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Conventional processes and membrane technology for carbon dioxide removal from natural gas:A review 被引量:19
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作者 Zee Ying Yeo Thiam Leng Chew +1 位作者 Abdul Rahman Mohamed Siang-Piao Chai 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2012年第3期282-298,共17页
Membrane technology is becoming more important for CO,_ separation from natural gas in the new era due to its process simplicity, relative ease of operation and control, compact, and easy to scale up as compared with ... Membrane technology is becoming more important for CO,_ separation from natural gas in the new era due to its process simplicity, relative ease of operation and control, compact, and easy to scale up as compared with conventional processes. Conventional processes such as absorption and adsorption for CO2 separation from natural gas are generally more energy demanding and costly for both operation and maintenance. Polymeric membranes are the current commercial membranes used for CO2 separation from natural gas. However, polymeric membranes possess drawbacks such as low permeability and selectivity, plasticization at high temperatures, as well as insufficient thermal and chemical stability. The shortcomings of commercial polymeric membranes have motivated researchers to opt for other alternatives, especially inorganic membranes due to their higher thermal stability, good chemical resistance to solvents, high mechanical strength and long lifetime. Surface modifications can be utilized in inorganic membranes to further enhance the selectivity, permeability or catalytic activities of the membrane. This paper is to provide a comprehensive review on gas separation, comparing membrane technology with other conventional methods of recovering CO2 from natural gas, challenges of current commercial polymeric membranes and inorganic membranes for CO2 removal and membrane surface modification for improved selectivity. 展开更多
关键词 membrane technology inorganic membrane CO2 separation natural gas: surface modification
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Bioregeneration of spent activated carbon:Review of key factors and recent mathematical models of kinetics
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作者 Kwok-Yii Leong Siew-Leng Loo +3 位作者 Mohammed J.K.Bashir Wen-Da Oh Pasupuleti Visweswara Rao Jun-Wei Lim 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第5期893-902,共10页
The disposal of spent activated carbon(AC) will inevitably create secondary pollution. In overcoming this problem, the spent AC can be regenerated by means of biological approach. Bioregeneration is the phenomenon in ... The disposal of spent activated carbon(AC) will inevitably create secondary pollution. In overcoming this problem, the spent AC can be regenerated by means of biological approach. Bioregeneration is the phenomenon in which through the action of microorganisms, the adsorbed pollutants on the surface of the AC will be biodegraded and this enables further adsorption of pollutants to occur with time elapse. This review provides the challenges and perspectives for effective bioregeneration to occur in biological activated carbon(BAC)column. Owing to very few reported works on the bioregeneration rate in BAC column, emphasis is put forward on the recently developed models of bioregeneration kinetic in batch system. All in all, providing potential solutions in increasing the lifespan of AC and the enhancement of bioregeneration rate will definitely overcome the bottlenecks in spent AC bioregeneration. 展开更多
