We present an assumed enhanced strain finite element framework for the simulation of tensile fracturing processes in transversely isotropic rocks.Fractures along the weak bedding planes and through the anisotropic roc...We present an assumed enhanced strain finite element framework for the simulation of tensile fracturing processes in transversely isotropic rocks.Fractures along the weak bedding planes and through the anisotropic rock matrix are treated with distinct enrichment,and a recently proposed dualmechanism tensile failure criterion for transversely isotropic rocks is adopted to determine crack initiation for the two failure modes.The cohesive crack model is adopted to characterize the response of embedded cracks.As for the numerical implementation of the proposed framework,both algorithms for the update of local history variables at Gauss points and of the global finite element system are derived.Four boundary-value problem simulations are carried out with the proposed framework,including uniaxial tension tests of Argillite,pre-notched square loaded in tension,three-point bending tests on Longmaxi shale,and simulations of tensile cracks induced by a strip load around a tunnel in transversely isotropic rocks.Simulation results reveal that the proposed framework can properly capture the tensile strength anisotropy and the anisotropic evolution of tensile cracks in transversely isotropic rocks.展开更多
Tunnel Boring Machines(TBMs)are vital for tunnel and underground construction due to their high safety and efficiency.Accurately predicting TBM operational parameters based on the surrounding environment is crucial fo...Tunnel Boring Machines(TBMs)are vital for tunnel and underground construction due to their high safety and efficiency.Accurately predicting TBM operational parameters based on the surrounding environment is crucial for planning schedules and managing costs.This study investigates the effectiveness of tree-based machine learning models,including Random Forest,Extremely Randomized Trees,Adaptive Boosting Machine,Gradient Boosting Machine,Extreme Gradient Boosting Machine(XGBoost),Light Gradient Boosting Machine,and CatBoost,in predicting the Penetration Rate(PR)of TBMs by considering rock mass and material characteristics.These techniques are able to provide a good relationship between input(s)and output parameters;hence,obtaining a high level of accuracy.To do that,a comprehensive database comprising various rock mass and material parameters,including Rock Mass Rating,Brazilian Tensile Strength,and Weathering Zone,was utilized for model development.The practical application of these models was assessed with a new dataset representing diverse rock mass and material properties.To evaluate model performance,ranking systems and Taylor diagrams were employed.CatBoost emerged as the most accurate model during training and testing,with R2 scores of 0.927 and 0.861,respectively.However,during validation,XGBoost demonstrated superior performance with an R2 of 0.713.Despite these variations,all tree-based models showed promising accuracy in predicting TBM performance,providing valuable insights for similar projects in the future.展开更多
The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic ...The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic frameworks(MOFs)are ideal self-sacrificing templates for the construction of carbon-based EMW absorbers.In this work,bimetallic FeMn-MOF-derived MnFe_(2)O_(4)/C/graphene composites were fabricated via a two-step route of solvothermal reaction and the following pyrolysis treatment.The results re-veal the evolution of the microscopic morphology of carbon skeletons from loofah-like to octahedral and then to polyhedron and pomegran-ate after the adjustment of the Fe^(3+)to Mn^(2+)molar ratio.Furthermore,at the Fe^(3+)to Mn^(2+)molar ratio of 2:1,the obtained MnFe_(2)O_(4)/C/graphene composite exhibited the highest EMW absorption capacity.Specifically,a minimum reflection loss of-72.7 dB and a max-imum effective absorption bandwidth of 5.1 GHz were achieved at a low filling ratio of 10wt%.In addition,the possible EMW absorp-tion mechanism of MnFe_(2)O_(4)/C/graphene composites was proposed.Therefore,the results of this work will contribute to the construction of broadband and efficient carbon-based EMW absorbers derived from MOFs.展开更多
Surrounding rock deterioration and large deformation have always been a significant difficulty in designing and constructing tunnels in soft rock.The key lies in real-time perception and quantitative assessment of the...Surrounding rock deterioration and large deformation have always been a significant difficulty in designing and constructing tunnels in soft rock.The key lies in real-time perception and quantitative assessment of the damaged area around the tunnel.An in situ microseismic(MS)monitoring system is established in the plateau soft tock tunnel.This technique facilitates spatiotemporal monitoring of the rock mass's fracturing expansion and squeezing deformation,which agree well with field convergence deformation results.The formation mechanisms of progressive failure evolution of soft rock tunnels were discussed and analyzed with MS data and numerical results.The results demonstrate that:(1)Localized stress concentration and layered rock result in significant asymmetry in micro-fractures propagation in the tunnel radial section.As excavation continues,the fracture extension area extends into the deep surrounding rockmass on the east side affected by the weak bedding;(2)Tunnel excavation and long-term deformation can induce tensile shear action on the rock mass,vertical tension fractures(account for 45%)exist in deep rockmass,which play a crucial role in controlling the macroscopic failure of surrounding rock;and(3)Based on the radiated MS energy,a three-dimensional model was created to visualize the damage zone of the tunnel surrounding rock.The model depicted varying degrees of damage,and three high damage zones were identified.Generally,the depth of high damage zone ranged from 4 m to 12 m.This study may be a valuable reference for the warning and controlling of large deformations in similar projects.展开更多
