The development of high-performance oxygen evolution reaction catalysts with low iridium content is the key to the scale-up of proton exchange membrane water electrolyzer(PEMWE)for green hydrogen production.Single-sit...The development of high-performance oxygen evolution reaction catalysts with low iridium content is the key to the scale-up of proton exchange membrane water electrolyzer(PEMWE)for green hydrogen production.Single-site electrocatalysts with maximized atomic efficiency are held as promising candidates but still suffer from inadequate activity and stability in practical electrolyzer due to the low site density.Here,we proposed a NaNO_(3)-assistant thermal decomposition strategy for the preparation of high-density Ir single sites on MnO_(2)substrate(NaNO_(3)-H-Ir-MnO_(2)).Direct spectroscopic evidence suggests the inclusion of NaNO_(3) accelerates the transformation of Ir-Cl to Ir-O coordination,thus generating uniform dispersed high-density Ir single sites in the products.The optimized H-Ir-MnO_(2)demonstrates not only high intrinsic activity in a three-electrode set-up but also boosted performance in scalable PEMWE,requiring a cell voltage of only 1.74 V to attain a high current density of 2 A cm^(-2) at a low Ir loading of 0.18 mgIr cm^(-2).This work offers a new insight for enhancing the industrial practicality of Ir-based single site catalysts.展开更多
A 1.60μm laser diode and electroabsorption modulator monolithically integrated with a novel dual-waveguide spot-size converter output for low-loss coupling to a cleaved single-mode optical fiber are demonstrated.The ...A 1.60μm laser diode and electroabsorption modulator monolithically integrated with a novel dual-waveguide spot-size converter output for low-loss coupling to a cleaved single-mode optical fiber are demonstrated.The devices emit in a single transverse and quasi single longitudinal mode with an SMSR of 25.6dB.These devices exhibit a 3dB modulation bandwidth of 15.0GHz,and modulator DC extinction ratios of 16.2dB.The output beam divergence angles of the spot-size converter in the horizontal and vertical directions are as small as 7.3°×18.0°,respectively,resulting in a 3.0dB coupling loss with a cleaved single-mode optical fiber.展开更多
A novel 1 55μm laser diode with spot size converter is designed and fabricated using conventional photolithography and chemical wet etching process.For the laser diode,a ridge double core structure is employed.For...A novel 1 55μm laser diode with spot size converter is designed and fabricated using conventional photolithography and chemical wet etching process.For the laser diode,a ridge double core structure is employed.For the spot size converter,a buried ridge double core structure is incorporated.The laterally tapered active core is designed and optically combined with the thin and wide passive core to control the size of mode.The laser diode threshold current is measured to be 40mA together with high slop efficiency of 0 35W/A.The beam divergence angles in the horizontal and vertical directions are as small as 14 89°×18 18°,respectively,resulting in low coupling losses with a cleaved optical fiber (3dB loss).展开更多
A novel optoelectronic functional circuit with heterojunction phototransistors (HPTs) and resonant tunneling diodes (RTDs) is described,which presents the function of both photocurrent switching and photo-current latc...A novel optoelectronic functional circuit with heterojunction phototransistors (HPTs) and resonant tunneling diodes (RTDs) is described,which presents the function of both photocurrent switching and photo-current latching.These behaviors have been demonstrated by simulating experiments and circuit simulation.Furthermore,basing on photo-current latching behavior,various photo-controlled basis logic elements such as delayed flip-flop (DFF) can be designed and fabricated.展开更多
The ultrafast dynamics through conical intersections in 2,6-dimethylpyridine has been studied by femtosecond time-resolved photoelectron imaging coupled with time-resolved mass spectroscopy. Upon absorption of 266 nm ...The ultrafast dynamics through conical intersections in 2,6-dimethylpyridine has been studied by femtosecond time-resolved photoelectron imaging coupled with time-resolved mass spectroscopy. Upon absorption of 266 nm pump laser, 2,6-dimethylpyridine is excited to the S2 state with a ππ character from So state. The time evolution of the parent ion signals consists of two exponential decays. One is a fast component on a timescale of 635 fs and the other is a slow component with a timescale of 4.37 ps. Time-dependent photo- electron angular distributions and energy-resolved photoelectron spectroscopy are extracted from time-resolved photoelectron imaging and provide the evolutive information of S2 state. In brief, the ultrafast component is a population transfer from S2 to S1 through the S2/S1 conical intersections, the slow component is attributed to simultaneous IC from the S2 state and the higher vibrational levels of S1 state to So state, which involves the coupling of S2/S0 and S1/So conical intersections. Additionally, the observed ultrafast S2--＋S1 transition occurs only with an 18% branching ratio.展开更多
