NiO_(x)as a hole transport material for inverted perovskite solar cells has received great attention owing to its high transparency,low fabrication temperature,and superior stability.However,the mismatched energy leve...NiO_(x)as a hole transport material for inverted perovskite solar cells has received great attention owing to its high transparency,low fabrication temperature,and superior stability.However,the mismatched energy levels and possible redox reactions at the NiO_(x)/perovskite interface severely limit the performance of NiO_(x) based inverted perovskite solar cells.Herein,we introduce a p-type self-assembled monolayer between NiO_(x)and perovskite layers to modify the interface and block the undesirable redox reaction between perovskite and NiO_(x)The selfassembled monolayer molecules all contain phosphoric acid function groups,which can be anchored onto the NiOr surface and passivate the surface defect.Moreover,the introduction of self-assembled monolayers can regulate the energy level structure of NiO_(x),reduce the interfacial band energy offset,and hence promote the hole transport from perovskite to NiO_(x)layer.Consequently,the device performance is significantly enhanced in terms of both power conversion efficiency and stability.展开更多
To investigate the effects of initial geometric imperfection and material nonlinearity on the stability analysis of the suspen-dome, the steel roof of Jiangsu Culture Sports Center Gymnasium was utilized as a numerica...To investigate the effects of initial geometric imperfection and material nonlinearity on the stability analysis of the suspen-dome, the steel roof of Jiangsu Culture Sports Center Gymnasium was utilized as a numerical model, and modal analyses were performed. Then, linear buckling analysis,geometric nonlinear stability analysis, geometric nonlinear stability analysis with initial imperfection, and double nonlinear analysis considering material nonlinearity and geometric nonlinearity were discussed in detail to compare the stability performance of the ellipse-like suspen-dome and the single-layer reticulated shell. The results showthat the cable-strut system increases the integrity of the suspen-dome, and moderates the sensibility of the single-layer reticulated shell to initial geometric imperfection. However, it has little influence on integral rigidity, fundamental vibration frequencies, linear ultimate live loads, and geometric nonlinear ultimate live loads without initial imperfection. When considering the material nonlinearity and initial imperfection, a significant reduction occurs in the ultimate stability capacities of these two structures. In this case, the suspen-dome with a lowrise-span ratio is sensitive to the initial imperfection and material nonlinearity. In addition, the distribution pattern of live loads significantly influences the instability modes of the structure, and the uniform live load with full span is not always the most dangerous case.展开更多
As a new frontier in catalysis field,single-atom catalysts(SACs)hold unique electronic structure and high atom utilization,which have displayed unprecedented activity and selectivity toward a wide range of catalytic r...As a new frontier in catalysis field,single-atom catalysts(SACs)hold unique electronic structure and high atom utilization,which have displayed unprecedented activity and selectivity toward a wide range of catalytic reactions.However,many reported SACs are susceptible to Ostwald ripening process in high temperature environment or long-term catalytic application,which will cause sintering and deactivation.This is due to the weak interaction between the metal atom and supports.The regeneration and recycling of deactivated catalysts will greatly increase the time and economic cost of industrial production.Therefore,it is necessary to develop SACs with excellent thermal stability to meet the industrial demands.Here,we discuss the fundamental comprehension of the stability of thermally stable SACs obtained from different synthesis methods.The influences of the speciation of metal centers and coordination environments on thermal stability are summarized.The importance of using novel in situ and operando characterizations to reveal dynamic structural evolution under synthesis and reaction conditions and to identify active sites of thermally stable SACs is highlighted.The mechanistic understanding of the unique role of thermally stable SACs in thermocatalytic application is also discussed.At last,a brief perspective on the remaining challenges and future directions of thermally stable SACs is presented.展开更多