关键词 BIOREGENERATION Spent activated carbon Modeling of bioregeneration kinetic Concentration gradient EXOENZYME
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秸秆和硫酸铝对淡黑钙土有机矿质复合体及有机碳分布的影响 被引量:8
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作者 赵兴敏 刘楠 +3 位作者 郭欣欣 王鸿斌 隋标 赵兰坡 《农业环境科学学报》 CAS CSCD 北大核心 2017年第5期950-956,共7页
以吉林省典型土壤淡黑钙土为研究对象,采用室内恒温培养法研究在不同秸秆和硫酸铝添加量下,淡黑钙土中有机矿质复合体的含量及有机碳在其中的分布,探讨有机矿质复合体对淡黑钙土固碳的贡献。结果表明:对于秸秆和硫酸铝添加的所有处理,... 以吉林省典型土壤淡黑钙土为研究对象,采用室内恒温培养法研究在不同秸秆和硫酸铝添加量下,淡黑钙土中有机矿质复合体的含量及有机碳在其中的分布,探讨有机矿质复合体对淡黑钙土固碳的贡献。结果表明:对于秸秆和硫酸铝添加的所有处理,复合体含量均表现为G_1(钠分散组)>G_0(水分散组)>G_2(钠质研磨分散组);与对照相比,秸秆和硫酸铝添加使得淡黑钙土中G_0组复合体的含量降低,G_2组复合体的含量明显上升,而对G_1组复合体的含量影响不大。单位质量复合体中有机碳的含量大小表现为G_2>G_0>G_1,G_2组复合体中的有机碳含量最高(平均含量为95.92 g·kg^(-1)),约为单位质量G_0组和G_1组复合体中有机碳含量的3倍,G_0组(平均含量为33.89 g·kg^(-1))略高于G_1组(平均含量为32.25 g·kg^(-1))。秸秆和硫酸铝添加均有助于提高G_0组复合体中有机碳的含量;而G_1组复合体有机碳含量的变化主要受秸秆添加量的影响,随着秸秆添加量的增加,G_1组复合体有机碳含量增加;秸秆对G_2组复合体中有机碳含量的提高具有促进作用,而硫酸铝的影响则相反。各组复合体对淡黑钙土固碳的贡献率取决于土壤中复合体的含量及单位质量复合体中有机碳的含量,其对固碳贡献的大小顺序为G_1>G_0>G_2;有机矿质复合体(G_0+G_1+G_2)质量仅占淡黑钙土质量的约四分之一,但其对于淡黑钙土固碳的贡献却为61.96%~73.56%。 展开更多
关键词 淡黑钙土 秸秆 硫酸铝 有机矿质复合体 土壤有机碳
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水体沉积物与岸边土壤颗粒组成及有机碳分布特征 被引量:10
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作者 赵兴敏 赵兰坡 +3 位作者 郭欣欣 李明堂 于珊珊 王铭阳 《水土保持学报》 CSCD 北大核心 2014年第6期304-308,共5页
以长春市新立城水库和第二松花江干流沉积物及其水体岸边的土壤为对象,研究沉积物、土壤的颗粒组成(有机无机复合体)及有机碳在颗粒中的分布特征。结果表明:松花江沉积物和岸边土壤有机无机复合体组成均以砂粒复合体为主,粉粒复合体含... 以长春市新立城水库和第二松花江干流沉积物及其水体岸边的土壤为对象,研究沉积物、土壤的颗粒组成(有机无机复合体)及有机碳在颗粒中的分布特征。结果表明:松花江沉积物和岸边土壤有机无机复合体组成均以砂粒复合体为主,粉粒复合体含量次之,黏粒复合体含量最少;整体而言,粘粒和粉粒复合体中有机质含量稍高,砂粒中有机含量略低。新立城水库沉积物有机无机复合体组成以黏粒复合体为主,粉粒复合体含量次之,砂粒复合体含量最少,而岸边土壤各级复合体的含量基本相当,大部分样品砂砾含量略微偏多;沉积物的有机碳平均含量高于土壤,且其黏粒复合体有机碳含量全部高于土壤黏粒复合体的有机碳含量,而粉粒复合体和砂粒复合体有机碳含量均低于岸边土壤的有机碳含量。以上说明对于流动性较大的河流,其岸边土壤各级复合体对沉积物复合体组成和有机碳分布均具有一定的贡献,而对于流动性较小的湖库,其岸边土壤各级复合体中黏粒复合体对沉积物复合体的组成和有机碳的分布具有较大的贡献。对于松花江水体而言,沉积物和岸边土壤粘土矿物组成基本相同,说明其中的沉积物颗粒部分来源于土壤。 展开更多
关键词 土壤 沉积物 有机物无机复合体 有机碳
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A systematic approach to ON-OFF event detection and clustering analysis of non-intrusive appliance load monitoring 被引量:8
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作者 Chuan Choong YANG Chit Siang SOH Vooi Voon YAP 《Frontiers in Energy》 SCIE CSCD 2015年第2期231-237,共7页
The aim of non-intrusive appliance load monitoring (NIALM) is to disaggregate the energy consumption of individual electrical appliances from total power consumption utilizing non-intrusive methods. In this paper, a... The aim of non-intrusive appliance load monitoring (NIALM) is to disaggregate the energy consumption of individual electrical appliances from total power consumption utilizing non-intrusive methods. In this paper, a systematic approach to 0N-0FF event detection and clustering analysis for NIALM were presented. From the aggregate power consumption data set, the data are passed through median filtering to reduce noise and prepared for the event detection algorithm. The event detection algorithm is to determine the switching of ON and OFF status of electrical appliances. The goodness- of-fit (GOF) methodology is the event detection algorithm implemented. After event detection, the events detected were paired into ON-0FF pairing appliances. The results from the ON-OFF pairing algorithm were further clustered in groups utilizing the K-means clustering analysis. The K- means clustering were implemented as an unsupervised learning methodology for the clustering analysis. The novelty of this paper is the determination of the time duration an electrical appliance is turned ON through combination of event detection, ON-OFF pairing and K- means clustering. The results of the algorithm implemen- tation were discussed and ideas on future work were also proposed. 展开更多
