合成了未见报道的标题配合物。通过化学分析、ICP和TG曲线确定了其化学式为K_8H_3[Y(PW_(11)O_(39))_2]·25H_2O;利用IR、UV、XRD、^(183)W-NMR、循环伏安等手段对其结构进行了表征,结果表明杂多阴离子为β_2型Keggin结构。采用稀...合成了未见报道的标题配合物。通过化学分析、ICP和TG曲线确定了其化学式为K_8H_3[Y(PW_(11)O_(39))_2]·25H_2O;利用IR、UV、XRD、^(183)W-NMR、循环伏安等手段对其结构进行了表征,结果表明杂多阴离子为β_2型Keggin结构。采用稀土多元渗的方法对配合物进行了气相热扩渗,经ICP和XPS测试表明:微量的稀土元素La和Ce可以渗入到配合物的体相,并与组份元素存在键合作用。扩渗后化合物的化学式为K_8H_6YLa_(0.11)Ce_(0.18)P_2W_4~ⅤW_(18)~ⅥO_(78)·15H_2O,其晶体属单斜晶系,晶胞参数:a=6.3775nm,b=3.6771nm,c=3.7727nm,β=90.192°,V=88.47326nm^3;导电性的测试结果表明:室温时,扩渗后试样的电导率提高了约10~3倍,且热稳定范围变宽,523K时的电导率为1.33×10^(-2)S·cm^(-1),有望成为实用化的导电材料;~1H MAS NMR测试结果表明其存在三种质子,其导电机理可能是质子导电。展开更多
The microstructure and electrochemical properties of Ti0.17Zr0.08V0.35Cr0.10Ni0.30 alloy were investigated. The alloy was found to be consisted of V-based solid solution phase with bcc structure and C14 Laves phase wi...The microstructure and electrochemical properties of Ti0.17Zr0.08V0.35Cr0.10Ni0.30 alloy were investigated. The alloy was found to be consisted of V-based solid solution phase with bcc structure and C14 Laves phase with hexagonal structure. SEM-FEG results show that C14 Laves phase precipitates between bcc phases. V and Cr essentially exist in bcc phase, Ti and Ni mainly in C14 Laves phase, as proved by EDX data. The electrochemical properties prove that the discharge capacity of Ti0.17Zr0.08V0.35Cr0.10Ni0.30 alloy electrode decreases slightly with increasing temperature, but it keeps high discharge capacity at 343 K. At the same time, the charge-transfer resistance decreases and the high rate dischargeability increases as temperature increases.展开更多
文摘合成了未见报道的标题配合物。通过化学分析、ICP和TG曲线确定了其化学式为K_8H_3[Y(PW_(11)O_(39))_2]·25H_2O;利用IR、UV、XRD、^(183)W-NMR、循环伏安等手段对其结构进行了表征,结果表明杂多阴离子为β_2型Keggin结构。采用稀土多元渗的方法对配合物进行了气相热扩渗,经ICP和XPS测试表明:微量的稀土元素La和Ce可以渗入到配合物的体相,并与组份元素存在键合作用。扩渗后化合物的化学式为K_8H_6YLa_(0.11)Ce_(0.18)P_2W_4~ⅤW_(18)~ⅥO_(78)·15H_2O,其晶体属单斜晶系,晶胞参数:a=6.3775nm,b=3.6771nm,c=3.7727nm,β=90.192°,V=88.47326nm^3;导电性的测试结果表明:室温时,扩渗后试样的电导率提高了约10~3倍,且热稳定范围变宽,523K时的电导率为1.33×10^(-2)S·cm^(-1),有望成为实用化的导电材料;~1H MAS NMR测试结果表明其存在三种质子,其导电机理可能是质子导电。
文摘The microstructure and electrochemical properties of Ti0.17Zr0.08V0.35Cr0.10Ni0.30 alloy were investigated. The alloy was found to be consisted of V-based solid solution phase with bcc structure and C14 Laves phase with hexagonal structure. SEM-FEG results show that C14 Laves phase precipitates between bcc phases. V and Cr essentially exist in bcc phase, Ti and Ni mainly in C14 Laves phase, as proved by EDX data. The electrochemical properties prove that the discharge capacity of Ti0.17Zr0.08V0.35Cr0.10Ni0.30 alloy electrode decreases slightly with increasing temperature, but it keeps high discharge capacity at 343 K. At the same time, the charge-transfer resistance decreases and the high rate dischargeability increases as temperature increases.
