The vector correlations between products and reagents for the title reactions have been calculated by the quasi-classical trajectory method at a collision energy of 21.32 kJ/mol on an accurate potential energy surface...The vector correlations between products and reagents for the title reactions have been calculated by the quasi-classical trajectory method at a collision energy of 21.32 kJ/mol on an accurate potential energy surface of Ho et al. （J. Chem. Phys. 119, 3063 （2003））. The peaks of the product angular distribution are found to be in both backward and forward directions for the two title reactions. The product rotational angular momentum is not only aligned, but also oriented along the negative direction of y-axis. These theoretical results are in good agreement with recent experimental findings for the two title reactions. The isotopic effect is also revealed and primarily attributed to the difference of the mass factor in the two title reactions.展开更多
A novel compression method for mechanical vibrating signals,binding with sub-band vector quantization(SVQ) by wavelet packet transformation(WPT) and discrete cosine transformation(DCT) is proposed.Firstly,the vibratin...A novel compression method for mechanical vibrating signals,binding with sub-band vector quantization(SVQ) by wavelet packet transformation(WPT) and discrete cosine transformation(DCT) is proposed.Firstly,the vibrating signal is decomposed into sub-bands by WPT.Then DCT and adaptive bit allocation are done per sub-band and SVQ is performed in each sub-band.It is noted that,after DCT,we only need to code the first components whose numbers are determined by the bits allocated to that sub-band.Through an actual signal,our algorithm is proven to improve the signal-to-noise ratio(SNR) of the reconstructed signal effectively,especially in the situation of lowrate transmission.展开更多
基金ACKNOWLEDGMENTS The authors thank Prof. Ke-li Han for providing stereodynamics QCT code, and thank Dr. T. S. Ho and Prof. H. Rabitz for providing the potential energy surface. This work is supported by the National Natural Science Foundation of China （No.10947103）, the Foundation for Outstanding Young Scientist in Shandong Province （No.2008BS01017）, and the Young Fhnding of Jining University （No.2009QNKJ02）.
文摘The vector correlations between products and reagents for the title reactions have been calculated by the quasi-classical trajectory method at a collision energy of 21.32 kJ/mol on an accurate potential energy surface of Ho et al. （J. Chem. Phys. 119, 3063 （2003））. The peaks of the product angular distribution are found to be in both backward and forward directions for the two title reactions. The product rotational angular momentum is not only aligned, but also oriented along the negative direction of y-axis. These theoretical results are in good agreement with recent experimental findings for the two title reactions. The isotopic effect is also revealed and primarily attributed to the difference of the mass factor in the two title reactions.
基金Supported by the National Natural Science Foundation of China(No.51135001)
文摘A novel compression method for mechanical vibrating signals,binding with sub-band vector quantization(SVQ) by wavelet packet transformation(WPT) and discrete cosine transformation(DCT) is proposed.Firstly,the vibrating signal is decomposed into sub-bands by WPT.Then DCT and adaptive bit allocation are done per sub-band and SVQ is performed in each sub-band.It is noted that,after DCT,we only need to code the first components whose numbers are determined by the bits allocated to that sub-band.Through an actual signal,our algorithm is proven to improve the signal-to-noise ratio(SNR) of the reconstructed signal effectively,especially in the situation of lowrate transmission.