Transition metal sulfides have great potential as anode mterials for sodium-ion batteries(SIBs)due to their high theoretical specific capacities.However,the inferior intrinsic conductivity and large volume variation d...Transition metal sulfides have great potential as anode mterials for sodium-ion batteries(SIBs)due to their high theoretical specific capacities.However,the inferior intrinsic conductivity and large volume variation during sodiation-desodiation processes seriously affect its high-rate and long-cyde performance,unbeneficial for the application as fast-charging and long-cycling SIBs anode.Herein,the three-dimensional porous Cu_(1.81)S/nitrogen-doped carbon frameworks(Cu_(1.81)S/NC)are synthesized by the simple and facile sol-gel and annealing processes,which can accommodate the volumetric expansion of Cu_(1.81)S nanoparticles and accelerate the transmission of ions and electrons during Na^(+)insertion/extraction processes,exhibiting the excellent rate capability(250.6 mA·g^(-1)at 20.0 A·g^(-1))and outstanding cycling stability(70% capacity retention for 6000 cycles at 10.0 A·g^(-1))for SIBs.Moreover,the Na-ion full cells coupled with Na_(3)V_(2)(PO_(4))_(3)/C cathode also demonstrate the satisfactory reversible specific capacity of 330.5 mAh·g^(-1)at 5.0 A·g^(-1)and long-cycle performance with the 86.9% capacity retention at 2.0 A·g^(-1)after 750 cycles.This work proposes a promising way for the conversionbased metal sulfides for the applications as fast-charging sodium-ion battery anode.展开更多
Understanding the mechanical properties of the lithologies is crucial to accurately determine the horizontal stress magnitude.To investigate the correlation between the rock mass properties and maximum horizontal stre...Understanding the mechanical properties of the lithologies is crucial to accurately determine the horizontal stress magnitude.To investigate the correlation between the rock mass properties and maximum horizontal stress,the three-dimensional(3D)stress tensors at 89 measuring points determined using an improved overcoring technique in nine mines in China were adopted,a newly defined characteristic parameter C_(ERP)was proposed as an indicator for evaluating the structural properties of rock masses,and a fuzzy relation matrix was established using the information distribution method.The results indicate that both the vertical stress and horizontal stress exhibit a good linear growth relationship with depth.There is no remarkable correlation between the elastic modulus,Poisson's ratio and depth,and the distribution of data points is scattered and messy.Moreover,there is no obvious relationship between the rock quality designation(RQD)and depth.The maximum horizontal stress σ_(H) is a function of rock properties,showing a certain linear relationship with the C_(ERP)at the same depth.In addition,the overall change trend of σ_(H) determined by the established fuzzy identification method is to increase with the increase of C_(ERP).The fuzzy identification method also demonstrates a relatively detailed local relationship betweenσ_H and C_(ERP),and the predicted curve rises in a fluctuating way,which is in accord well with the measured stress data.展开更多
目的:观察化瘀通络灸对血管性痴呆大鼠Ras同源物基因组成员A(Ras homolog gene family member A,RhoA)/Rho激酶(Rho associated protein kinase, ROCK)轴突生长抑制性信号通路相关蛋白的影响,探讨其治疗血管性痴呆的机制。方法:使用Mor...目的:观察化瘀通络灸对血管性痴呆大鼠Ras同源物基因组成员A(Ras homolog gene family member A,RhoA)/Rho激酶(Rho associated protein kinase, ROCK)轴突生长抑制性信号通路相关蛋白的影响,探讨其治疗血管性痴呆的机制。方法:使用Morris水迷宫筛除贴壁、原地旋转或溺水的Wistar大鼠,将符合条件大鼠分为假手术组、造模组。假手术组暴露大鼠颈总动脉;造模组用改良的双侧颈总动脉永久结扎术制备血管性痴呆大鼠模型,术后3 d用水迷宫对大鼠进行模型鉴定,将合格者随机分为模型组、艾灸组和西药组。于鉴定次日对大鼠进行治疗,艾灸组悬灸百会、大椎、神庭,20 min/次,1次/d, 1周为1疗程,2个疗程间休息1 d,共3个疗程;西药组用吡拉西坦溶液灌胃,2次/d;假手术组、模型组行灸架固定。治疗结束,取大鼠脑组织,用免疫荧光单染法、蛋白免疫印迹法检测其脑内目的蛋白RhoA、Rho相关螺旋卷曲蛋白激酶Ⅱ(Rho protein-related curl spiral kinase-Ⅱ,ROCKⅡ)、肌球蛋白轻链磷酸化(Phosphorylation of myosin light chain, P-MLC)的阳性表达。结果:模型组大鼠海马、皮质RhoA、ROCKⅡ、P-MLC蛋白表达高于假手术组(P<0.01);艾灸组、西药组海马和皮质RhoA、ROCKⅡ、P-MLC蛋白表达较模型组低(P<0.05);艾灸组皮质ROCKⅡ蛋白表达较西药组稍低(P<0.05);艾灸组与西药组海马ROCKⅡ、海马与皮质RhoA、P-MLC蛋白表达差异无统计学意义(P>0.05)。结论:化瘀通络灸可能是通过下调RhoA/ROCK轴突生长抑制性信号通路相关蛋白的表达提高血管性痴呆大鼠的记忆力,从而发挥治疗血管性痴呆的作用。展开更多
(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under...(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.展开更多
The nature of rock fragmentation affects the downstream mining processes like loading, hauling, and crushing the blasted rock. Therefore, it is important to evaluate rock fragmentation after blasting for choosing or d...The nature of rock fragmentation affects the downstream mining processes like loading, hauling, and crushing the blasted rock. Therefore, it is important to evaluate rock fragmentation after blasting for choosing or designing optimal strategies for these processes. However, current techniques of rock fragmentation analysis such as sieving, image-based analysis, empirical methods or artificial intelligence-based methods entail different practical challenges, for example, excessive processing time, higher costs, applicability issues in underground environments, user-biasness, accuracy issues, etc. A classification model has been developed by utilizing image analysis techniques to overcome these challenges. The model was tested on about 7500 videos of load-haul-dump (LHD) buckets with blasted material from Malmberget iron ore mine in Sweden. A Kernel-based support vector machine (SVM) method was utilized to extract frames comprising loaded LHD buckets. Then, the blasted rock in the buckets was classified into five distinct categories using the bagging k-nearest neighbor (KNN) technique. The results showed 99.8% and 89.8% accuracy for kernel-based SVM and bagging KNN classifiers, respectively. The developed framework is efficient in terms of the operation time, cost and practicability for different mines and variate amounts of rock masses.展开更多
The stratum lithology and geological structure of the highway tunnel in the mountainous areas of western China are complex,and the engineering geological conditions are complicated.When the highway tunnel passes throu...The stratum lithology and geological structure of the highway tunnel in the mountainous areas of western China are complex,and the engineering geological conditions are complicated.When the highway tunnel passes through different lithological strata,its structural design and construction technology are completely diff erent.Therefore,in order to support the tunnel design and construction,the tunnel survey Among them,the identifi cation of the contact boundary between magmatic rock and metamorphic rock and the grade of surrounding rock is very important.Through magnetotelluric survey of the Mupi tunnel of Jiuzhaigou-Mianyang highway on G8513 line,2D forward numerical simulation,1D,2D,3D inversion,and engineering geological analysis,it is revealed that the electrical characteristics of each layer,focusing on the identifi cation of the contact boundary between magmatic rock and metamorphic rock.This study provides the electrical characteristics of the magmatic rock and metamorphic rock contact boundary of the Mupi Tunnel.It is speculated that the boundary is revealed by the tunnel construction excavation,which verifies the correctness of the geophysical inversion model and provides a more detailed design basis for the tunnel design.I believe that taking the Mupi Tunnel survey as an example,through this research,it can provide detailed geophysical evidence for highway tunnels to distinguish between magmatic rock and metamorphic rock.展开更多