Self-made TiO2 nanoparticles were used as photoelectrode material of dye sensitized solar cell. The TiO2 thin film coats through spreading nanoparticles evenly onto the ITO glass via self-made spin-heat platform, and ...Self-made TiO2 nanoparticles were used as photoelectrode material of dye sensitized solar cell. The TiO2 thin film coats through spreading nanoparticles evenly onto the ITO glass via self-made spin-heat platform, and then TiO2 thin film is soaked in the dye N-719 more than 12 h to prepare the photoelectrode device. The TiO2 nanoparticles produced by electric-discharge-nanofluid-process have premium anatase crystal property, and its diameter can be controlled within a range of 20-50 nm. The surface energy zeta potential of nanofluid is from -22 mV to -28.8 mV, it is a stable particle suspension in the deionized water. A trace of surfactant Triton X-100 put upon the surface of ITO glass can produce a uniform and dense TiO2 thin film and heating up the spin platform to 200 oC is able to eliminate mixed surfac-tant. Self-made TiO2 film presents excellent dye absorption performance and even doesn＇t need heat treatment procedure to enhance essential property. Results of energy analysis show the thicker film structure will increase the short-circuit current density that causes higher conversion efficiency. But, as the film structure is large and thick, both the open-circuit voltage and fill factor will decline gradually to lead bad efficiency of dye-sensitized solar cell.展开更多
This paper describes the development of a timer based voltage to frequency converter(V FC).Timer LM555is used in astable multivibrator mode with two OPTO-LDRs(light dependent resistors)in the circuitry.The frequency o...This paper describes the development of a timer based voltage to frequency converter(V FC).Timer LM555is used in astable multivibrator mode with two OPTO-LDRs(light dependent resistors)in the circuitry.The frequency of timer output waveform which is measured using a digital storage oscillator(DSO)is almost linearly proportional to the applied input voltage.Hence we obtain a linear relationship between the frequency of timer output waveform and the input voltage.Because of its quasi-digital output,the main advantages of this developed converter are linear input-output relationship,small size,easy portabilityand high cost performance.In addition,the timer output waveform can be directly interfaced with personal computer or microprocessor/microcontroller for further processing of the input voltage signal without intervening any analog-to-digital converter(ADC).展开更多
MXenes,a new family of two-dimensional(2D)materials,have received extensive interest due to their fascinating physicochemical properties,such as outstandinglight-to-heat conversion efficiency.However,the photothermal ...MXenes,a new family of two-dimensional(2D)materials,have received extensive interest due to their fascinating physicochemical properties,such as outstandinglight-to-heat conversion efficiency.However,the photothermal conversion mechanism of MXenes is still poorly understood.Here,by using femtosecond visible and mid-infrared transient absorption spectroscopy,the electronic energy dissipation dynamics of MXene(Ti_(3)C_(2)T_(x))nanosheets dispersed in various solvents are carefully studied.Our results indicate that the lifetime of photoexcited MXene is strongly dependent on the surrounding environment.Especially,the interfacial electron-vibration coupling between the MXene nanosheets and the adjacent solvent molecules is directly observed following the ultrafast photoexcitation of MXene.It suggests that the interfacial interactions at the MXene-solvent interface play a critical role in the ultrafast energy transport dynamics of MXene,which offers a potentially feasible route for tailoring the light conversion properties of 2D systems.展开更多
