The line intensities of 001-000 transition of the asymptotic asymmetric-top Oa molecule at several temperatures are calculated by directly calculating the partition functions and regarding the rotationless transition ...The line intensities of 001-000 transition of the asymptotic asymmetric-top Oa molecule at several temperatures are calculated by directly calculating the partition functions and regarding the rotationless transition dipole moment squared as a constant. The calculated values of the total internM partition sums （TIPS） are consistent with the data of HITRAN database with -0.61% at 296 K. The calculated line intensity data at 500 K and 3000 K are also in excellent agreement with the data in HITRAN database with less than 0.659% and 5.458% at 500 K and 3000 K, which provide a strong support for the calculations of partition function and fine intensity at high temperature. Then we extend the calculation to higher temperatures. The line intensities and simulated spectra of v3 band of the asymptotic asymmetric-top O3 molecule at 4000 and 5000 K are reported. The results are of significance for the studying of the molecular high-temperature spectrum including experimental measurements and theoretical calculations.展开更多
ZSM-5 zeolites with similar St/Al ratio were synthesized successfully using various templates [n- butylamine （BTA）, tetrapropylammonium bromide （TPABr） and no template （NT）] under hydrothermal conditions, The sa...ZSM-5 zeolites with similar St/Al ratio were synthesized successfully using various templates [n- butylamine （BTA）, tetrapropylammonium bromide （TPABr） and no template （NT）] under hydrothermal conditions, The samples were characterized by XRD, SEM, Py-IR and BET surface area measurements in order to understand the template eiTects and the differences between the ZSM-5 santples. The synthesis of ZSM-5 with organic templates was relatively easier than those with inorganic templates and withnut template. SEM results revealed that ZSM-5 synthesized with different templates had different morphologies in similar particle size. Toluene disproportiortation reaction was carried out over the catalyst samples to evaluate the catalytic properties. The results have shown that large crystals which have a correspondingly small external surface showed a high para-xylene selectivity, and the amount of C9^＋ and C5^＋ was much less than that obtained from zeolite with small crystals.展开更多
New classes of exact solutions of the quasi-linear diffusion-reaction equations are obtained by seeking for the high-order conditional Lie-Baeklund symmetries of the considered equations. The method used here extends ...New classes of exact solutions of the quasi-linear diffusion-reaction equations are obtained by seeking for the high-order conditional Lie-Baeklund symmetries of the considered equations. The method used here extends the approaches of derivative-dependent functional separation of variables and the invariant subspace. Behavior to some solutions such as blow-up and quenching is also described.展开更多
Two factorization approaches have been proposed for single transverse spin asymmetries. One is the cofiinear factorization, the other is the transverse-momentum-dependent factorization. They have been previously deriv...Two factorization approaches have been proposed for single transverse spin asymmetries. One is the cofiinear factorization, the other is the transverse-momentum-dependent factorization. They have been previously derived in a formal way by using diagram expansion at hadron level. If the two factorizations hold or can be proven, they should also hold when we replace hadrons with patton states. We examine these two factorizations at patton level with massless partons. It is nontrivial to generate these asymmetries at parton level with massless patrons because the asymmetries require helicity-flip and nonzero absorptive parts in scattering amplitudes. By constructing suitable patton states with massless partons we derive the two factorizations for the asymmetry in Drell-Yan processes. It is found from our results that the collinear factorization derived at parton level is not the same as that derived at hadron level. Our results with massless partons confirm those derived with single massive parton state in our previous works.展开更多
The barrier against the spontaneous fission has been determined within the Generalized Liquid Drop Model （GLDM） including the mass and charge asymmetry, and the proximity energy. The shell correction of the spherica...The barrier against the spontaneous fission has been determined within the Generalized Liquid Drop Model （GLDM） including the mass and charge asymmetry, and the proximity energy. The shell correction of the spherical parent nucleus is calculated by using the Strutinsky method, and the empirical shape-dependent shell correction is 6mp10yed during the deformation process. A quasi-molecular shape sequence has been defined to describe the whole process from one-body shape to two-body shape system, and a two-touching-ellipsoid is adopted when the superdeformed one-body system reaches the rupture point. On these bases the spontaneous fission barriers are systematically studied for nuclei from 2a^Th to 249 Cm for different possible exiting channels with the different mass and charge asymmetries. The double, and triple bumps are found in the fission potential energy in this region, which roughly agree with the experimental results. It is found that at around Sn-like fragment the outer fission barriers are lower, while the partner of the Sn-like fragment is in the range near l^SRu where the ground-state mass is lowered by allowing axially symmetric shapes. The preferable fission channels are distinctly pronounced, which should be corresponding to the fragment mass distributions.展开更多
基金supported by National Natural Science Foundation of China under Grant No.10574096the Major Program for Basic Research of National Security of China under Grant No.5134202-04the Natural Science Foundation of the Bureau of Education of Guizhou Province under Grant No.2006204
文摘The line intensities of 001-000 transition of the asymptotic asymmetric-top Oa molecule at several temperatures are calculated by directly calculating the partition functions and regarding the rotationless transition dipole moment squared as a constant. The calculated values of the total internM partition sums （TIPS） are consistent with the data of HITRAN database with -0.61% at 296 K. The calculated line intensity data at 500 K and 3000 K are also in excellent agreement with the data in HITRAN database with less than 0.659% and 5.458% at 500 K and 3000 K, which provide a strong support for the calculations of partition function and fine intensity at high temperature. Then we extend the calculation to higher temperatures. The line intensities and simulated spectra of v3 band of the asymptotic asymmetric-top O3 molecule at 4000 and 5000 K are reported. The results are of significance for the studying of the molecular high-temperature spectrum including experimental measurements and theoretical calculations.
