Depth profiles of absorbed hydrogen introduced by electrochemical charging and light elements were analyzed in Ni-Nb-Zr-H amorphous alloy ribbons using a glow discharge optical emission spectrometer. It was clarified ...Depth profiles of absorbed hydrogen introduced by electrochemical charging and light elements were analyzed in Ni-Nb-Zr-H amorphous alloy ribbons using a glow discharge optical emission spectrometer. It was clarified that the absorbed hydrogen was comparatively well-distributed on the sample surface and that the content of the hydrogen decreased with increasing depth from the surface. That is, the amount of absorbed hydrogen on the surface was about 17 at %, while that inside the specimens decreased to several atomic percent. The depth profiles of the hydrogen which were close to the surface were slightly different between those on the roller side and those on the free side in the melt-spun ribbon. The difference is thought to originate from the existence of oxygen impurity on the surface and from the difference of the Zr content.展开更多
In this study,FLUENT software was employed to simulate the flow pattern and water depth changes in a 120° sharp bend at four discharge rates.To verify the numerical model,a 90° sharp bend was first modeled w...In this study,FLUENT software was employed to simulate the flow pattern and water depth changes in a 120° sharp bend at four discharge rates.To verify the numerical model,a 90° sharp bend was first modeled with a three-dimensional numerical model,and the results were compared with available experimental results.Based on the numerical model validation,a 120° bend was simulated.The results show that the rate of increase of the water depth at the cross-section located 40 cm before the bend,compared with the cross-sections located 40 cm and 80 cm after the bend,decreases with the increase of the normal water depth in the 120° curved channel.Moreover,with increasing normal water depth,the dimensionless water depth change decreases at all cross-sections.At the interior cross-sections of the bend,the transverse water depth slope of the inner half-width is always greater than that of the outer half-width of the channel.Hence,the water depth slope is nonlinear at each crosssection in sharp bends.Two equations reflecting the relationships between the maximum and minimum dimensionless water depths and the normal water depth throughout the channel were obtained.展开更多
Lithium element has attracted remarkable attraction for energy storage devices, over the past 30 years. Lithium is a light element and exhibits the low atomic number 3, just after hydrogen and helium in the periodic t...Lithium element has attracted remarkable attraction for energy storage devices, over the past 30 years. Lithium is a light element and exhibits the low atomic number 3, just after hydrogen and helium in the periodic table. The lithium atom has a strong tendency to release one electron and constitute a positive charge, as Li<sup> </sup>. Initially, lithium metal was employed as a negative electrode, which released electrons. However, it was observed that its structure changed after the repetition of charge-discharge cycles. To remedy this, the cathode mainly consisted of layer metal oxide and olive, e.g., cobalt oxide, LiFePO<sub>4</sub>, etc., along with some contents of lithium, while the anode was assembled by graphite and silicon, etc. Moreover, the electrolyte was prepared using the lithium salt in a suitable solvent to attain a greater concentration of lithium ions. Owing to the lithium ions’ role, the battery’s name was mentioned as a lithium-ion battery. Herein, the presented work describes the working and operational mechanism of the lithium-ion battery. Further, the lithium-ion batteries’ general view and future prospects have also been elaborated.展开更多
Aqueous Zn batteries are promising candidates for grid-scale renewable energy storage.Foil electrodes have been widely investigated and applied as anode materials for aqueous Zn batteries,however,they suffer from limi...Aqueous Zn batteries are promising candidates for grid-scale renewable energy storage.Foil electrodes have been widely investigated and applied as anode materials for aqueous Zn batteries,however,they suffer from limited surface area and severe interfacial issues including metallic dendrites and corrosion side reactions,limiting the depth of discharge(DOD)of the foil electrode materials.Herein,a low-temperature replacement reaction is utilized to in-situ construct a three-dimensional(3D)corrosion-resistant interface for deeply rechargeable Zn foil electrodes.Specifically,the deliberate low-temperature environment controlled the replacement rate between polycrystalline Zn metal and oxalic acid,producing a Zn foil electrode with distinct 3D corrosion-resistant interface(3DCI-Zn),which differed from conventional two-dimensional(2D)protective structure and showed an order of magnitude higher surface area.Consequently,the 3DCI-Zn electrode exhibited dendrite-free and anticorrosion properties,and achieved stable plating/stripping performance for 1000 h at 10 mA cm^(-2)and 10 mAh cm^(-2)with a remarkable DOD of 79%.After pairing with a MnO2cathode with a high areal capacity of 4.2 mAh cm^(-2),the pouch cells delivered 168 Wh L^(-1)and a capacity retention of 89.7%after 100 cycles with a low negative/positive(N/P)ratio of 3:1.展开更多