In order to solve excessive insertion loss and low on/off ratio in quantum well reflection-type waveguide optical switches, a novel InGaAs/InAlAs coupled quantum well structure is proposed. In the case of low applied ...In order to solve excessive insertion loss and low on/off ratio in quantum well reflection-type waveguide optical switches, a novel InGaAs/InAlAs coupled quantum well structure is proposed. In the case of low applied electric field （F=19 kV/cm） and low absorption loss （ et ~ 61.2 cm-1）, a large negative field-induced refractive index change （ A n=-0.0134） is obtained in the novel coupled quantum well structure at the operating wavelength （ 2 =1550 rim）. The value is larger by over one to two order of maL, nitude comoared to that in a rectanaular ouantum well （ROW） on the above same work conditions.展开更多
The solar energy conversion system is very interesting alternative on supplement the electric system generation, due to the persistent cost reduction of the overall system and cleaner power generation. To obtain a sta...The solar energy conversion system is very interesting alternative on supplement the electric system generation, due to the persistent cost reduction of the overall system and cleaner power generation. To obtain a stable voltage from an input supply （PV cells） that is higher and lower than the output, a high efficiency and minimum ripple DC-DC converter required in the system for residential power production. Buck-boost converters make it possible to efficiently convert a DC voltage to either a lower or higher voltages. Buck-boost converters are especially useful for PV maximum power tracking purposes, where the objective is to draw maximum possible power from solar panels at all times, regardless of the load. This paper analyzes and describes step by step the process of designing, and simulation of high efficiency low ripple voltage buck-boost DC-DC converter for the photovoltaic solar conversion system applicable to a （typical） single family home based on battery-based systems. The input voltage can typically change from （20 V） initially, down to （5 V）, and provide a regulated voltage within the range of the battery （12 V）. PLECS simulation results provide strong evidences about the high efficiency, minimum ripple voltage, high accuracy, and the usefulness of the system of the proposed converter when applied to either residential or solar home applications.展开更多
Traditional light bulbs （e.g., incandescent, fluorescent） use too much electricity, convert very little energy into light of sufficient quality and in their production use toxic contaminants. During the last few yea...Traditional light bulbs （e.g., incandescent, fluorescent） use too much electricity, convert very little energy into light of sufficient quality and in their production use toxic contaminants. During the last few years, a new type of light source, LED （light emitting diode） bulb, has gained increasing popularity and its costs are set to plunge even further. LED bulbs offer many advantages over traditional sources, and they can be used as a direct replacement to existing lighting. This paper will use a spreadsheet-based analysis with hourly solar data supplied by Ecotect to show that, the efficiency of LED installations can be increased when used in conjunction with photovoltaic modules, as the two generate （and use） DC （direct-current） electricity, thereby eliminating intermediate-level losses in the electronic circuitry. If a storage battery is included, the solar panels generate electricity during the times when the occupants are not necessarily using the lighting, but the stored electricity can be used to power the lighting when the energy is required. The latest results demonstrate that, a slight reduction in the required floor area to be lit allows the solar-battery-LED system to be implemented in small buildings using a storage battery size that is within the range of present commercial devices.展开更多
文摘The development of high-performance oxygen evolution reaction catalysts with low iridium content is the key to the scale-up of proton exchange membrane water electrolyzer(PEMWE)for green hydrogen production.Single-site electrocatalysts with maximized atomic efficiency are held as promising candidates but still suffer from inadequate activity and stability in practical electrolyzer due to the low site density.Here,we proposed a NaNO_(3)-assistant thermal decomposition strategy for the preparation of high-density Ir single sites on MnO_(2)substrate(NaNO_(3)-H-Ir-MnO_(2)).Direct spectroscopic evidence suggests the inclusion of NaNO_(3) accelerates the transformation of Ir-Cl to Ir-O coordination,thus generating uniform dispersed high-density Ir single sites in the products.The optimized H-Ir-MnO_(2)demonstrates not only high intrinsic activity in a three-electrode set-up but also boosted performance in scalable PEMWE,requiring a cell voltage of only 1.74 V to attain a high current density of 2 A cm^(-2) at a low Ir loading of 0.18 mgIr cm^(-2).This work offers a new insight for enhancing the industrial practicality of Ir-based single site catalysts.
