The laminar flame propagation of 1-heptene/air mixtures covering equivalence ratios from 0.7 to 1.5 is investigated in a constant-volume cylindrical combustion vessel at 373K and elevated pressures (1, 2, 5, and 10 at...The laminar flame propagation of 1-heptene/air mixtures covering equivalence ratios from 0.7 to 1.5 is investigated in a constant-volume cylindrical combustion vessel at 373K and elevated pressures (1, 2, 5, and 10 atm). Laminar flame speed and Markstein length are derived from the recorded schlieren images. A kinetic model of 1-heptene combustion is developed based on our previous kinetic model of 1-hexene. The model is validated against the laminar flame speed data measured in this work and the ignition delay time data in literature. Modeling analyses, such as sensitivity analysis and rate of production analysis, are performed to help understand the high temperature chemistry of 1-heptene under various pressures and its influence on the laminar flame propagation. Furthermore, the laminar flame propagation of 1-heptene/air mixtures is compared with that of n-heptane/air mixtures reported in our previous work. The laminar flame speed values of 1-heptene/air mixtures are observed to be faster than those of n-heptane/air mixtures under most conditions due to the enhanced exothermicity and reactivity.展开更多
The escape of particles in an open square-shaped cavity has been examined. We consider a family of trajectories launched from the left bottom lead of the square cavity and escaped from the right boundary. For each esc...The escape of particles in an open square-shaped cavity has been examined. We consider a family of trajectories launched from the left bottom lead of the square cavity and escaped from the right boundary. For each escaping trajectories, we record the propagation time and the detector position. We find that the escape time graph exhibits a regular sawtooth structure. For a set of detector points, we search for the classical trajectories from the source point to the detector points. Then we use semiclassical theory to construct the wave function at different given points. The calculation results suggest that the escape probability density depends on the detector position and the momentum of the particle sensitively. The Fourier transform of the semiclassical wave function gives the path length spectrum. Each peak in the path length spectrum corresponds to the length of one escape trajectory of the particle. We hope that our results will be useful in understanding the escape and transport process of particles inside a microcavity.展开更多
基金supported by the National Key R&D Program of China (No.2017YFA0402800)National Natural Science Foundation of China (No.51622605 and No.91541201)Shanghai Science and Technology Committee (No.17XD1402000)
文摘The laminar flame propagation of 1-heptene/air mixtures covering equivalence ratios from 0.7 to 1.5 is investigated in a constant-volume cylindrical combustion vessel at 373K and elevated pressures (1, 2, 5, and 10 atm). Laminar flame speed and Markstein length are derived from the recorded schlieren images. A kinetic model of 1-heptene combustion is developed based on our previous kinetic model of 1-hexene. The model is validated against the laminar flame speed data measured in this work and the ignition delay time data in literature. Modeling analyses, such as sensitivity analysis and rate of production analysis, are performed to help understand the high temperature chemistry of 1-heptene under various pressures and its influence on the laminar flame propagation. Furthermore, the laminar flame propagation of 1-heptene/air mixtures is compared with that of n-heptane/air mixtures reported in our previous work. The laminar flame speed values of 1-heptene/air mixtures are observed to be faster than those of n-heptane/air mixtures under most conditions due to the enhanced exothermicity and reactivity.
基金Supported by the National Natural Science Foundation of China under Grant No.11074104the University Student's Science and Technology Innovation Fund of Ludong University of China under Grant No.12z004
文摘The escape of particles in an open square-shaped cavity has been examined. We consider a family of trajectories launched from the left bottom lead of the square cavity and escaped from the right boundary. For each escaping trajectories, we record the propagation time and the detector position. We find that the escape time graph exhibits a regular sawtooth structure. For a set of detector points, we search for the classical trajectories from the source point to the detector points. Then we use semiclassical theory to construct the wave function at different given points. The calculation results suggest that the escape probability density depends on the detector position and the momentum of the particle sensitively. The Fourier transform of the semiclassical wave function gives the path length spectrum. Each peak in the path length spectrum corresponds to the length of one escape trajectory of the particle. We hope that our results will be useful in understanding the escape and transport process of particles inside a microcavity.