Rockbursts, which mainly affect mining roadways, are dynamic disasters arising from the surrounding rock under high stress. Understanding the interaction between supports and the surrounding rock is necessary for effe...Rockbursts, which mainly affect mining roadways, are dynamic disasters arising from the surrounding rock under high stress. Understanding the interaction between supports and the surrounding rock is necessary for effective rockburst control. In this study, the squeezing behavior of the surrounding rock is analyzed in rockburst roadways, and a mechanical model of rockbursts is established considering the dynamic support stress, thus deriving formulas and providing characteristic curves for describing the interaction between the support and surrounding rock. Design principles and parameters of supports for rockburst control are proposed. The results show that only when the geostress magnitude exceeds a critical value can it drive the formation of rockburst conditions. The main factors influencing the convergence response and rockburst occurrence around roadways are geostress, rock brittleness, uniaxial compressive strength, and roadway excavation size. Roadway support devices can play a role in controlling rockburst by suppressing the squeezing evolution of the surrounding rock towards instability points of rockburst. Further, the higher the strength and the longer the impact stroke of support devices with constant resistance, the more easily multiple balance points can be formed with the surrounding rock to control rockburst occurrence. Supports with long impact stroke allow adaptation to varying geostress levels around the roadway, aiding in rockburst control. The results offer a quantitative method for designing support systems for rockburst-prone roadways. The design criterion of supports is determined by the intersection between the convergence curve of the surrounding rock and the squeezing deformation curve of the support devices.展开更多
The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significan...The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significance to accurately characterize the actual microstructures and their influence on stress and damage evolution inside the rocks. In this study, an image-based fast Fourier transform (FFT) method is developed for reconstructing the actual rock microstructures by combining it with the digital image processing (DIP) technique. A series of experimental investigations were conducted to acquire information regarding the actual microstructure and the mechanical properties. Based on these experimental evidences, the processed microstructure information, in conjunction with the proposed micromechanical model, is incorporated into the numerical calculation. The proposed image-based FFT method was firstly validated through uniaxial compression tests. Subsequently, it was employed to predict and analyze the influence of microstructure on macroscopic mechanical behaviors, local stress distribution and the internal crack evolution process in brittle rocks. The distribution of feldspar is considerably more heterogeneous and scattered than that of quartz, which results in a greater propensity for the formation of cracks in feldspar. It is observed that initial cracks and new cracks, including intragranular and boundary ones, ultimately coalesce and connect as the primary through cracks, which are predominantly distributed along the boundary of the feldspar. This phenomenon is also predicted by the proposed numerical method. The results indicate that the proposed numerical method provides an effective approach for analyzing, understanding and predicting the nonlinear mechanical and cracking behaviors of brittle rocks by taking into account the actual microstructure characteristics.展开更多
The risk of infection following consumption of foodborne pathogens contaminated foods became a significant concern for human health and imposes great economic losses to food industry.Herein,Ag nanoparticles were integ...The risk of infection following consumption of foodborne pathogens contaminated foods became a significant concern for human health and imposes great economic losses to food industry.Herein,Ag nanoparticles were integrated to Cu-based metal-organic framework(Cu-MOF)for antibacterial activity.The crystal structure,morphology and composition of the prepared composite Ag@Cu-MOF were confirmed by powder X-ray diffraction,thermogravimetric analysis,scanning electron microscope,transmission electron microscope,Fourier transform infrared spectroscopy,and X-ray photoelectron spectroscopy.Antibacterial assays revealed that Ag@Cu-MOF exhibited increased inhibitory activity against Escherichia coli O157:H7 in comparison to Cu-MOF.Ag@Cu-MOF treated bacterial cells displayed distinct morphological changes,a decreased ratio of live/dead cells,as well as a reduction of intracellular ATP.Antibiofilm studies demonstrated that Ag@CuMOF could dramatically inhibit biofilm formation and disrupt preformed biofilms by interfering the metabolic activity and decreasing the expression of biofilm-associated genes.Food contamination model illustrated that Ag@Cu-MOF significantly prevented the growth of E.coli O157:H7 in packed pork.This study sheds light on the potential of Ag@Cu-MOF as a promising antimicrobial material for preserving pork.展开更多
Rock fragmentation is an important indicator for assessing the quality of blasting operations.However,accurate prediction of rock fragmentation after blasting is challenging due to the complicated blasting parameters ...Rock fragmentation is an important indicator for assessing the quality of blasting operations.However,accurate prediction of rock fragmentation after blasting is challenging due to the complicated blasting parameters and rock properties.For this reason,optimized by the Bayesian optimization algorithm(BOA),four hybrid machine learning models,including random forest,adaptive boosting,gradient boosting,and extremely randomized trees,were developed in this study.A total of 102 data sets with seven input parameters(spacing-to-burden ratio,hole depth-to-burden ratio,burden-to-hole diameter ratio,stemming length-to-burden ratio,powder factor,in situ block size,and elastic modulus)and one output parameter(rock fragment mean size,X_(50))were adopted to train and validate the predictive models.The root mean square error(RMSE),the mean absolute error(MAE),and the coefficient of determination(R^(2))were used as the evaluation metrics.The evaluation results demonstrated that the hybrid models showed superior performance than the standalone models.The hybrid model consisting of gradient boosting and BOA(GBoost-BOA)achieved the best prediction results compared with the other hybrid models,with the highest R^(2)value of 0.96 and the smallest values of RMSE and MAE of 0.03 and 0.02,respectively.Furthermore,sensitivity analysis was carried out to study the effects of input variables on rock fragmentation.In situ block size(XB),elastic modulus(E),and stemming length-to-burden ratio(T/B)were set as the main influencing factors.The proposed hybrid model provided a reliable prediction result and thus could be considered an alternative approach for rock fragment prediction in mining engineering.展开更多
