With a particular focus on the connection between liquid flow distribution and gas-liquid mass transfer in monolithic beds in the Taylor flow regime, hydrodynamic and gas-liquid mass transfer experiments were carriedo...With a particular focus on the connection between liquid flow distribution and gas-liquid mass transfer in monolithic beds in the Taylor flow regime, hydrodynamic and gas-liquid mass transfer experiments were carriedout in a column with a monolithic bed of cell density of 50 cpsi with trio different distributors （nozzle and packed bed distributors）. Liquid saturation in individual channels was measured by using self-made micro-conductivity probes. A mal-distribution factor was used to evaluate uniform degree of phase distribution in monoliths. Overall bed pressure drop and mass transfer coefficients were measured. For liquid flow distribution and gas-liquid masstransfer, it is found that the superficial liquid velocity is a crucial factor and the packed bed distributor is better than the nozzle distributor. A semi-theoretical analysis using single channel models shows that the packed bed distributor always yields shorter and uniformly distributed liquid slugs compared to the nozzle distributor, which in turn ensures a better mass transfer performance. A bed scale mass transfer model is proposed by employing the single channel models in individual channels and incorporating effects of non-uniform liquid distribution along the bedcross-section. The model predicts the overall gas-liquid mass transfer coefficient wig a relative error within ＋30%.展开更多
This work was focused on the measurement of the solubility of hydrogen （H2） in anthraquinone working solution at temperatures of 30.0-80.0℃ and pressures of 0.2-3.0 MPa by the method of experimental and COSMO-RS mo...This work was focused on the measurement of the solubility of hydrogen （H2） in anthraquinone working solution at temperatures of 30.0-80.0℃ and pressures of 0.2-3.0 MPa by the method of experimental and COSMO-RS model study. The influence of various factors, i.e., including pressure, temperature and solvent volume ratio, on H2 solubility was investigated. According to the experimental results, H2 solubility in anthraquinone working solution increases with the increase of pressure. At low pressures, the temperature had little effect on H2 solubility while under high pressures H2 solubility increases with increasing temperature. Henry＇s constant In/-/has a good linear relationship with 1/T （lnH = -- 1319.1/T ＋ 9.91 ）. The effect of volume ratio of trioctyl phos- phate to trimethylbenzene on the solubility of hydrogen was studied and the results showed that increasing the amount of trimethylbenzene was conducive to the dissolution of hydrogen. In addition, there is a linear relationship between ln（（Po - Pe） / （Pt - Pe）） and the time t. Gas-liquid mass transfer coefficient was obtained by calculating the slope of the line.展开更多
abstract The volumetric mass transfer coefficient kLa of gases （H2, CO, CO2） and mass transfer coefficient kL on liquid par-affin side were studied using the dynamic absorption method in slurry bubble column reactor...abstract The volumetric mass transfer coefficient kLa of gases （H2, CO, CO2） and mass transfer coefficient kL on liquid par-affin side were studied using the dynamic absorption method in slurry bubble column reactors under elevated temperature and elevated pressure. Meanwhile, gas-holdup and gas-liquid interfacial area a were obtained. The effects of temperature, pressure, superficial gas velocity and solid concentration on the mass transfer coeffi-cient were discussed. Experimental results show that the gas-liquid volumetric mass transfer coefficient kLa and interfacial area a increased with the increase of pressure, temperature, and superficial gas velocity, and decreased with the slurry concentration. The mass transfer coefficient kL increased with increasing superficial gas velocity and temperature and decreased with higher slurry concentration, while it changed slightly with pressure. Ac-cording to analysis of experimental data, an empirical correlation is obtained to calculate the values of kLa for H2 （CO, CO2） in the gas-paraffin-quartz system in a bubble column under elevated temperature and elevated pressure.展开更多
基金Supported by the State Key Development Program for Basic Research of China (2006CB202503)
文摘With a particular focus on the connection between liquid flow distribution and gas-liquid mass transfer in monolithic beds in the Taylor flow regime, hydrodynamic and gas-liquid mass transfer experiments were carriedout in a column with a monolithic bed of cell density of 50 cpsi with trio different distributors （nozzle and packed bed distributors）. Liquid saturation in individual channels was measured by using self-made micro-conductivity probes. A mal-distribution factor was used to evaluate uniform degree of phase distribution in monoliths. Overall bed pressure drop and mass transfer coefficients were measured. For liquid flow distribution and gas-liquid masstransfer, it is found that the superficial liquid velocity is a crucial factor and the packed bed distributor is better than the nozzle distributor. A semi-theoretical analysis using single channel models shows that the packed bed distributor always yields shorter and uniformly distributed liquid slugs compared to the nozzle distributor, which in turn ensures a better mass transfer performance. A bed scale mass transfer model is proposed by employing the single channel models in individual channels and incorporating effects of non-uniform liquid distribution along the bedcross-section. The model predicts the overall gas-liquid mass transfer coefficient wig a relative error within ＋30%.
基金Supported by the National Natural Science Foundation of China(Nos.21476009,21406007,and U1462104)
文摘This work was focused on the measurement of the solubility of hydrogen （H2） in anthraquinone working solution at temperatures of 30.0-80.0℃ and pressures of 0.2-3.0 MPa by the method of experimental and COSMO-RS model study. The influence of various factors, i.e., including pressure, temperature and solvent volume ratio, on H2 solubility was investigated. According to the experimental results, H2 solubility in anthraquinone working solution increases with the increase of pressure. At low pressures, the temperature had little effect on H2 solubility while under high pressures H2 solubility increases with increasing temperature. Henry＇s constant In/-/has a good linear relationship with 1/T （lnH = -- 1319.1/T ＋ 9.91 ）. The effect of volume ratio of trioctyl phos- phate to trimethylbenzene on the solubility of hydrogen was studied and the results showed that increasing the amount of trimethylbenzene was conducive to the dissolution of hydrogen. In addition, there is a linear relationship between ln（（Po - Pe） / （Pt - Pe）） and the time t. Gas-liquid mass transfer coefficient was obtained by calculating the slope of the line.
基金Supported by the National Natural Science Foundation of China(20776018)the Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions(CIT&TCD20130325)
文摘abstract The volumetric mass transfer coefficient kLa of gases （H2, CO, CO2） and mass transfer coefficient kL on liquid par-affin side were studied using the dynamic absorption method in slurry bubble column reactors under elevated temperature and elevated pressure. Meanwhile, gas-holdup and gas-liquid interfacial area a were obtained. The effects of temperature, pressure, superficial gas velocity and solid concentration on the mass transfer coeffi-cient were discussed. Experimental results show that the gas-liquid volumetric mass transfer coefficient kLa and interfacial area a increased with the increase of pressure, temperature, and superficial gas velocity, and decreased with the slurry concentration. The mass transfer coefficient kL increased with increasing superficial gas velocity and temperature and decreased with higher slurry concentration, while it changed slightly with pressure. Ac-cording to analysis of experimental data, an empirical correlation is obtained to calculate the values of kLa for H2 （CO, CO2） in the gas-paraffin-quartz system in a bubble column under elevated temperature and elevated pressure.