文摘A 1.60μm laser diode and electroabsorption modulator monolithically integrated with a novel dual-waveguide spot-size converter output for low-loss coupling to a cleaved single-mode optical fiber are demonstrated.The devices emit in a single transverse and quasi single longitudinal mode with an SMSR of 25.6dB.These devices exhibit a 3dB modulation bandwidth of 15.0GHz,and modulator DC extinction ratios of 16.2dB.The output beam divergence angles of the spot-size converter in the horizontal and vertical directions are as small as 7.3°×18.0°,respectively,resulting in a 3.0dB coupling loss with a cleaved single-mode optical fiber.
文摘A novel 1 55μm laser diode with spot size converter is designed and fabricated using conventional photolithography and chemical wet etching process.For the laser diode,a ridge double core structure is employed.For the spot size converter,a buried ridge double core structure is incorporated.The laterally tapered active core is designed and optically combined with the thin and wide passive core to control the size of mode.The laser diode threshold current is measured to be 40mA together with high slop efficiency of 0 35W/A.The beam divergence angles in the horizontal and vertical directions are as small as 14 89°×18 18°,respectively,resulting in low coupling losses with a cleaved optical fiber (3dB loss).
文摘A novel optoelectronic functional circuit with heterojunction phototransistors (HPTs) and resonant tunneling diodes (RTDs) is described,which presents the function of both photocurrent switching and photo-current latching.These behaviors have been demonstrated by simulating experiments and circuit simulation.Furthermore,basing on photo-current latching behavior,various photo-controlled basis logic elements such as delayed flip-flop (DFF) can be designed and fabricated.
基金This work was supported by the National Natural Science Foundation of China （No.10704083）,the Innovation Foundation of Chinese Academyof Sciences （No.KJCX1-YW-N30）, and the Public Science and Technology Program of Shenzhen （No.SY200806260026A）.
文摘The ultrafast dynamics through conical intersections in 2,6-dimethylpyridine has been studied by femtosecond time-resolved photoelectron imaging coupled with time-resolved mass spectroscopy. Upon absorption of 266 nm pump laser, 2,6-dimethylpyridine is excited to the S2 state with a ππ character from So state. The time evolution of the parent ion signals consists of two exponential decays. One is a fast component on a timescale of 635 fs and the other is a slow component with a timescale of 4.37 ps. Time-dependent photo- electron angular distributions and energy-resolved photoelectron spectroscopy are extracted from time-resolved photoelectron imaging and provide the evolutive information of S2 state. In brief, the ultrafast component is a population transfer from S2 to S1 through the S2/S1 conical intersections, the slow component is attributed to simultaneous IC from the S2 state and the higher vibrational levels of S1 state to So state, which involves the coupling of S2/S0 and S1/So conical intersections. Additionally, the observed ultrafast S2--＋S1 transition occurs only with an 18% branching ratio.
文摘Self-made TiO2 nanoparticles were used as photoelectrode material of dye sensitized solar cell. The TiO2 thin film coats through spreading nanoparticles evenly onto the ITO glass via self-made spin-heat platform, and then TiO2 thin film is soaked in the dye N-719 more than 12 h to prepare the photoelectrode device. The TiO2 nanoparticles produced by electric-discharge-nanofluid-process have premium anatase crystal property, and its diameter can be controlled within a range of 20-50 nm. The surface energy zeta potential of nanofluid is from -22 mV to -28.8 mV, it is a stable particle suspension in the deionized water. A trace of surfactant Triton X-100 put upon the surface of ITO glass can produce a uniform and dense TiO2 thin film and heating up the spin platform to 200 oC is able to eliminate mixed surfac-tant. Self-made TiO2 film presents excellent dye absorption performance and even doesn＇t need heat treatment procedure to enhance essential property. Results of energy analysis show the thicker film structure will increase the short-circuit current density that causes higher conversion efficiency. But, as the film structure is large and thick, both the open-circuit voltage and fill factor will decline gradually to lead bad efficiency of dye-sensitized solar cell.
文摘This paper describes the development of a timer based voltage to frequency converter(V FC).Timer LM555is used in astable multivibrator mode with two OPTO-LDRs(light dependent resistors)in the circuitry.The frequency of timer output waveform which is measured using a digital storage oscillator(DSO)is almost linearly proportional to the applied input voltage.Hence we obtain a linear relationship between the frequency of timer output waveform and the input voltage.Because of its quasi-digital output,the main advantages of this developed converter are linear input-output relationship,small size,easy portabilityand high cost performance.In addition,the timer output waveform can be directly interfaced with personal computer or microprocessor/microcontroller for further processing of the input voltage signal without intervening any analog-to-digital converter(ADC).