This study proposed a repeated adjustable mixture injection strategy(RAM)based microbial induced carbonate precipitation(MICP)for efficient mitigation of rock fracture leakage.Granite fractures with small apertures we...This study proposed a repeated adjustable mixture injection strategy(RAM)based microbial induced carbonate precipitation(MICP)for efficient mitigation of rock fracture leakage.Granite fractures with small apertures were investigated,and bio-sealing experiments were conducted using five different cementation solution(CS)concentrations(0.25−2 M).The results showed that the RAM-based bio-sealing method can seal and bond the small aperture rock fractures with high efficiency and uniform precipitation by adjusting the CS concentration.The RAM-based bio-sealing mechanism is attributed to the following four stages:(1)fixation of bacterial flocs onto the fracture surfaces,(2)precipitation of CaCO3 onto the fracture surfaces,(3)growth of pre-precipitated CaCO3 and adhesion of new-suspended CaCO3,and(4)bridging and clogging processes.The optimal CS concentration of 1 M resulted in a fracture filling rate up to 85%,a transmissivity reduction of 4 orders of magnitude,and a shear strength ranging from 512 kPa to 688 kPa.The bio-sealing effect was found to be influenced by the CS concentration on bacterial attachment,calcium carbonate yield and calcium carbonate bulk density.The CS concentration of 1 M promoted bacterial attachment,and increased calcium carbonate yield as well as calcium carbonate bulk density,while concentrations above 1 M had the opposite effect.The bulk density of calcium carbonate played a crucial role in the sealing and bonding performance of bio-sealed fractures,particularly at comparable filling ratios and bridging areas.The bulk density was regulated by the size of calcium carbonate crystals and was determined by Ca2+concentration in the CS.This study provides valuable insights into the RAM-based bio-sealing method,highlighting its potential for efficient rock fracture leakage mitigation through precise control of CS concentration and understanding the underlying mechanisms.展开更多
Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the st...Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the stress development within the backfill material,leaving the influence of stope backfilling on stress distribution in surrounding rock mass and ground stability largely unexplored.Therefore,this paper presents numerical models in FLAC3D to investigate,for the first time,the time-dependent stress redistribution around a vertical backfilled stope and its implications on ground stability,considering the creep of surrounding rock mass.Using the Soft Soil constitutive model,the compressibility of backfill under large pressure was captured.It is found that the creep deformation of rock mass exercises compression on backfill and results in a less void ratio and increased modulus for fill material.The compacted backfill conversely influenced the stress distribution and ground stability of rock mass which was a combined effect of wall creep and compressibility of backfill.With the increase of time or/and creep deformation,the minimum principal stress in the rocks surrounding the backfilled stope increased towards the pre-mining stress state,while the deviatoric stress reduces leading to an increased factor of safety and improved ground stability.This improvement effect of backfill on ground stability increased with the increase of mine depth and stope height,while it is also more pronounced for the narrow stope,the backfill with a smaller compression index,and the soft rocks with a smaller viscosity coefficient.Furthermore,the results emphasize the importance of minimizing empty time and backfilling extracted stope as soon as possible for ground control.Reduction of filling gap height enhances the local stability around the roof of stope.展开更多
Controllable rock cracking technology is crucial for the exploration and exploitation of deep underground resources.Many existing studies have been dedicated to the laser-assisted rock-weakening technology.It has been...Controllable rock cracking technology is crucial for the exploration and exploitation of deep underground resources.Many existing studies have been dedicated to the laser-assisted rock-weakening technology.It has been proved that laser irradiation can improve drilling and blasting efficiency when combined with mechanical rock fracturing methods,which are irrelevant for borehole stabilization.To improve the latter,this study used laser ablation for borehole reinforcement.The high-power laser was applied to typical rock samples(sandstone,mudstone and coal)in both dry and saturated conditions.Multi-technique observations and measurements were used to fully understand the peculiar modifications of the specimens under laser treatment,i.e.mechanical loading,acoustic emission(AE)monitoring,digital image correlation(DIC)strain field evaluation,infrared thermography(IRT)monitoring and X-ray computed tomography(CT)scanning.The results showed that,in addition to the effects already demonstrated,laser irradiation can improve the strength of the soft rock,especially in the saturated state.The process involved a complicated phase change including melting and evaporation of the matrix under high-temperature and high-pressure to form a glassy high strength silicate material.This process is similar to the reaction between molten lava and water,or the impact of an asteroid on the earth.Inspired by the results,a conceptual path for a new borehole stabilization technology using laser ablation was outlined.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.52038005 and 52201326)the fellowship of China Postdoctoral Science Foundation(Grant No.2022M721883)Tsinghua University Initiative Scientific Research Program.