文摘ZSM-5 zeolites with similar St/Al ratio were synthesized successfully using various templates [n- butylamine （BTA）, tetrapropylammonium bromide （TPABr） and no template （NT）] under hydrothermal conditions, The samples were characterized by XRD, SEM, Py-IR and BET surface area measurements in order to understand the template eiTects and the differences between the ZSM-5 santples. The synthesis of ZSM-5 with organic templates was relatively easier than those with inorganic templates and withnut template. SEM results revealed that ZSM-5 synthesized with different templates had different morphologies in similar particle size. Toluene disproportiortation reaction was carried out over the catalyst samples to evaluate the catalytic properties. The results have shown that large crystals which have a correspondingly small external surface showed a high para-xylene selectivity, and the amount of C9^＋ and C5^＋ was much less than that obtained from zeolite with small crystals.
基金supported by the National Natural Science Foundation of China under Grant No. 10671156the Program for New Century Excellent Talents in Universities under Grant No. NCET-04-0968
文摘New classes of exact solutions of the quasi-linear diffusion-reaction equations are obtained by seeking for the high-order conditional Lie-Baeklund symmetries of the considered equations. The method used here extends the approaches of derivative-dependent functional separation of variables and the invariant subspace. Behavior to some solutions such as blow-up and quenching is also described.
基金Supported by National Natural Science Foundation of China under Grant Nos. 10721063, 10575126, and 10975169
文摘Two factorization approaches have been proposed for single transverse spin asymmetries. One is the cofiinear factorization, the other is the transverse-momentum-dependent factorization. They have been previously derived in a formal way by using diagram expansion at hadron level. If the two factorizations hold or can be proven, they should also hold when we replace hadrons with patton states. We examine these two factorizations at patton level with massless partons. It is nontrivial to generate these asymmetries at parton level with massless patrons because the asymmetries require helicity-flip and nonzero absorptive parts in scattering amplitudes. By constructing suitable patton states with massless partons we derive the two factorizations for the asymmetry in Drell-Yan processes. It is found from our results that the collinear factorization derived at parton level is not the same as that derived at hadron level. Our results with massless partons confirm those derived with single massive parton state in our previous works.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11175074,11120101005,11105035,and 10805061the Fundamental Research Funds for the Central Universities under Grant No.lzujbky-2012-5the Knowledge Innovation Project of the Chinese Academy of Sciences under Grant No.KJCX2-EW-N01
文摘The barrier against the spontaneous fission has been determined within the Generalized Liquid Drop Model （GLDM） including the mass and charge asymmetry, and the proximity energy. The shell correction of the spherical parent nucleus is calculated by using the Strutinsky method, and the empirical shape-dependent shell correction is 6mp10yed during the deformation process. A quasi-molecular shape sequence has been defined to describe the whole process from one-body shape to two-body shape system, and a two-touching-ellipsoid is adopted when the superdeformed one-body system reaches the rupture point. On these bases the spontaneous fission barriers are systematically studied for nuclei from 2a^Th to 249 Cm for different possible exiting channels with the different mass and charge asymmetries. The double, and triple bumps are found in the fission potential energy in this region, which roughly agree with the experimental results. It is found that at around Sn-like fragment the outer fission barriers are lower, while the partner of the Sn-like fragment is in the range near l^SRu where the ground-state mass is lowered by allowing axially symmetric shapes. The preferable fission channels are distinctly pronounced, which should be corresponding to the fragment mass distributions.