Permanent magnetic actuator （PMA）, as a new electronic actuator of vacuum circuit breakers, certainly will be used to replace the traditional mechanical actuator. It has such advantages as simple structure, high rel...Permanent magnetic actuator （PMA）, as a new electronic actuator of vacuum circuit breakers, certainly will be used to replace the traditional mechanical actuator. It has such advantages as simple structure, high reliability, free maintenance, and so on. This paper summarizes the development, structure, magnetic analysis, character analysis, and control strategy of PMA, and also predicts the future trend of PMA development展开更多
In this paper, the nonlinear singular stabilization, H∞ control problem of systems with ordinary homogeneous properties is considered. At first, we discuss the stabilization problems of nonlinear systems with homogen...In this paper, the nonlinear singular stabilization, H∞ control problem of systems with ordinary homogeneous properties is considered. At first, we discuss the stabilization problems of nonlinear systems with homogeneous. Secondly, by vitue of Hamilton-Jacobi-Isaacs equations or inequalities, we solve regular H∞ of nonlinear systems with homogeneous properties. To overcome the H∞ problem of singular nonlinear system, we try to transform inputs of the singular nonlinear system into two parts： regular part input and singular part input. Following the previous results, we solve the singular nonlinear system H∞ control, we give the Lyapunov function and the state feedback controller of the singular nonlinear systems with homogeneous properties.展开更多
The stability of single layer armour units on low crested and submerged breakwaters has been investigated in 2D hydraulic model tests. Armour unit movements including settlements, rocking and displacements have been d...The stability of single layer armour units on low crested and submerged breakwaters has been investigated in 2D hydraulic model tests. Armour unit movements including settlements, rocking and displacements have been determined. The effect of freeboard, packing density and wave steepness on the armour layer stability on crest, front and rear slope has been investigated. Armour units were mostly displaced in the most upper part of the seaward slope and at the seaward side of the crest. Damage on the crest was progressing towards the rear slope. About 40% to 50% larger armour units are required on the seaward slope and crest of low crested structures （as compared to conventional high crested breakwaters）. About 35% larger armour units are required on the rear slope. Larger armour units are not required on submerged breakwaters if the water depth on the crest exceeds 40% of design wave height.展开更多
Objective： The aim of the study was to evaluate the impact of the chemosensitivity assay in vitro and establish a standard process of measuring the anti-cancer drug sensitivity with MTT assay. Methods： Some influenc...Objective： The aim of the study was to evaluate the impact of the chemosensitivity assay in vitro and establish a standard process of measuring the anti-cancer drug sensitivity with MTT assay. Methods： Some influencing factors of MTT assay in studying the sensitivity of human peripheral blood mononuclear cells （PBMC） to anti-cancer drugs were observed, including red blood cells, platelets, three different kinds of DMSO and different concentrations of MTT. Meanwhile the stability of tumor drug-coated plate was monitored. Results： The red blood cells and platelets may affect the results at a certain range of concentration. Analytical pure DMSO, both imported and domestic reagents showed the same color with MI3-, and the A values of the reaction were dependent on MTT dose. The stability of the freeze-drying drug-coated plates was superior to non freeze-drying ones. Conclusion： To make clear and definite all kinds of influencing factors might contribute to a kind of standard MTT assay for drug sensitivity test in vitro.展开更多
In this paper,we investigated the effects of temperature,oxygen,antioxidants,and corn germ oil on the stability of astaxanthin from Haematococcus pluvialis under different storage conditions,and changes in the composi...In this paper,we investigated the effects of temperature,oxygen,antioxidants,and corn germ oil on the stability of astaxanthin from Haematococcus pluvialis under different storage conditions,and changes in the composition of astaxanthin esters during storage using high performance liquid chromatography and spectrophotometry.Oxygen and high temperatures(22–25°C) significantly reduced the stability of astaxanthin esters.Corn germ oil and antioxidants(ascorbic acid and vitamin E)failed to protect astaxanthin from oxidation,and actually significantly increased the instability of astaxanthin.A change in the relative composition of astaxanthin esters was observed after 96 weeks of long-term storage.During storage,the relative amounts of free astaxanthin and astaxanthin monoesters declined,while the relative amount of astaxanthin diesters increased.Thus,the ratio of astaxanthin diester to monoester increased,and this ratio could be used to indicate if astaxanthin esters have been properly preserved.If the ratio is greater than 0.2,it suggests that the decrease in astaxanthin content could be higher than 20%.Our results show that storing algal powder from H.pluvialis or other natural astaxanthin products under vacuum and in the dark below 4°C is the most economical and applicable storage method for the large-scale production of astaxanthin from H.pluvialis.This storage method can produce an astaxanthin preservation rate of at least 80%after 96 weeks of storage.展开更多