文摘We present an assumed enhanced strain finite element framework for the simulation of tensile fracturing processes in transversely isotropic rocks.Fractures along the weak bedding planes and through the anisotropic rock matrix are treated with distinct enrichment,and a recently proposed dualmechanism tensile failure criterion for transversely isotropic rocks is adopted to determine crack initiation for the two failure modes.The cohesive crack model is adopted to characterize the response of embedded cracks.As for the numerical implementation of the proposed framework,both algorithms for the update of local history variables at Gauss points and of the global finite element system are derived.Four boundary-value problem simulations are carried out with the proposed framework,including uniaxial tension tests of Argillite,pre-notched square loaded in tension,three-point bending tests on Longmaxi shale,and simulations of tensile cracks induced by a strip load around a tunnel in transversely isotropic rocks.Simulation results reveal that the proposed framework can properly capture the tensile strength anisotropy and the anisotropic evolution of tensile cracks in transversely isotropic rocks.
文摘Tunnel Boring Machines(TBMs)are vital for tunnel and underground construction due to their high safety and efficiency.Accurately predicting TBM operational parameters based on the surrounding environment is crucial for planning schedules and managing costs.This study investigates the effectiveness of tree-based machine learning models,including Random Forest,Extremely Randomized Trees,Adaptive Boosting Machine,Gradient Boosting Machine,Extreme Gradient Boosting Machine(XGBoost),Light Gradient Boosting Machine,and CatBoost,in predicting the Penetration Rate(PR)of TBMs by considering rock mass and material characteristics.These techniques are able to provide a good relationship between input(s)and output parameters;hence,obtaining a high level of accuracy.To do that,a comprehensive database comprising various rock mass and material parameters,including Rock Mass Rating,Brazilian Tensile Strength,and Weathering Zone,was utilized for model development.The practical application of these models was assessed with a new dataset representing diverse rock mass and material properties.To evaluate model performance,ranking systems and Taylor diagrams were employed.CatBoost emerged as the most accurate model during training and testing,with R2 scores of 0.927 and 0.861,respectively.However,during validation,XGBoost demonstrated superior performance with an R2 of 0.713.Despite these variations,all tree-based models showed promising accuracy in predicting TBM performance,providing valuable insights for similar projects in the future.
基金supported by the Natural Science Research Project of the Anhui Educational Committee,China(No.2022AH050827)the Open Research Fund Program of Anhui Province Key Laboratory of Specialty Polymers,Anhui University of Science and Technology,China(No.AHKLSP23-12)the Joint National-Local Engineering Research Center for Safe and Precise Coal Mining Fund,China(No.EC2022020)。
文摘The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic frameworks(MOFs)are ideal self-sacrificing templates for the construction of carbon-based EMW absorbers.In this work,bimetallic FeMn-MOF-derived MnFe_(2)O_(4)/C/graphene composites were fabricated via a two-step route of solvothermal reaction and the following pyrolysis treatment.The results re-veal the evolution of the microscopic morphology of carbon skeletons from loofah-like to octahedral and then to polyhedron and pomegran-ate after the adjustment of the Fe^(3+)to Mn^(2+)molar ratio.Furthermore,at the Fe^(3+)to Mn^(2+)molar ratio of 2:1,the obtained MnFe_(2)O_(4)/C/graphene composite exhibited the highest EMW absorption capacity.Specifically,a minimum reflection loss of-72.7 dB and a max-imum effective absorption bandwidth of 5.1 GHz were achieved at a low filling ratio of 10wt%.In addition,the possible EMW absorp-tion mechanism of MnFe_(2)O_(4)/C/graphene composites was proposed.Therefore,the results of this work will contribute to the construction of broadband and efficient carbon-based EMW absorbers derived from MOFs.
基金the funding support from the National Natural Science Foundation of China(Grant Nos.U23A2060,42177143 and 42277461).
文摘Surrounding rock deterioration and large deformation have always been a significant difficulty in designing and constructing tunnels in soft rock.The key lies in real-time perception and quantitative assessment of the damaged area around the tunnel.An in situ microseismic(MS)monitoring system is established in the plateau soft tock tunnel.This technique facilitates spatiotemporal monitoring of the rock mass's fracturing expansion and squeezing deformation,which agree well with field convergence deformation results.The formation mechanisms of progressive failure evolution of soft rock tunnels were discussed and analyzed with MS data and numerical results.The results demonstrate that:(1)Localized stress concentration and layered rock result in significant asymmetry in micro-fractures propagation in the tunnel radial section.As excavation continues,the fracture extension area extends into the deep surrounding rockmass on the east side affected by the weak bedding;(2)Tunnel excavation and long-term deformation can induce tensile shear action on the rock mass,vertical tension fractures(account for 45%)exist in deep rockmass,which play a crucial role in controlling the macroscopic failure of surrounding rock;and(3)Based on the radiated MS energy,a three-dimensional model was created to visualize the damage zone of the tunnel surrounding rock.The model depicted varying degrees of damage,and three high damage zones were identified.Generally,the depth of high damage zone ranged from 4 m to 12 m.This study may be a valuable reference for the warning and controlling of large deformations in similar projects.