针对现存锂电池组内串联单体锂电池健康状态(state of health,SOH)均衡方案需要集中控制器和全局通信、系统建设成本居高不下等问题,提出一种基于一致性算法的锂电池组内单体锂电池SOH主动均衡方案。分析了SOH参数、放电深度(depth of d...针对现存锂电池组内串联单体锂电池健康状态(state of health,SOH)均衡方案需要集中控制器和全局通信、系统建设成本居高不下等问题,提出一种基于一致性算法的锂电池组内单体锂电池SOH主动均衡方案。分析了SOH参数、放电深度(depth of discharge,DOD)和有功功率三者之间的内在联系,设计了有功功率分配和控制算法切换法则。利用一致性算法求解DOD平均值,以达到在无需集中控制器和减少通信信号数量的前提下,实现锂电池组内单体锂电池SOH均衡的控制目标,提高锂电池容量利用率,降低锂电池维护成本。最后,Matlab/Simulink仿真结果说明,所提方案在负荷变化、通信中断、锂电池块数增加和DOD出现测量误差的情况下,均能使锂电池组内串联单体锂电池SOH自均衡。展开更多
The standard deviation of the central Pacific sea surface temperature anomaly （SSTA） during the period from October to February shows that the central Pacific SSTA variation is primarily due to the occurrence of the...The standard deviation of the central Pacific sea surface temperature anomaly （SSTA） during the period from October to February shows that the central Pacific SSTA variation is primarily due to the occurrence of the Central Pacific E1 Nifio （CP-E1 Nifio） and has a connection with the subtropical air-sea interaction in the northeastern Pacific. After removing the influence of the Eastern Pacific E1 Nifio, an S-EOF analysis is conducted and the leading mode shows a clear seasonal SSTA evolving from the subtropical northeastern Pacific to the tropical central Pacific with a quasi-biennial period. The initial subtropical SSTA is generated by the wind speed decrease and surface heat flux increase due to a north Pacific anomalous cyclone. Such subtropical SSTA can further influence the establishment of the SSTA in the tropical central Pacific via the wind-evaporation-SST （WES） feedback. After established, the central equatorial Pacific SSTA can be strengthened by the zonal advective feedback and thermocline feedback, and develop into CP-E1 Nifio. However, as the thermocline feedback increases the SSTA cooling after the mature phase, the heat flux loss and the reversed zonal advective feedback can cause the phase transition of CP-EI Nifio. Along with the wind stress variability, the recharge （discharge） process occurs in the central （eastern） equatorial Pacific and such a process causes the phase consistency between the thermocline depth and SST anomalies, which presents a contrast to the original recharge/discharge theory.展开更多
This paper assesses the sediment load of the glacier fed Langtang River, Nepal from April 2014 to March 2015. Water samples were collected from the centre of the river with a frequency of two samples per each sampling...This paper assesses the sediment load of the glacier fed Langtang River, Nepal from April 2014 to March 2015. Water samples were collected from the centre of the river with a frequency of two samples per each sampling day using the Depth Integration Technique (DIT) on daily basis in the monsoon season, weekly in the pre- and post-monsoon seasons and bi-monthly in the winter season. Suspended sediment concentration (SSC) is calculated from the water samples using filtration followed by oven-drying, and a rating curve is used to calculate daily discharge of the Langtang River. The annual sediment yield is 109,276.75 tons and 37.69, 11.52 and 5.54 tons of sediment is transported per day in the pre-monsoon, post-monsoon and winter seasons, respectively. There is a very high value of 872.86 tons per day in the monsoon season, which contributes the highest sediment load among all of the seasons comprising 83% of the total sediment transport. Diurnal cycle of sediment discharge is clearly seen with higher sediment discharge during the evening than the morning and reaching maximum values of 41.1 kg·s<sup>-1</sup> and 61.5 kg·s<sup>-1</sup>, respectively. A clock-wise hysteresis loop has been obtained for discharge and sediment discharge where sediment flux is higher in the early monsoon than in the late monsoon for a corresponding discharge.展开更多
