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非溶剂对成膜过程凝胶速率的影响 被引量:3
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作者 魏永明 许振良 杨晓天 《膜科学与技术》 CAS CSCD 北大核心 2006年第5期37-41,共5页
基于Flory-Huggins高分子溶液理论,计算了聚砜(PSF)-二甲基乙酰胺(DMAc)-非溶剂铸膜体系的三元相图,其中二甲基乙酰胺(DMAc)为溶剂,水、甘油、乙醇和正已烷为非溶剂.通过相图分析了不同非溶剂对凝胶时间的影响,同时考虑了扩散的影响.... 基于Flory-Huggins高分子溶液理论,计算了聚砜(PSF)-二甲基乙酰胺(DMAc)-非溶剂铸膜体系的三元相图,其中二甲基乙酰胺(DMAc)为溶剂,水、甘油、乙醇和正已烷为非溶剂.通过相图分析了不同非溶剂对凝胶时间的影响,同时考虑了扩散的影响.根据计算结果得到如下结论:双节线或旋节线与聚合物-溶剂轴的距离越近,凝胶时间越短;非溶剂与溶剂的相互扩散速度越快,凝胶时间越短;联结线的斜率越小,即分相时聚合物稀相中非溶剂的量越少,凝胶时间越短。 展开更多
关键词 三元相图 凝胶速率 凝胶时间 瞬时分相 延迟分相
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不同添加剂对聚偏氟乙烯膜结构和性能的影响 被引量:8
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作者 李倩 许振良 +1 位作者 俞丽芸 袁国林 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2010年第2期80-83,共4页
利用非溶剂相转化法(NIPS),以N,N-二甲基乙酰胺(DMAc)为溶剂,聚乙烯吡咯烷酮(PVPK30)和一水合氯化锂(LiCl·H2O)为混合添加剂,改变PVPK30-LiCl·H2O配比得到不同性能和结构的聚偏氟乙烯(PVDF)膜。考察了不同种类添加剂(PVP、LiC... 利用非溶剂相转化法(NIPS),以N,N-二甲基乙酰胺(DMAc)为溶剂,聚乙烯吡咯烷酮(PVPK30)和一水合氯化锂(LiCl·H2O)为混合添加剂,改变PVPK30-LiCl·H2O配比得到不同性能和结构的聚偏氟乙烯(PVDF)膜。考察了不同种类添加剂(PVP、LiCl·H2O、H2O和PEG200)及不同配比的PVPK30-LiCl·H2O添加剂对PVDF成膜分相延时时间、分相速率的影响。实验结果表明,采用PVPK30为添加剂,铸膜液呈瞬时分相行为,膜通量很大;增大混合添加剂中PVPK30/LiCl·H2O的比例,会增加液液分相速率,使膜结构中的大孔贯通整个膜结构。 展开更多
关键词 聚偏氟乙烯 混合添加剂 分相延迟时间 分相速率
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Numerical analysis on car-following traffic flow models with delay time
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作者 李莉 施鹏飞 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2006年第2期204-209,共6页
Effects of the speed relaxation time on the optimal velocity car-following model (OVM) with delay time due to driver reaction time proposed by Bando et al.(1995) were studied by numerical methods. Results showed that ... Effects of the speed relaxation time on the optimal velocity car-following model (OVM) with delay time due to driver reaction time proposed by Bando et al.(1995) were studied by numerical methods. Results showed that the OVM including the delay is not physically sensitive to the speed relaxation times. A modified car-following model is proposed to overcome the deficiency. Analyses of the linear stability of the modified model were conducted. It is shown that coexisting flows appear if the initial homogeneous headway of the traffic flow is between critical values. In addition, phase transitions occur on varying the initially homogeneous headway. 展开更多
关键词 Car-following models Delay time Relaxation time Phase transitions
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Relative position determination of a lunar rover using the biased differential phase delay of same-beam VLBI 被引量:12
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作者 CHEN Ming LIU QingHui +2 位作者 WU YaJun ZHAO RongBing DAI ZhiQiang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第12期2284-2295,共12页
When only data transmission signals with a bandwidth of 1 MHz exist in the rover, the position can be obtained using the differential group delay data of the same-beam very long baseline interferometry (VLBI). The rel... When only data transmission signals with a bandwidth of 1 MHz exist in the rover, the position can be obtained using the differential group delay data of the same-beam very long baseline interferometry (VLBI). The relative position between a lunar rover and a lander can be determined with an error of several hundreds of meters. When the guidance information of the rover is used to determine relative position, the rover's wheel skid behavior and integral movement may influence the accuracy of the determined position. This paper proposes a new method for accurately determining relative position. The differential group delay and biased differential phase delay are obtained from the same-beam VLBI observation, while the modified biased differential phase delay is obtained using the statistic mean value of the differential group delay and the biased phase delay as basis. The small bias in the modified biased phase delay is estimated together with other parameters when the relative position of the rover is calculated. The effectiveness of the proposed method is confirmed using the same-beam VLBI observation data of SELENE. The radio sources onboard the rover and the lander are designed for same-beam VLBI observations. The results of the simulations of the differential delay of the same-beam VLBI observation between the rover and the lander show that the differential delay is sensitive to relative position. An approach to solving the relative position and a strategy for tracking are also introduced. When the lunar topography data near the rover are used and the observations are scheduled properly, the determined relative position of the rover may be nearly as accurate as that solved using differential phase delay data. 展开更多
关键词 same-beam VLBI biased differential phase delay relative position determination lunar rover
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Methods for optical phase retardation measurement:A review 被引量:6
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作者 ZHANG Peng TAN YiDong +1 位作者 LIU WeiXin CHEN WenXue 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第5期1155-1163,共9页
Optical-phase-retardation elements are widely used in many fields.Accurate measurement of their phase retardation is crucial to the practical effect of the element's processing and application.The development and ... Optical-phase-retardation elements are widely used in many fields.Accurate measurement of their phase retardation is crucial to the practical effect of the element's processing and application.The development and present situation of the methods for optical phase retardation measurement are reviewed,with the wave plate,the most typical phase-retardation element,as an example.The latest research progress in this field is introduced;the principles and characteristics of individual measurement method are summarized and discussed.Three new methods based on laser frequency splitting or laser feedback are presented in detail,in which the laser is not only regarded as a light source but also plays a role of sensor.Moreover,no standard wave plates are needed and arbitrary phase retardation can be measured.Traceability,high precision and high repeatability are achieved as well. 展开更多
关键词 optical measurement phase retardation wave plate frequency splitting laser feedback
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