文摘NiO_(x)as a hole transport material for inverted perovskite solar cells has received great attention owing to its high transparency,low fabrication temperature,and superior stability.However,the mismatched energy levels and possible redox reactions at the NiO_(x)/perovskite interface severely limit the performance of NiO_(x) based inverted perovskite solar cells.Herein,we introduce a p-type self-assembled monolayer between NiO_(x)and perovskite layers to modify the interface and block the undesirable redox reaction between perovskite and NiO_(x)The selfassembled monolayer molecules all contain phosphoric acid function groups,which can be anchored onto the NiOr surface and passivate the surface defect.Moreover,the introduction of self-assembled monolayers can regulate the energy level structure of NiO_(x),reduce the interfacial band energy offset,and hence promote the hole transport from perovskite to NiO_(x)layer.Consequently,the device performance is significantly enhanced in terms of both power conversion efficiency and stability.
基金The National Key Technology R&D Program of China(No.2012BAJ03B06)the National Natural Science Foundation of China(No.51308105)+1 种基金the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the Fundamental Research Funds for the Southeast University(No.KYLX_0152,SJLX_0084,KYLX_0149)
文摘To investigate the effects of initial geometric imperfection and material nonlinearity on the stability analysis of the suspen-dome, the steel roof of Jiangsu Culture Sports Center Gymnasium was utilized as a numerical model, and modal analyses were performed. Then, linear buckling analysis,geometric nonlinear stability analysis, geometric nonlinear stability analysis with initial imperfection, and double nonlinear analysis considering material nonlinearity and geometric nonlinearity were discussed in detail to compare the stability performance of the ellipse-like suspen-dome and the single-layer reticulated shell. The results showthat the cable-strut system increases the integrity of the suspen-dome, and moderates the sensibility of the single-layer reticulated shell to initial geometric imperfection. However, it has little influence on integral rigidity, fundamental vibration frequencies, linear ultimate live loads, and geometric nonlinear ultimate live loads without initial imperfection. When considering the material nonlinearity and initial imperfection, a significant reduction occurs in the ultimate stability capacities of these two structures. In this case, the suspen-dome with a lowrise-span ratio is sensitive to the initial imperfection and material nonlinearity. In addition, the distribution pattern of live loads significantly influences the instability modes of the structure, and the uniform live load with full span is not always the most dangerous case.
文摘As a new frontier in catalysis field,single-atom catalysts(SACs)hold unique electronic structure and high atom utilization,which have displayed unprecedented activity and selectivity toward a wide range of catalytic reactions.However,many reported SACs are susceptible to Ostwald ripening process in high temperature environment or long-term catalytic application,which will cause sintering and deactivation.This is due to the weak interaction between the metal atom and supports.The regeneration and recycling of deactivated catalysts will greatly increase the time and economic cost of industrial production.Therefore,it is necessary to develop SACs with excellent thermal stability to meet the industrial demands.Here,we discuss the fundamental comprehension of the stability of thermally stable SACs obtained from different synthesis methods.The influences of the speciation of metal centers and coordination environments on thermal stability are summarized.The importance of using novel in situ and operando characterizations to reveal dynamic structural evolution under synthesis and reaction conditions and to identify active sites of thermally stable SACs is highlighted.The mechanistic understanding of the unique role of thermally stable SACs in thermocatalytic application is also discussed.At last,a brief perspective on the remaining challenges and future directions of thermally stable SACs is presented.