In order to understand the process of surface erosion and acquire basic data of conditions on hillslope without vegetation, a sprinkling experiment is conducted on a bare slope in Mt.Tanakami in the central part of Ja...In order to understand the process of surface erosion and acquire basic data of conditions on hillslope without vegetation, a sprinkling experiment is conducted on a bare slope in Mt.Tanakami in the central part of Japan. Based on the measurements of runoff, mean soil erosion depth, and sediment yield, etc., the results suggest the following characteristics in the process of surface erosion in the experimental area. (1) The occurrence of sediment discharge is interrupted; (2) Surface runoff is a saturated overland flow; (3) The mean soil erosion depth is thick compared with other areas in Mt.Tanakami; (4) Sediment discharge process is detachment-limited.展开更多
Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage due to the excellent safety, environmental friendliness, natural abundance, high theoretical specific capacity, and low re...Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage due to the excellent safety, environmental friendliness, natural abundance, high theoretical specific capacity, and low redox potential of zinc(Zn) metal. However,several issues such as dendrite formation, hydrogen evolution, corrosion, and passivation of Zn metal anodes cause irreversible loss of the active materials. To solve these issues, researchers often use large amounts of excess Zn to ensure a continuous supply of active materials for Zn anodes. This leads to the ultralow utilization of Zn anodes and squanders the high energy density of AZMBs. Herein, the design strategies for AZMBs with high Zn utilization are discussed in depth, from utilizing thinner Zn foils to constructing anode-free structures with theoretical Zn utilization of 100%, which provides comprehensive guidelines for further research. Representative methods for calculating the depth of discharge of Zn anodes with different structures are first summarized. The reasonable modification strategies of Zn foil anodes, current collectors with pre-deposited Zn, and anode-free aqueous Zn metal batteries(AF-AZMBs) to improve Zn utilization are then detailed. In particular, the working mechanism of AF-AZMBs is systematically introduced. Finally, the challenges and perspectives for constructing high-utilization Zn anodes are presented.展开更多
Placing metals within microwave ovens has been generally viewed as a dangerous practice because of occurrence of violent discharge,but in recent years such discharge phenomenon has attracted increasing attention and h...Placing metals within microwave ovens has been generally viewed as a dangerous practice because of occurrence of violent discharge,but in recent years such discharge phenomenon has attracted increasing attention and has enabled a variety of exciting applications.In this work,we provide a comprehensive review of fundamental understanding of microwave-metal discharge interaction and its state-of-the-art application for nanomaterials synthesis.We introduce the microscopic interaction between different categories of materials and the electric and magnetic field of microwaves.For microwave-metal interaction,we highlight its size-dependence and point out the influence of the oxide layer on the surface of metals.We discuss the required conditions for occurrence of discharge,microscopic formation mechanism,and characteristic features of microwave-metal discharge processes.Through analyzing the influence from the microwave input,discharging metals,and surrounding discharging media,we discuss the strategy for systematical regulation of the discharge process.We describe the applications of the microwave-metal discharge for facile synthesis of various functional nanomaterials including core-shell carbon/metal,metal oxides,metal chalcogenides,intermetallic compounds,metallic nanoparticles and metallic compounds,and organic compounds.Finally,the challenges in precise characterization and dynamic regulation of the discharge process as well as exciting application opportunities are discussed.展开更多
文摘Depth profiles of absorbed hydrogen introduced by electrochemical charging and light elements were analyzed in Ni-Nb-Zr-H amorphous alloy ribbons using a glow discharge optical emission spectrometer. It was clarified that the absorbed hydrogen was comparatively well-distributed on the sample surface and that the content of the hydrogen decreased with increasing depth from the surface. That is, the amount of absorbed hydrogen on the surface was about 17 at %, while that inside the specimens decreased to several atomic percent. The depth profiles of the hydrogen which were close to the surface were slightly different between those on the roller side and those on the free side in the melt-spun ribbon. The difference is thought to originate from the existence of oxygen impurity on the surface and from the difference of the Zr content.