关键词 non-intrusive appliance load monitoring event detection goodness-of-fit (GOF) K-means clustering ON-OFF pairing
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Microwave assisted digestion followed by ICP-MS for determination of trace metals in atmospheric and lake ecosystem 被引量:12
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作者 Manan Ahmed Ying Hui Chin +1 位作者 Xinxin Guo Xing-Min Zhao 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2017年第5期1-10,共10页
The study of trace metals in the atmosphere and lake water is important due to their critical effects on humans, aquatic animals and the geochemical balance of ecosystems. The objective of this study was to investigat... The study of trace metals in the atmosphere and lake water is important due to their critical effects on humans, aquatic animals and the geochemical balance of ecosystems. The objective of this study was to investigate the concentration of trace metals in atmospheric and lake water samples during the rainy season (before and after precipitation) between November and December 2015. Typical methods of sample preparation for trace metal determination such as cloud point extraction, solid phase extraction and dispersive liquid- liquid micro-extraction are time-consuming and difficult to perform; therefore, there is a crucial need for development of more effective sample preparation procedure. A convection microwave assisted digestion procedure for extraction of trace metals was developed for use prior to inductively couple plasma-mass spectrometric determination. The result showed that metals like zinc (133.50-419.30 μg/m3) and aluminum (53.58-378.93 μg/m3) had higher concentrations in atmospheric samples as compared to lake samples before precipitation. On the other hand, the concentrations of zinc, aluminum, chromium and arsenic were significantly higher in lake samples after precipitation and lower in atmospheric samples. The relationship between physicochemical parameters (pH and turbidity) and heavy metal concentrations was investigated as well. Furthermore, enrichment factor analysis indicated that anthropogenic sources such as soil dust, biomass burning and fuel combustion influenced the metal concentrations in the atmosphere. 展开更多
关键词 Trace metals Microwave digestion ICP-MS Atmospheric environment Lake ecosystem
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Composition and source apportionment of dust fall around a natural lake 被引量:1
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作者 Mohd Talib Latif Sofia Aida Ngah +4 位作者 Doreena Dominick Intan Suraya Razak Xinxin Guo Thunwadee Srithawirat Idris Mushrifah 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2015年第7期143-155,共13页