文摘Permanent magnetic actuator （PMA）, as a new electronic actuator of vacuum circuit breakers, certainly will be used to replace the traditional mechanical actuator. It has such advantages as simple structure, high reliability, free maintenance, and so on. This paper summarizes the development, structure, magnetic analysis, character analysis, and control strategy of PMA, and also predicts the future trend of PMA development
基金Supported by the Education Department of Henan Province(200511517007)
文摘In this paper, the nonlinear singular stabilization, H∞ control problem of systems with ordinary homogeneous properties is considered. At first, we discuss the stabilization problems of nonlinear systems with homogeneous. Secondly, by vitue of Hamilton-Jacobi-Isaacs equations or inequalities, we solve regular H∞ of nonlinear systems with homogeneous properties. To overcome the H∞ problem of singular nonlinear system, we try to transform inputs of the singular nonlinear system into two parts： regular part input and singular part input. Following the previous results, we solve the singular nonlinear system H∞ control, we give the Lyapunov function and the state feedback controller of the singular nonlinear systems with homogeneous properties.
文摘The stability of single layer armour units on low crested and submerged breakwaters has been investigated in 2D hydraulic model tests. Armour unit movements including settlements, rocking and displacements have been determined. The effect of freeboard, packing density and wave steepness on the armour layer stability on crest, front and rear slope has been investigated. Armour units were mostly displaced in the most upper part of the seaward slope and at the seaward side of the crest. Damage on the crest was progressing towards the rear slope. About 40% to 50% larger armour units are required on the seaward slope and crest of low crested structures （as compared to conventional high crested breakwaters）. About 35% larger armour units are required on the rear slope. Larger armour units are not required on submerged breakwaters if the water depth on the crest exceeds 40% of design wave height.
文摘Objective： The aim of the study was to evaluate the impact of the chemosensitivity assay in vitro and establish a standard process of measuring the anti-cancer drug sensitivity with MTT assay. Methods： Some influencing factors of MTT assay in studying the sensitivity of human peripheral blood mononuclear cells （PBMC） to anti-cancer drugs were observed, including red blood cells, platelets, three different kinds of DMSO and different concentrations of MTT. Meanwhile the stability of tumor drug-coated plate was monitored. Results： The red blood cells and platelets may affect the results at a certain range of concentration. Analytical pure DMSO, both imported and domestic reagents showed the same color with MI3-, and the A values of the reaction were dependent on MTT dose. The stability of the freeze-drying drug-coated plates was superior to non freeze-drying ones. Conclusion： To make clear and definite all kinds of influencing factors might contribute to a kind of standard MTT assay for drug sensitivity test in vitro.
基金Supported by the Yunnan Provincial Sciences and Technology Department,China(No.2007AD009)the National Natural Science Foundation of China(No.31272680)the Ministry of Science and Technology of China(No.2013AA065805)
文摘In this paper,we investigated the effects of temperature,oxygen,antioxidants,and corn germ oil on the stability of astaxanthin from Haematococcus pluvialis under different storage conditions,and changes in the composition of astaxanthin esters during storage using high performance liquid chromatography and spectrophotometry.Oxygen and high temperatures(22–25°C) significantly reduced the stability of astaxanthin esters.Corn germ oil and antioxidants(ascorbic acid and vitamin E)failed to protect astaxanthin from oxidation,and actually significantly increased the instability of astaxanthin.A change in the relative composition of astaxanthin esters was observed after 96 weeks of long-term storage.During storage,the relative amounts of free astaxanthin and astaxanthin monoesters declined,while the relative amount of astaxanthin diesters increased.Thus,the ratio of astaxanthin diester to monoester increased,and this ratio could be used to indicate if astaxanthin esters have been properly preserved.If the ratio is greater than 0.2,it suggests that the decrease in astaxanthin content could be higher than 20%.Our results show that storing algal powder from H.pluvialis or other natural astaxanthin products under vacuum and in the dark below 4°C is the most economical and applicable storage method for the large-scale production of astaxanthin from H.pluvialis.This storage method can produce an astaxanthin preservation rate of at least 80%after 96 weeks of storage.