文摘In this study,FLUENT software was employed to simulate the flow pattern and water depth changes in a 120° sharp bend at four discharge rates.To verify the numerical model,a 90° sharp bend was first modeled with a three-dimensional numerical model,and the results were compared with available experimental results.Based on the numerical model validation,a 120° bend was simulated.The results show that the rate of increase of the water depth at the cross-section located 40 cm before the bend,compared with the cross-sections located 40 cm and 80 cm after the bend,decreases with the increase of the normal water depth in the 120° curved channel.Moreover,with increasing normal water depth,the dimensionless water depth change decreases at all cross-sections.At the interior cross-sections of the bend,the transverse water depth slope of the inner half-width is always greater than that of the outer half-width of the channel.Hence,the water depth slope is nonlinear at each crosssection in sharp bends.Two equations reflecting the relationships between the maximum and minimum dimensionless water depths and the normal water depth throughout the channel were obtained.
文摘Lithium element has attracted remarkable attraction for energy storage devices, over the past 30 years. Lithium is a light element and exhibits the low atomic number 3, just after hydrogen and helium in the periodic table. The lithium atom has a strong tendency to release one electron and constitute a positive charge, as Li<sup> </sup>. Initially, lithium metal was employed as a negative electrode, which released electrons. However, it was observed that its structure changed after the repetition of charge-discharge cycles. To remedy this, the cathode mainly consisted of layer metal oxide and olive, e.g., cobalt oxide, LiFePO<sub>4</sub>, etc., along with some contents of lithium, while the anode was assembled by graphite and silicon, etc. Moreover, the electrolyte was prepared using the lithium salt in a suitable solvent to attain a greater concentration of lithium ions. Owing to the lithium ions’ role, the battery’s name was mentioned as a lithium-ion battery. Herein, the presented work describes the working and operational mechanism of the lithium-ion battery. Further, the lithium-ion batteries’ general view and future prospects have also been elaborated.
基金financially supported by the National Natural Science Foundation of China (No.22205068,22109144)the“CUG Scholar”Scientific Research Funds at China University of Geosciences (Wuhan) (Project No.2022118)the Fundamental Research Funds for the Central Universities,China University of Geosciences (Wuhan) (No.162301202673)。
文摘Aqueous Zn batteries are promising candidates for grid-scale renewable energy storage.Foil electrodes have been widely investigated and applied as anode materials for aqueous Zn batteries,however,they suffer from limited surface area and severe interfacial issues including metallic dendrites and corrosion side reactions,limiting the depth of discharge(DOD)of the foil electrode materials.Herein,a low-temperature replacement reaction is utilized to in-situ construct a three-dimensional(3D)corrosion-resistant interface for deeply rechargeable Zn foil electrodes.Specifically,the deliberate low-temperature environment controlled the replacement rate between polycrystalline Zn metal and oxalic acid,producing a Zn foil electrode with distinct 3D corrosion-resistant interface(3DCI-Zn),which differed from conventional two-dimensional(2D)protective structure and showed an order of magnitude higher surface area.Consequently,the 3DCI-Zn electrode exhibited dendrite-free and anticorrosion properties,and achieved stable plating/stripping performance for 1000 h at 10 mA cm^(-2)and 10 mAh cm^(-2)with a remarkable DOD of 79%.After pairing with a MnO2cathode with a high areal capacity of 4.2 mAh cm^(-2),the pouch cells delivered 168 Wh L^(-1)and a capacity retention of 89.7%after 100 cycles with a low negative/positive(N/P)ratio of 3:1.