基金supported by the National Key Research and Development Program of China(No.2018YFA0208700)the National Natural Science Foundation of China (No.21773302)the Strategic Priority Research Program of Chinese Academy of Sciences (No.XDB30000000)
文摘MXenes,a new family of two-dimensional(2D)materials,have received extensive interest due to their fascinating physicochemical properties,such as outstandinglight-to-heat conversion efficiency.However,the photothermal conversion mechanism of MXenes is still poorly understood.Here,by using femtosecond visible and mid-infrared transient absorption spectroscopy,the electronic energy dissipation dynamics of MXene(Ti_(3)C_(2)T_(x))nanosheets dispersed in various solvents are carefully studied.Our results indicate that the lifetime of photoexcited MXene is strongly dependent on the surrounding environment.Especially,the interfacial electron-vibration coupling between the MXene nanosheets and the adjacent solvent molecules is directly observed following the ultrafast photoexcitation of MXene.It suggests that the interfacial interactions at the MXene-solvent interface play a critical role in the ultrafast energy transport dynamics of MXene,which offers a potentially feasible route for tailoring the light conversion properties of 2D systems.
基金Supported by the National Natural Science Foundation of China under Grant No. 60277034 and 60436020
文摘In order to solve excessive insertion loss and low on/off ratio in quantum well reflection-type waveguide optical switches, a novel InGaAs/InAlAs coupled quantum well structure is proposed. In the case of low applied electric field （F=19 kV/cm） and low absorption loss （ et ~ 61.2 cm-1）, a large negative field-induced refractive index change （ A n=-0.0134） is obtained in the novel coupled quantum well structure at the operating wavelength （ 2 =1550 rim）. The value is larger by over one to two order of maL, nitude comoared to that in a rectanaular ouantum well （ROW） on the above same work conditions.
文摘The solar energy conversion system is very interesting alternative on supplement the electric system generation, due to the persistent cost reduction of the overall system and cleaner power generation. To obtain a stable voltage from an input supply （PV cells） that is higher and lower than the output, a high efficiency and minimum ripple DC-DC converter required in the system for residential power production. Buck-boost converters make it possible to efficiently convert a DC voltage to either a lower or higher voltages. Buck-boost converters are especially useful for PV maximum power tracking purposes, where the objective is to draw maximum possible power from solar panels at all times, regardless of the load. This paper analyzes and describes step by step the process of designing, and simulation of high efficiency low ripple voltage buck-boost DC-DC converter for the photovoltaic solar conversion system applicable to a （typical） single family home based on battery-based systems. The input voltage can typically change from （20 V） initially, down to （5 V）, and provide a regulated voltage within the range of the battery （12 V）. PLECS simulation results provide strong evidences about the high efficiency, minimum ripple voltage, high accuracy, and the usefulness of the system of the proposed converter when applied to either residential or solar home applications.
文摘Traditional light bulbs （e.g., incandescent, fluorescent） use too much electricity, convert very little energy into light of sufficient quality and in their production use toxic contaminants. During the last few years, a new type of light source, LED （light emitting diode） bulb, has gained increasing popularity and its costs are set to plunge even further. LED bulbs offer many advantages over traditional sources, and they can be used as a direct replacement to existing lighting. This paper will use a spreadsheet-based analysis with hourly solar data supplied by Ecotect to show that, the efficiency of LED installations can be increased when used in conjunction with photovoltaic modules, as the two generate （and use） DC （direct-current） electricity, thereby eliminating intermediate-level losses in the electronic circuitry. If a storage battery is included, the solar panels generate electricity during the times when the occupants are not necessarily using the lighting, but the stored electricity can be used to power the lighting when the energy is required. The latest results demonstrate that, a slight reduction in the required floor area to be lit allows the solar-battery-LED system to be implemented in small buildings using a storage battery size that is within the range of present commercial devices.