基金financially supported by the National Natural Science Foundation of China(Nos.U1904173 and 52272219)the Key Research Projects of Henan Provincial Department of Education(No.19A150043)+2 种基金the Natural Science Foundation of Henan Province(Nos.202300410330 and 222300420276)the Nanhu Scholars Program for Young Scholars of Xinyang Normal Universitythe Xinyang Normal University Analysis&Testing Center。
文摘Transition metal sulfides have great potential as anode mterials for sodium-ion batteries(SIBs)due to their high theoretical specific capacities.However,the inferior intrinsic conductivity and large volume variation during sodiation-desodiation processes seriously affect its high-rate and long-cyde performance,unbeneficial for the application as fast-charging and long-cycling SIBs anode.Herein,the three-dimensional porous Cu_(1.81)S/nitrogen-doped carbon frameworks(Cu_(1.81)S/NC)are synthesized by the simple and facile sol-gel and annealing processes,which can accommodate the volumetric expansion of Cu_(1.81)S nanoparticles and accelerate the transmission of ions and electrons during Na^(+)insertion/extraction processes,exhibiting the excellent rate capability(250.6 mA·g^(-1)at 20.0 A·g^(-1))and outstanding cycling stability(70% capacity retention for 6000 cycles at 10.0 A·g^(-1))for SIBs.Moreover,the Na-ion full cells coupled with Na_(3)V_(2)(PO_(4))_(3)/C cathode also demonstrate the satisfactory reversible specific capacity of 330.5 mAh·g^(-1)at 5.0 A·g^(-1)and long-cycle performance with the 86.9% capacity retention at 2.0 A·g^(-1)after 750 cycles.This work proposes a promising way for the conversionbased metal sulfides for the applications as fast-charging sodium-ion battery anode.
基金financially supported by the National Natural Science Foundation of China(No.52204084)the Open Research Fund of the State Key Laboratory of Coal Resources and safe Mining,CUMT,China(No.SKLCRSM 23KF004)+3 种基金the Interdisciplinary Research Project for Young Teachers of USTB(Fundamental Research Funds for the Central Universities),China(No.FRF-IDRY-GD22-002)the Fundamental Research Funds for the Central Universities and the Youth Teacher International Exchange and Growth Program,China(No.QNXM20220009)the National Key R&D Program of China(Nos.2022YFC2905600 and 2022 YFC3004601)the Science,Technology&Innovation Project of Xiongan New Area,China(No.2023XAGG0061)。
文摘Understanding the mechanical properties of the lithologies is crucial to accurately determine the horizontal stress magnitude.To investigate the correlation between the rock mass properties and maximum horizontal stress,the three-dimensional(3D)stress tensors at 89 measuring points determined using an improved overcoring technique in nine mines in China were adopted,a newly defined characteristic parameter C_(ERP)was proposed as an indicator for evaluating the structural properties of rock masses,and a fuzzy relation matrix was established using the information distribution method.The results indicate that both the vertical stress and horizontal stress exhibit a good linear growth relationship with depth.There is no remarkable correlation between the elastic modulus,Poisson's ratio and depth,and the distribution of data points is scattered and messy.Moreover,there is no obvious relationship between the rock quality designation(RQD)and depth.The maximum horizontal stress σ_(H) is a function of rock properties,showing a certain linear relationship with the C_(ERP)at the same depth.In addition,the overall change trend of σ_(H) determined by the established fuzzy identification method is to increase with the increase of C_(ERP).The fuzzy identification method also demonstrates a relatively detailed local relationship betweenσ_H and C_(ERP),and the predicted curve rises in a fluctuating way,which is in accord well with the measured stress data.
文摘(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.
文摘The nature of rock fragmentation affects the downstream mining processes like loading, hauling, and crushing the blasted rock. Therefore, it is important to evaluate rock fragmentation after blasting for choosing or designing optimal strategies for these processes. However, current techniques of rock fragmentation analysis such as sieving, image-based analysis, empirical methods or artificial intelligence-based methods entail different practical challenges, for example, excessive processing time, higher costs, applicability issues in underground environments, user-biasness, accuracy issues, etc. A classification model has been developed by utilizing image analysis techniques to overcome these challenges. The model was tested on about 7500 videos of load-haul-dump (LHD) buckets with blasted material from Malmberget iron ore mine in Sweden. A Kernel-based support vector machine (SVM) method was utilized to extract frames comprising loaded LHD buckets. Then, the blasted rock in the buckets was classified into five distinct categories using the bagging k-nearest neighbor (KNN) technique. The results showed 99.8% and 89.8% accuracy for kernel-based SVM and bagging KNN classifiers, respectively. The developed framework is efficient in terms of the operation time, cost and practicability for different mines and variate amounts of rock masses.
基金National Natural Science Foundation of China(41630640)National Science Foundation of Innovation Research Group(41521002)+1 种基金National Natural Science Foundation of China(41790445)Construction S&T Project of Department of Transportation of Sichuan Province(Grant No.2020A01).