文摘针对现存锂电池组内串联单体锂电池健康状态(state of health,SOH)均衡方案需要集中控制器和全局通信、系统建设成本居高不下等问题,提出一种基于一致性算法的锂电池组内单体锂电池SOH主动均衡方案。分析了SOH参数、放电深度(depth of discharge,DOD)和有功功率三者之间的内在联系,设计了有功功率分配和控制算法切换法则。利用一致性算法求解DOD平均值,以达到在无需集中控制器和减少通信信号数量的前提下,实现锂电池组内单体锂电池SOH均衡的控制目标,提高锂电池容量利用率,降低锂电池维护成本。最后,Matlab/Simulink仿真结果说明,所提方案在负荷变化、通信中断、锂电池块数增加和DOD出现测量误差的情况下,均能使锂电池组内串联单体锂电池SOH自均衡。
基金supported by the National Basic Research Program of China(973Program:2012CB955604)National Natural Science Foundation of China(Nos.40975038and40830106)+5 种基金the CMA Program(GYHY200906008)the financial support provided by the China Scholarship Counciljointly supported by the 973 Program of China(2010CB950404)DOE grant DE-SC0005110National Science Foundation(NSF)grants ATM1034798NOAA grand NA10OAR4310200
文摘The standard deviation of the central Pacific sea surface temperature anomaly （SSTA） during the period from October to February shows that the central Pacific SSTA variation is primarily due to the occurrence of the Central Pacific E1 Nifio （CP-E1 Nifio） and has a connection with the subtropical air-sea interaction in the northeastern Pacific. After removing the influence of the Eastern Pacific E1 Nifio, an S-EOF analysis is conducted and the leading mode shows a clear seasonal SSTA evolving from the subtropical northeastern Pacific to the tropical central Pacific with a quasi-biennial period. The initial subtropical SSTA is generated by the wind speed decrease and surface heat flux increase due to a north Pacific anomalous cyclone. Such subtropical SSTA can further influence the establishment of the SSTA in the tropical central Pacific via the wind-evaporation-SST （WES） feedback. After established, the central equatorial Pacific SSTA can be strengthened by the zonal advective feedback and thermocline feedback, and develop into CP-E1 Nifio. However, as the thermocline feedback increases the SSTA cooling after the mature phase, the heat flux loss and the reversed zonal advective feedback can cause the phase transition of CP-EI Nifio. Along with the wind stress variability, the recharge （discharge） process occurs in the central （eastern） equatorial Pacific and such a process causes the phase consistency between the thermocline depth and SST anomalies, which presents a contrast to the original recharge/discharge theory.
文摘This paper assesses the sediment load of the glacier fed Langtang River, Nepal from April 2014 to March 2015. Water samples were collected from the centre of the river with a frequency of two samples per each sampling day using the Depth Integration Technique (DIT) on daily basis in the monsoon season, weekly in the pre- and post-monsoon seasons and bi-monthly in the winter season. Suspended sediment concentration (SSC) is calculated from the water samples using filtration followed by oven-drying, and a rating curve is used to calculate daily discharge of the Langtang River. The annual sediment yield is 109,276.75 tons and 37.69, 11.52 and 5.54 tons of sediment is transported per day in the pre-monsoon, post-monsoon and winter seasons, respectively. There is a very high value of 872.86 tons per day in the monsoon season, which contributes the highest sediment load among all of the seasons comprising 83% of the total sediment transport. Diurnal cycle of sediment discharge is clearly seen with higher sediment discharge during the evening than the morning and reaching maximum values of 41.1 kg·s<sup>-1</sup> and 61.5 kg·s<sup>-1</sup>, respectively. A clock-wise hysteresis loop has been obtained for discharge and sediment discharge where sediment flux is higher in the early monsoon than in the late monsoon for a corresponding discharge.
