展开更多
关键词 Hamiltonian system symplectic elasticity QUASICRYSTALS analytic solution state function
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Adsorption behaviors and mechanisms of gold recovery from thiosulfate solution by ion exchange resin 被引量:2
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作者 Zhong-lin DONG Tao JIANG +2 位作者 Bin XU Qian LI Yong-bin YANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第10期3372-3385,共14页
The adsorption behaviors and mechanisms of gold from thiosulfate solution on strong-base anion exchange resin were systematically investigated.The comparison experiment of adsorption ability and selectivity for gold s... The adsorption behaviors and mechanisms of gold from thiosulfate solution on strong-base anion exchange resin were systematically investigated.The comparison experiment of adsorption ability and selectivity for gold showed that gel Amberlite IRA-400 resin with Type Ⅰ quaternary ammonium functional group had better adsorption performance.The increases of resin dosage,ammonia concentration and solution pH were favorable to gold adsorption,whereas the rises of cupric and thiosulfate concentrations were disadvantageous to gold loading.Microscopic characterization results indicated that gold was adsorbed in the form of [Au(S_(2)O_(3))_(2)]^(3–) complex anion by exchanging with the counter ion Cl^(–) in the functional group of the resin.Density functional theory calculation result manifested that gold adsorption was mainly depended on the hydrogen bond and van der Waals force generated between O atom in [Au(S_(2)O_(3))_(2)]^(3–) and H atom in the quaternary ammonium functional group of the resin. 展开更多
关键词 GOLD thiosulfate solution resin adsorption behaviors and mechanisms density functional theory calculation
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