The aim of this study was to determine the source apportionment of dust fall around Lake Chini, Malaysia. Samples were collected monthly between December 2012 and March2013 at seven sampling stations located around La... The aim of this study was to determine the source apportionment of dust fall around Lake Chini, Malaysia. Samples were collected monthly between December 2012 and March2013 at seven sampling stations located around Lake Chini. The samples were filtered to separate the dissolved and undissolved solids. The ionic compositions(NO-3, SO2-4, Cl-and NH+4) were determined using ion chromatography(IC) while major elements(K, Na, Ca and Mg) and trace metals(Zn, Fe, Al, Ni, Mn, Cr, Pb and Cd) were determined using inductively coupled plasma mass spectrometry(ICP-MS). The results showed that the average concentration of total solids around Lake Chini was 93.49 ± 16.16 mg/(m2·day). SO2-4, Na and Zn dominated the dissolved portion of the dust fall. The enrichment factors(EF) revealed that the source of the trace metals and major elements in the rain water was anthropogenic, except for Fe. Hierarchical agglomerative cluster analysis(HACA) classified the seven monitoring stations and 16 variables into five groups and three groups respectively. A coupled receptor model, principal component analysis multiple linear regression(PCA-MLR), revealed that the sources of dust fall in Lake Chini were dominated by agricultural and biomass burning(42%),followed by the earth's crust(28%), sea spray(16%) and a mixture of soil dust and vehicle emissions(14%). 展开更多
关键词 Trace metal Major element ANION Source apportionment Lake Ghini MALAYSIA
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Effects of inventory classifications on CONWIP system: a case study
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作者 Joshua Prakash Jeng Feng Chin 《Journal of Management Analytics》 EI 2017年第3期296-320,共25页
This paper studies the effects of integrating four inventory classification methods into constant work-in-process(CONWIP)systems in a multistage batch production.The inventory classification methods are multiple close... This paper studies the effects of integrating four inventory classification methods into constant work-in-process(CONWIP)systems in a multistage batch production.The inventory classification methods are multiple closed-loop CONWIP(MCC),parallel CONWIP(PC),analytical hierarchy procedure,and weighted linear optimization(WLO).Discrete-event simulation models were built.A full-factorial experimental design was employed.Response surface methodology generated suitable regression models for performance comparison of different ABC analysis methods.In the second stage of experiment,the ABC analysis methods from the first stage were fine-tuned and compared.PC and WLO are the most preferred methods because of higher total outputs,lower work-in-process levels,and shorter flow times compared with the other two methods.However,the revenue accrued through WLO is higher than that accrued via PC.This study complements existing literature on price setting in manufacturing organizations by delineating classification of finished goods based on both exogenous and production factors. 展开更多
关键词 analytical hierarchy procedure weighted linear optimization CONWIP ABC analysis inventory classification
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水体底泥及岸边土壤有机无机复合体对磷吸附特征对比 被引量:6
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作者 赵兴敏 赵兰坡 +2 位作者 李明堂 郭欣欣 任航 《环境科学学报》 CAS CSCD 北大核心 2014年第5期1285-1291,共7页
