Solid oxide fuel cell (SOFC) has been identified as an effective and clean alternative choice for marine power system.This paper emphasizes on the dynamic modeling of SOFC power system and its performance based upon m...Solid oxide fuel cell (SOFC) has been identified as an effective and clean alternative choice for marine power system.This paper emphasizes on the dynamic modeling of SOFC power system and its performance based upon marine operating circumstance.A SOFC power system model has been provided considering thermodynamic and electrochemical reaction mechanism.Subcomponents of lithium ion battery, power conditioning unit, stack structure and controller are integrated in the model.The dynamic response of the system is identified according to the inertia of its subcomponent and controller.Validation of the whole system simulation at steady state and transit period are presented, concerning the effects of thermo inertia, control strategy and seagoing environment.The simulation results show reasonable accuracy compare with lab test.The models can be used to predict performance of a SOFC power system and identify the system response when part of the component parameter is adjusted.展开更多
This article aims to investigate the transient behavior of a planar direct internal reforming solid oxide fuel cell （DIR-SOFC） comprehensively. A one-dimensional dynamic model of a planar D1R-SOFC is first developed...This article aims to investigate the transient behavior of a planar direct internal reforming solid oxide fuel cell （DIR-SOFC） comprehensively. A one-dimensional dynamic model of a planar D1R-SOFC is first developed based on mass and energy balances, and electrochemical principles. Further, a solution strategy is presented to solve the model, and the International Energy Agency （IEA） benchmark test is used to validate the model. Then, through model-based simulations, the steady-state performance of a co-flow planar DIR-SOFC under specified initial operating conditions and its dynamic response to introduced operating parameter disturbances are studied. The dynamic responses of important SOFC variables, such as cell temperature, current density, and cell voltage are all investigated when the SOFC is subjected to the step-changes in various operating parameters including both the load current and the inlet fuel and air flow rates. The results indicate that the rapid dynamics of the current density and the cell voltage are mainly influenced by the gas composition, particularly the H2 molar fraction in anode gas channels, while their slow dynamics are both dominated by the SOLID （including the PEN and interconnects） temperature. As the load current increases, the SOLID temperature and the maximum SOLID temperature gradient both increase, and thereby, the cell breakdown is apt to occur because of excessive thermal stresses. Changing the inlet fuel flow rate might lead to the change in the anode gas composition and the consequent change in the current density distribution and cell voltage. The inlet air flow rate has a great impact on the cell temperature distribution along the cell, and thus, is a suitable manipulated variable to control the cell temperature.展开更多
The article reviews a brief literature on the modeling of hydrogen storage device for fuel cell. Different dimensional approaches in modeling hydrogen absorption/desorption in a metal hydride reactor for use in fuel c...The article reviews a brief literature on the modeling of hydrogen storage device for fuel cell. Different dimensional approaches in modeling hydrogen absorption/desorption in a metal hydride reactor for use in fuel cell are summarized. Mathematical modeling equations involved are also stated. The effect of various operating parameters such as temperature, concentration, viscosity, thermal conductivity and time on the gas is also verified. The importance of various simulation software with reference to their major functions is also identified. The review concludes on the opportunities and challenges with the use of hydrogen as an alternative renewable energy.展开更多
文摘Solid oxide fuel cell (SOFC) has been identified as an effective and clean alternative choice for marine power system.This paper emphasizes on the dynamic modeling of SOFC power system and its performance based upon marine operating circumstance.A SOFC power system model has been provided considering thermodynamic and electrochemical reaction mechanism.Subcomponents of lithium ion battery, power conditioning unit, stack structure and controller are integrated in the model.The dynamic response of the system is identified according to the inertia of its subcomponent and controller.Validation of the whole system simulation at steady state and transit period are presented, concerning the effects of thermo inertia, control strategy and seagoing environment.The simulation results show reasonable accuracy compare with lab test.The models can be used to predict performance of a SOFC power system and identify the system response when part of the component parameter is adjusted.
基金Supported by the National High Technology Research and Development Program of China (2006AA05Z148)
文摘This article aims to investigate the transient behavior of a planar direct internal reforming solid oxide fuel cell （DIR-SOFC） comprehensively. A one-dimensional dynamic model of a planar D1R-SOFC is first developed based on mass and energy balances, and electrochemical principles. Further, a solution strategy is presented to solve the model, and the International Energy Agency （IEA） benchmark test is used to validate the model. Then, through model-based simulations, the steady-state performance of a co-flow planar DIR-SOFC under specified initial operating conditions and its dynamic response to introduced operating parameter disturbances are studied. The dynamic responses of important SOFC variables, such as cell temperature, current density, and cell voltage are all investigated when the SOFC is subjected to the step-changes in various operating parameters including both the load current and the inlet fuel and air flow rates. The results indicate that the rapid dynamics of the current density and the cell voltage are mainly influenced by the gas composition, particularly the H2 molar fraction in anode gas channels, while their slow dynamics are both dominated by the SOLID （including the PEN and interconnects） temperature. As the load current increases, the SOLID temperature and the maximum SOLID temperature gradient both increase, and thereby, the cell breakdown is apt to occur because of excessive thermal stresses. Changing the inlet fuel flow rate might lead to the change in the anode gas composition and the consequent change in the current density distribution and cell voltage. The inlet air flow rate has a great impact on the cell temperature distribution along the cell, and thus, is a suitable manipulated variable to control the cell temperature.
文摘The article reviews a brief literature on the modeling of hydrogen storage device for fuel cell. Different dimensional approaches in modeling hydrogen absorption/desorption in a metal hydride reactor for use in fuel cell are summarized. Mathematical modeling equations involved are also stated. The effect of various operating parameters such as temperature, concentration, viscosity, thermal conductivity and time on the gas is also verified. The importance of various simulation software with reference to their major functions is also identified. The review concludes on the opportunities and challenges with the use of hydrogen as an alternative renewable energy.
