A model is developed to calculate emission spectrum of non-local thermodynamic equilibrium(NLTE) plasmas. The Collisional-Radiative model is adopted for non-LTE population calculations. Configuration-averaged rate coe...A model is developed to calculate emission spectrum of non-local thermodynamic equilibrium(NLTE) plasmas. The Collisional-Radiative model is adopted for non-LTE population calculations. Configuration-averaged rate coefficients that needed in the rate equations are obtained based on the first order perturbation theory. The Hatree-Fock-Slater self-consistent-field method is used to calculate electron wave functions. The present model is applied to the calculation of emissivity from a Ar plasma. The features of the spectra are in good agreement with those calculated by other theoretical models, but the data of the integrated emissivity differ by a factor 2～8.展开更多
In recent years, plasma technology has emerged as a novel technique for the manufacture of newer and better materials. The thermodynamic state of thermal plasma approaches local thermodynamic equilibrium, temperature ...In recent years, plasma technology has emerged as a novel technique for the manufacture of newer and better materials. The thermodynamic state of thermal plasma approaches local thermodynamic equilibrium, temperature of heavy particle is higher （ 10^3 -10^4 K ） and the temperature range of electron is 10^4- 10^6 K. The state of thermal plasma can be described by an unitive thermodynamic temperature. The characteristics of thermal plasmas are high temperature, high enthalpy, high energy density, controllable atmosphere, steep temperature gradient etc. It has been widely applied in field of processing, metallurgy, material, chemical engineering, environmental protection.展开更多
文摘A model is developed to calculate emission spectrum of non-local thermodynamic equilibrium(NLTE) plasmas. The Collisional-Radiative model is adopted for non-LTE population calculations. Configuration-averaged rate coefficients that needed in the rate equations are obtained based on the first order perturbation theory. The Hatree-Fock-Slater self-consistent-field method is used to calculate electron wave functions. The present model is applied to the calculation of emissivity from a Ar plasma. The features of the spectra are in good agreement with those calculated by other theoretical models, but the data of the integrated emissivity differ by a factor 2～8.
文摘In recent years, plasma technology has emerged as a novel technique for the manufacture of newer and better materials. The thermodynamic state of thermal plasma approaches local thermodynamic equilibrium, temperature of heavy particle is higher （ 10^3 -10^4 K ） and the temperature range of electron is 10^4- 10^6 K. The state of thermal plasma can be described by an unitive thermodynamic temperature. The characteristics of thermal plasmas are high temperature, high enthalpy, high energy density, controllable atmosphere, steep temperature gradient etc. It has been widely applied in field of processing, metallurgy, material, chemical engineering, environmental protection.