以长春市新立城水库底泥及岸边土壤为研究对象,利用平衡吸附法研究底泥、土壤及二者有机无机复合体(砂粒、粉粒和粘粒)对磷的吸附热力学和动力学特征,并探讨底泥和土壤各级复合体对磷的吸附贡献,以期探明底泥和土壤对磷的富集规律.结果... 以长春市新立城水库底泥及岸边土壤为研究对象,利用平衡吸附法研究底泥、土壤及二者有机无机复合体(砂粒、粉粒和粘粒)对磷的吸附热力学和动力学特征,并探讨底泥和土壤各级复合体对磷的吸附贡献,以期探明底泥和土壤对磷的富集规律.结果表明,底泥和土壤对磷的吸附热力学均符合Langmuir方程和Freundlich方程,且底泥对磷的理论最大吸附量约是土壤的3倍.底泥及土壤粘粒复合体对磷的吸附热力学符合Langmuir方程和Freundlich方程,粉粒及砂粒复合体对磷的吸附符合Henry方程.粘粒复合体对磷的吸附量均大于粉粒复合体,而粉粒复合体均大于砂粒复合体.底泥及土壤粘粒复合体对磷的吸附贡献约为60%,粉粒复合体对磷的吸附贡献稍大于砂粒复合体的吸附贡献.底泥、土壤及二者有机无机复合体对磷的吸附动力学符合一级动力学方程、Elovich方程和双常数方程,且均在24 h以内达到吸附平衡.研究结果表明,底泥与岸边土壤对磷的吸附具有相似的规律,且底泥及其复合体对磷的吸附能力均大于土壤,说明若磷素由于地表径流等因素由土壤进入到水体中,底泥对磷会有较强的吸附净化作用,即某种意义上底泥为河流磷素有效的"汇". 展开更多
关键词 底泥 土壤 有机物无机复合体 吸附
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长春市典型高架公路大气环境颗粒物中重金属污染特征 被引量:14
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作者 赵兴敏 杨扬 +3 位作者 郭欣欣 毛艺颖 李明堂 赵兰坡 《环境科学学报》 CAS CSCD 北大核心 2017年第9期3280-3288,共9页
于2014年4—11月对长春市典型高架公路大气颗粒物PM_(2.5)和PM_(10)进行采样,对颗粒物中主要重金属元素的浓度进行了分析,并采用变异系数法、地积累指数法和富集因子法对大气颗粒物重金属污染情况进行评价.研究表明,道路施工期间,PM_(2... 于2014年4—11月对长春市典型高架公路大气颗粒物PM_(2.5)和PM_(10)进行采样,对颗粒物中主要重金属元素的浓度进行了分析,并采用变异系数法、地积累指数法和富集因子法对大气颗粒物重金属污染情况进行评价.研究表明,道路施工期间,PM_(2.5)和PM_(10)中重金属的浓度普遍低于道路运行通车后的浓度,而采暖期重金属的浓度又高于非采暖期的浓度.重金属元素在PM_(2.5)中的含量占PM_(10)中总含量的比例均超过50%,说明颗粒物越细越容易富集重金属.Zn、Fe和Mn的变异系数较小,说明来源稳定,自然源占主导地位.富集因子法表明,Zn的富集程度极强,Mn无富集.Cr和Cd的变异系数较大,受人为活动干扰严重,在道路施工期间二者富集程度较轻,道路通行加之采暖后富集程度加强,主要来源为汽油和煤的燃烧.Pb、Cu和Ni的变异系数在0.56~0.76之间,有一定的人为干扰,Pb和Ni在高架公路施工期富集程度较轻,道路运行及取暖期富集程度显著,主要来源是交通源;Cu富集程度强,主要来源可能是油燃烧、建筑扬尘. 展开更多
关键词 交通环境 PM_(2.5)和PM_(10) 重金属 污染评价 来源分析
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A systematic approach in load disaggregation utilizing a multi-stage classification algorithm for consumer electrical appliances classification 被引量:5
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作者 Chuan Choong YANG Chit Siang SOH Vooi Voon YAP 《Frontiers in Energy》 SCIE CSCD 2019年第2期386-398,共13页
The potential to save energy in existing consumer electrical appliances is very high. One of the ways to achieve energy saving and improve energy use awareness is to recognize the energy consumption of individual elec... The potential to save energy in existing consumer electrical appliances is very high. One of the ways to achieve energy saving and improve energy use awareness is to recognize the energy consumption of individual electrical appliances. To recognize the energy consumption of consumer electrical appliances, the load disaggregation methodology is utilized. Non-intrusive appliance load monitoring (NIALM) is a load disaggrega-tion methodology that disaggregates the sum of power consumption in a single point into the power consumption of individual electrical appliances. In this study, load disaggregation is performed through voltage and current waveform, known as the V-I trajectory. The classification algorithm performs cropping and image pyramid reduction of the V-I trajectory plot template images before utilizing the principal component analysis (PCA) and the k-nearest neighbor (k-NN) algorithm. The novelty of this paper is to establish a systematic approach of load disaggregation through V-I trajectory-based load signature images by utilizing a multi-stage classification algorithm methodol-ogy. The contribution of this paper is in utilizing the “k- value,” the number of closest data points to the nearest neighbor, in the k-NN algorithm to be effective in classification of electrical appliances. The results of the multi-stage classification algorithm implementation have been discussed and the idea on future work has also been proposed. 展开更多
关键词 LOAD DISAGGREGATION voltage-current (V-I) trajectory MULTI-STAGE CLASSIFICATION algorithm principal component analysis (PCA) k-nearest NEIGHBOR (k-NN)
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