文摘The stratum lithology and geological structure of the highway tunnel in the mountainous areas of western China are complex,and the engineering geological conditions are complicated.When the highway tunnel passes through different lithological strata,its structural design and construction technology are completely diff erent.Therefore,in order to support the tunnel design and construction,the tunnel survey Among them,the identifi cation of the contact boundary between magmatic rock and metamorphic rock and the grade of surrounding rock is very important.Through magnetotelluric survey of the Mupi tunnel of Jiuzhaigou-Mianyang highway on G8513 line,2D forward numerical simulation,1D,2D,3D inversion,and engineering geological analysis,it is revealed that the electrical characteristics of each layer,focusing on the identifi cation of the contact boundary between magmatic rock and metamorphic rock.This study provides the electrical characteristics of the magmatic rock and metamorphic rock contact boundary of the Mupi Tunnel.It is speculated that the boundary is revealed by the tunnel construction excavation,which verifies the correctness of the geophysical inversion model and provides a more detailed design basis for the tunnel design.I believe that taking the Mupi Tunnel survey as an example,through this research,it can provide detailed geophysical evidence for highway tunnels to distinguish between magmatic rock and metamorphic rock.
基金funded by the National Natural Science Foundation of China (No. 52304133)the National Key R&D Program of China (No. 2022YFC3004605)the Department of Science and Technology of Liaoning Province (No. 2023-BS-083)。
文摘Rockbursts, which mainly affect mining roadways, are dynamic disasters arising from the surrounding rock under high stress. Understanding the interaction between supports and the surrounding rock is necessary for effective rockburst control. In this study, the squeezing behavior of the surrounding rock is analyzed in rockburst roadways, and a mechanical model of rockbursts is established considering the dynamic support stress, thus deriving formulas and providing characteristic curves for describing the interaction between the support and surrounding rock. Design principles and parameters of supports for rockburst control are proposed. The results show that only when the geostress magnitude exceeds a critical value can it drive the formation of rockburst conditions. The main factors influencing the convergence response and rockburst occurrence around roadways are geostress, rock brittleness, uniaxial compressive strength, and roadway excavation size. Roadway support devices can play a role in controlling rockburst by suppressing the squeezing evolution of the surrounding rock towards instability points of rockburst. Further, the higher the strength and the longer the impact stroke of support devices with constant resistance, the more easily multiple balance points can be formed with the surrounding rock to control rockburst occurrence. Supports with long impact stroke allow adaptation to varying geostress levels around the roadway, aiding in rockburst control. The results offer a quantitative method for designing support systems for rockburst-prone roadways. The design criterion of supports is determined by the intersection between the convergence curve of the surrounding rock and the squeezing deformation curve of the support devices.
基金supported by the National Natural Science Foundation of China(Grant No.11802332)the China Scholarship Council(Grant No.202206435003)the Fundamental Research Funds for the Central Universities(Grant No.2024ZKPYLJ03).
文摘The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significance to accurately characterize the actual microstructures and their influence on stress and damage evolution inside the rocks. In this study, an image-based fast Fourier transform (FFT) method is developed for reconstructing the actual rock microstructures by combining it with the digital image processing (DIP) technique. A series of experimental investigations were conducted to acquire information regarding the actual microstructure and the mechanical properties. Based on these experimental evidences, the processed microstructure information, in conjunction with the proposed micromechanical model, is incorporated into the numerical calculation. The proposed image-based FFT method was firstly validated through uniaxial compression tests. Subsequently, it was employed to predict and analyze the influence of microstructure on macroscopic mechanical behaviors, local stress distribution and the internal crack evolution process in brittle rocks. The distribution of feldspar is considerably more heterogeneous and scattered than that of quartz, which results in a greater propensity for the formation of cracks in feldspar. It is observed that initial cracks and new cracks, including intragranular and boundary ones, ultimately coalesce and connect as the primary through cracks, which are predominantly distributed along the boundary of the feldspar. This phenomenon is also predicted by the proposed numerical method. The results indicate that the proposed numerical method provides an effective approach for analyzing, understanding and predicting the nonlinear mechanical and cracking behaviors of brittle rocks by taking into account the actual microstructure characteristics.
基金funded by the Key Research and Development Projects of Shaanxi Province(2023-YBNY-178)Shaanxi Fundamental Science Research Project for Chemistry&Biology(22JHQ029)+1 种基金China Postdoctoral Science Foundation(2019M653766)National Natural Science Foundation of China(21901212)。
文摘The risk of infection following consumption of foodborne pathogens contaminated foods became a significant concern for human health and imposes great economic losses to food industry.Herein,Ag nanoparticles were integrated to Cu-based metal-organic framework(Cu-MOF)for antibacterial activity.The crystal structure,morphology and composition of the prepared composite Ag@Cu-MOF were confirmed by powder X-ray diffraction,thermogravimetric analysis,scanning electron microscope,transmission electron microscope,Fourier transform infrared spectroscopy,and X-ray photoelectron spectroscopy.Antibacterial assays revealed that Ag@Cu-MOF exhibited increased inhibitory activity against Escherichia coli O157:H7 in comparison to Cu-MOF.Ag@Cu-MOF treated bacterial cells displayed distinct morphological changes,a decreased ratio of live/dead cells,as well as a reduction of intracellular ATP.Antibiofilm studies demonstrated that Ag@CuMOF could dramatically inhibit biofilm formation and disrupt preformed biofilms by interfering the metabolic activity and decreasing the expression of biofilm-associated genes.Food contamination model illustrated that Ag@Cu-MOF significantly prevented the growth of E.coli O157:H7 in packed pork.This study sheds light on the potential of Ag@Cu-MOF as a promising antimicrobial material for preserving pork.
