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新型低温泡沫玻璃陶瓷复合建筑保温材料制备 被引量:11
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作者 仝凡 王小山 +3 位作者 屠浩驰 阮华 李陆宝 王智宇 《材料科学与工程学报》 CAS CSCD 北大核心 2021年第4期585-589,共5页
以Na_(2)O-B_(2)O_(3)-Al_(2)O_(3)-SiO_(2)-H_(2)O系水合玻璃溶胶为基体,外掺一定尺寸的晶相矿物粉末粉煤灰,采用低温发泡及高温去羟基化二步热处理工艺制备低温泡沫玻璃陶瓷复合材料。粉煤灰引入的细小石英晶粒均匀分布于玻璃基体中,... 以Na_(2)O-B_(2)O_(3)-Al_(2)O_(3)-SiO_(2)-H_(2)O系水合玻璃溶胶为基体,外掺一定尺寸的晶相矿物粉末粉煤灰,采用低温发泡及高温去羟基化二步热处理工艺制备低温泡沫玻璃陶瓷复合材料。粉煤灰引入的细小石英晶粒均匀分布于玻璃基体中,通过相互搭接形成一定的骨架支撑作用,增大了泡沫材料的孔壁强度,减小了高温去羟基化热处理过程中材料内羟基含量降低的同时伴随的收缩形变。研究结果表明,粉煤灰引入后,500℃下,材料的体积收缩由31%降至1%~5%,在粉煤灰外掺量达20~25 wt.%,去羟基化热处理时间在3 h及以上时,可制备出容重为192~256 kg/m 3,软化系数达0.85~0.95,导热系数在0.06 W/(m·K)左右,综合性能优良的低温泡沫玻璃陶瓷复合建筑保温材料。 展开更多
关键词 胶体化学法 水合玻璃 晶体 泡沫玻璃陶瓷 复合材料
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Research on New Silica Sol Matrix Used in Fluid Catalytic Cracking Reaction 被引量:3
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作者 Zhang Zhongdong Liu Zhaoyong +3 位作者 Yan Zifeng Wang Yi Zhang Haitao Wang Zhifeng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第2期29-33,共5页
A new silica sol binder was obtained by mixing the acid-modified aluminium sulfate and water glass. The effect of SiO2 concentration in sodium silicate, pH value and polymerization was investigated. The new silica sol... A new silica sol binder was obtained by mixing the acid-modified aluminium sulfate and water glass. The effect of SiO2 concentration in sodium silicate, pH value and polymerization was investigated. The new silica sol binder, which possessed abundant pore volume and suitable acid amount, was an ideal component for preparing cracking catalyst. As a result, the corresponding catalyst comprising the new binder showed excellent performance. Compared with the reference sample, the liquefied petroleum gas(LPG) and propylene yield obtained over this catalyst increased by 3.49 and 1.20 percentage points, respectively. The perfect pore structure and suitable Lewis acid amount of new silica sol were the possible reason leading to its outstanding performance. 展开更多
关键词 silica sol BINDER pH value LPG PROPYLENE CATALYST
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