文摘In order to understand the process of surface erosion and acquire basic data of conditions on hillslope without vegetation, a sprinkling experiment is conducted on a bare slope in Mt.Tanakami in the central part of Japan. Based on the measurements of runoff, mean soil erosion depth, and sediment yield, etc., the results suggest the following characteristics in the process of surface erosion in the experimental area. (1) The occurrence of sediment discharge is interrupted; (2) Surface runoff is a saturated overland flow; (3) The mean soil erosion depth is thick compared with other areas in Mt.Tanakami; (4) Sediment discharge process is detachment-limited.
基金the financial support from the National Natural Science Foundation of China (Grant Nos. 52201201, 52372171)the State Key Lab of Advanced Metals and Materials (Grant No. 2022Z-11)+1 种基金the Fundamental Research Funds for the Central Universities (Grant No. 00007747, 06500205)the Initiative Postdocs Supporting Program (Grant No. BX20190002)。
文摘Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage due to the excellent safety, environmental friendliness, natural abundance, high theoretical specific capacity, and low redox potential of zinc(Zn) metal. However,several issues such as dendrite formation, hydrogen evolution, corrosion, and passivation of Zn metal anodes cause irreversible loss of the active materials. To solve these issues, researchers often use large amounts of excess Zn to ensure a continuous supply of active materials for Zn anodes. This leads to the ultralow utilization of Zn anodes and squanders the high energy density of AZMBs. Herein, the design strategies for AZMBs with high Zn utilization are discussed in depth, from utilizing thinner Zn foils to constructing anode-free structures with theoretical Zn utilization of 100%, which provides comprehensive guidelines for further research. Representative methods for calculating the depth of discharge of Zn anodes with different structures are first summarized. The reasonable modification strategies of Zn foil anodes, current collectors with pre-deposited Zn, and anode-free aqueous Zn metal batteries(AF-AZMBs) to improve Zn utilization are then detailed. In particular, the working mechanism of AF-AZMBs is systematically introduced. Finally, the challenges and perspectives for constructing high-utilization Zn anodes are presented.
基金supported by the National Key Research and Development Project from Ministry of Science and Technology of China(No.2022YFA1203100)Innovation Program of Shanghai Municipal Education Commission(No.2019-01-07-00-02-E00069)+1 种基金the National Natural Science Foundation of China(No.51873105)the Top Young Talents of Ten Thousand Talents Plan.
文摘Placing metals within microwave ovens has been generally viewed as a dangerous practice because of occurrence of violent discharge,but in recent years such discharge phenomenon has attracted increasing attention and has enabled a variety of exciting applications.In this work,we provide a comprehensive review of fundamental understanding of microwave-metal discharge interaction and its state-of-the-art application for nanomaterials synthesis.We introduce the microscopic interaction between different categories of materials and the electric and magnetic field of microwaves.For microwave-metal interaction,we highlight its size-dependence and point out the influence of the oxide layer on the surface of metals.We discuss the required conditions for occurrence of discharge,microscopic formation mechanism,and characteristic features of microwave-metal discharge processes.Through analyzing the influence from the microwave input,discharging metals,and surrounding discharging media,we discuss the strategy for systematical regulation of the discharge process.We describe the applications of the microwave-metal discharge for facile synthesis of various functional nanomaterials including core-shell carbon/metal,metal oxides,metal chalcogenides,intermetallic compounds,metallic nanoparticles and metallic compounds,and organic compounds.Finally,the challenges in precise characterization and dynamic regulation of the discharge process as well as exciting application opportunities are discussed.