基金National Natural Science Foundation of China,Grant/Award Number:52374153。
文摘Rock fragmentation is an important indicator for assessing the quality of blasting operations.However,accurate prediction of rock fragmentation after blasting is challenging due to the complicated blasting parameters and rock properties.For this reason,optimized by the Bayesian optimization algorithm(BOA),four hybrid machine learning models,including random forest,adaptive boosting,gradient boosting,and extremely randomized trees,were developed in this study.A total of 102 data sets with seven input parameters(spacing-to-burden ratio,hole depth-to-burden ratio,burden-to-hole diameter ratio,stemming length-to-burden ratio,powder factor,in situ block size,and elastic modulus)and one output parameter(rock fragment mean size,X_(50))were adopted to train and validate the predictive models.The root mean square error(RMSE),the mean absolute error(MAE),and the coefficient of determination(R^(2))were used as the evaluation metrics.The evaluation results demonstrated that the hybrid models showed superior performance than the standalone models.The hybrid model consisting of gradient boosting and BOA(GBoost-BOA)achieved the best prediction results compared with the other hybrid models,with the highest R^(2)value of 0.96 and the smallest values of RMSE and MAE of 0.03 and 0.02,respectively.Furthermore,sensitivity analysis was carried out to study the effects of input variables on rock fragmentation.In situ block size(XB),elastic modulus(E),and stemming length-to-burden ratio(T/B)were set as the main influencing factors.The proposed hybrid model provided a reliable prediction result and thus could be considered an alternative approach for rock fragment prediction in mining engineering.
基金supported by the National Natural Science Foundation of China(Grant No.41925012)Key task project for joint research and development of the Yangtze River Delta Science and Technology Innovation Community(Grant No.2022CSJGG1200)State Key Laboratory for GeoMechanics and Deep Underground Engineering(Grant No.SKLGDUEK2214).
文摘This study proposed a repeated adjustable mixture injection strategy(RAM)based microbial induced carbonate precipitation(MICP)for efficient mitigation of rock fracture leakage.Granite fractures with small apertures were investigated,and bio-sealing experiments were conducted using five different cementation solution(CS)concentrations(0.25−2 M).The results showed that the RAM-based bio-sealing method can seal and bond the small aperture rock fractures with high efficiency and uniform precipitation by adjusting the CS concentration.The RAM-based bio-sealing mechanism is attributed to the following four stages:(1)fixation of bacterial flocs onto the fracture surfaces,(2)precipitation of CaCO3 onto the fracture surfaces,(3)growth of pre-precipitated CaCO3 and adhesion of new-suspended CaCO3,and(4)bridging and clogging processes.The optimal CS concentration of 1 M resulted in a fracture filling rate up to 85%,a transmissivity reduction of 4 orders of magnitude,and a shear strength ranging from 512 kPa to 688 kPa.The bio-sealing effect was found to be influenced by the CS concentration on bacterial attachment,calcium carbonate yield and calcium carbonate bulk density.The CS concentration of 1 M promoted bacterial attachment,and increased calcium carbonate yield as well as calcium carbonate bulk density,while concentrations above 1 M had the opposite effect.The bulk density of calcium carbonate played a crucial role in the sealing and bonding performance of bio-sealed fractures,particularly at comparable filling ratios and bridging areas.The bulk density was regulated by the size of calcium carbonate crystals and was determined by Ca2+concentration in the CS.This study provides valuable insights into the RAM-based bio-sealing method,highlighting its potential for efficient rock fracture leakage mitigation through precise control of CS concentration and understanding the underlying mechanisms.
基金the funding support from the National Natural Science Foundation of China(Grant Nos.52304101 and 52004206)the China Postdoctoral Science Foundation(Grant No.2023MD734215)。
文摘Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the stress development within the backfill material,leaving the influence of stope backfilling on stress distribution in surrounding rock mass and ground stability largely unexplored.Therefore,this paper presents numerical models in FLAC3D to investigate,for the first time,the time-dependent stress redistribution around a vertical backfilled stope and its implications on ground stability,considering the creep of surrounding rock mass.Using the Soft Soil constitutive model,the compressibility of backfill under large pressure was captured.It is found that the creep deformation of rock mass exercises compression on backfill and results in a less void ratio and increased modulus for fill material.The compacted backfill conversely influenced the stress distribution and ground stability of rock mass which was a combined effect of wall creep and compressibility of backfill.With the increase of time or/and creep deformation,the minimum principal stress in the rocks surrounding the backfilled stope increased towards the pre-mining stress state,while the deviatoric stress reduces leading to an increased factor of safety and improved ground stability.This improvement effect of backfill on ground stability increased with the increase of mine depth and stope height,while it is also more pronounced for the narrow stope,the backfill with a smaller compression index,and the soft rocks with a smaller viscosity coefficient.Furthermore,the results emphasize the importance of minimizing empty time and backfilling extracted stope as soon as possible for ground control.Reduction of filling gap height enhances the local stability around the roof of stope.
基金supported by the National Natural Science Foundation of China(Grant No.51804296)China Scholarship Council Grant(Grant No.CSC#202006425019).
文摘Controllable rock cracking technology is crucial for the exploration and exploitation of deep underground resources.Many existing studies have been dedicated to the laser-assisted rock-weakening technology.It has been proved that laser irradiation can improve drilling and blasting efficiency when combined with mechanical rock fracturing methods,which are irrelevant for borehole stabilization.To improve the latter,this study used laser ablation for borehole reinforcement.The high-power laser was applied to typical rock samples(sandstone,mudstone and coal)in both dry and saturated conditions.Multi-technique observations and measurements were used to fully understand the peculiar modifications of the specimens under laser treatment,i.e.mechanical loading,acoustic emission(AE)monitoring,digital image correlation(DIC)strain field evaluation,infrared thermography(IRT)monitoring and X-ray computed tomography(CT)scanning.The results showed that,in addition to the effects already demonstrated,laser irradiation can improve the strength of the soft rock,especially in the saturated state.The process involved a complicated phase change including melting and evaporation of the matrix under high-temperature and high-pressure to form a glassy high strength silicate material.This process is similar to the reaction between molten lava and water,or the impact of an asteroid on the earth.Inspired by the results,a conceptual path for a new borehole stabilization technology using laser ablation was outlined.
