The low spatial charge-storage density of porous carbons greatly limits volumetric performance in electrochemical capacitors.An increase of charge-storage density requires structural refinements to balance the trade-o...The low spatial charge-storage density of porous carbons greatly limits volumetric performance in electrochemical capacitors.An increase of charge-storage density requires structural refinements to balance the trade-offs between the porosity and density of materials,but the limited mechanical properties of carbons usually fail to withstand effective densifying processes and obtain an ideal pore structure.Herein,we design the stiffened graphene of superior bending rigidity,enabling the fine adjustments of pore structure to maximize the volumetric capacitance for the graphene-based electrodes.The inplane crumples on graphene sheets are found to contribute largely to the bending rigidity,which is useful to control the structural evolution and maintain sufficient ion-accessible surface area during the assembling process.This makes the capacitance of stiffening activated graphene keep 98%when the electrode density increases by 769%to reach 1.13 g cm^(-3) after mechanical pressure,an excellent volumetric energy density of 98.7 Wh L^(-1) in an ionic-liquid electrolyte is achieved.Our results demonstrate the role of intrinsic material properties on the performance of carbon-based electrodes for capacitive energy storage.展开更多
The development of tissue engineering and regeneration research has created new platforms for bone transplantation.However,the preparation of scaffolds with good fiber integrity is challenging,because scaffolds prepar...The development of tissue engineering and regeneration research has created new platforms for bone transplantation.However,the preparation of scaffolds with good fiber integrity is challenging,because scaffolds prepared by traditional printing methods are prone to fiber cracking during solvent evaporation.Human skin has an excellent natural heat-management system,which helps to maintain a constant body temperature through perspiration or blood-vessel constriction.In this work,an electrohydrodynamic-jet 3D-printing method inspired by the thermal-management system of skin was developed.In this system,the evaporation of solvent in the printed fibers can be adjusted using the temperature-change rate of the substrate to prepare 3D structures with good structural integrity.To investigate the solvent evaporation and the interlayer bonding of the fibers,finite-element analysis simulations of a three-layer microscale structure were carried out.The results show that the solvent-evaporation path is from bottom to top,and the strain in the printed structure becomes smaller with a smaller temperaturechange rate.Experimental results verified the accuracy of these simulation results,and a variety of complex 3D structures with high aspect ratios were printed.Microscale cracks were reduced to the nanoscale by adjusting the temperature-change rate from 2.5 to 0.5℃s-1.Optimized process parameters were selected to prepare a tissue engineering scaffold with high integrity.It was confirmed that this printed scaffold had good biocompatibility and could be used for bone-tissue regeneration.This simple and flexible 3D-printing method can also help with the preparation of a wide range of micro-and nanostructured sensors and actuators.展开更多
High efficiency, environmental protection and sustainability have become the main theme of the development of the protection engineering, requiring that the components not only meet the basic functions, but also have ...High efficiency, environmental protection and sustainability have become the main theme of the development of the protection engineering, requiring that the components not only meet the basic functions, but also have chemical properties such as acid and alkali corrosion resistance and aging resistance. Polyisocyanate-oxazodone(POZD) polymer has the above characteristics, it also has the advantages of strong toughness, high strength and high elongation. The concrete slab sprayed with POZD material has excellent anti-blast performance. In order to explore the damage characteristics of POZD sprayed concrete slabs under the action of contact explosion thoroughly, the contact explosion test of POZD concrete slabs with different charges were carried out. On the basis of experimental verification,numerical simulation were used to study the influence of the thickness of the POZD on the blast resistance of the concrete slab. According to the test and numerical simulation results that as the thickness of the coating increases, the anti-blast performance of the concrete slab gradually increases,and the TNT equivalent required for critical failure is larger. Based on the above analysis, empirical expressions on normalized crater diameter, the normalized spall diameter and normalized spall diameter are obtained.展开更多
In this paper,UR50 ultra-early-strength cement-based self-compacting high-strength concrete slabs(URCS)have been subjected to contact explosion tests with different TNT charge quality,aiming to evaluate the anti-explo...In this paper,UR50 ultra-early-strength cement-based self-compacting high-strength concrete slabs(URCS)have been subjected to contact explosion tests with different TNT charge quality,aiming to evaluate the anti-explosive performance of URCS.In the experiment,three kinds of ultra-early-strength cement-based reinforced concrete slabs with different reinforcement ratios and a normal concrete slab(NRCS)were used as the control specimen,the curing time of URCS is 28 days and 24 h respectively.The research results show that URCS has a stronger anti-explosion ability than NRCS.The failure mode of URCS under contact explosion is that the front of the reinforced concrete slab explodes into a crater,and the back is spall.With the increase of the charge,the failure mode of the reinforced concrete slab gradually changed to explosive penetration and explosive punching.The experiment results also show that the reinforcement ratio of URCS has little effect on the anti-blast performance,and URCS can reach its anti-blast performance at 28 days after curing for 24 h.On this basis,the damage parameters of URCS for different curing durations were quantified,and an empirical formula for predicting the diameter of the crater and spalling was established.展开更多
The ether electrolytes usually outperform ester electrolytes by evaluating sodium-ion batteries(SIBs)rate performance,which is a near-unanimous conclusion of previous studies based on an essential configuration of the...The ether electrolytes usually outperform ester electrolytes by evaluating sodium-ion batteries(SIBs)rate performance,which is a near-unanimous conclusion of previous studies based on an essential configuration of the half-cell test.However,here we find that contrary to consensus,the ester electrolyte shows better Na storage capability than the ether electrolyte in full cells.An in-depth analysis of three-electrode,symmetric cell,and in situ XRD tests indicates that traditional half-cell test results are unreliable due to interference from Na electrodes.In particular,Na electrodes show a huge stability difference in ester and ether electrolytes,and ester electrolytes suffer more severe interference than ether electrolytes,resulting in the belief that esters are far inferior to ether electrolytes.More seriously,the more accurate three-electrode test would also suffer from Na electrode interference.Thus,a“corrected half-cell test”protocol is developed to shield the Na electrode interference,revealing the very close super rate capability of hard carbon in ester and ether electrolytes.This work breaks the inherent perception that the kinetic properties of ester electrolytes are inferior to ethers in sodium-ion batteries,reveals the pitfalls of half-cell tests,and proposes a new test protocol for reliable results,greatly accelerating the commercialization of sodium-ion batteries.展开更多
基金financial support from the National Natural Science Foundation of China(22078164,and 22079164)the Major Special Projects of the Plan“Science and Technology Innovation 2025”in Ningbo(2019B10045)。
文摘The low spatial charge-storage density of porous carbons greatly limits volumetric performance in electrochemical capacitors.An increase of charge-storage density requires structural refinements to balance the trade-offs between the porosity and density of materials,but the limited mechanical properties of carbons usually fail to withstand effective densifying processes and obtain an ideal pore structure.Herein,we design the stiffened graphene of superior bending rigidity,enabling the fine adjustments of pore structure to maximize the volumetric capacitance for the graphene-based electrodes.The inplane crumples on graphene sheets are found to contribute largely to the bending rigidity,which is useful to control the structural evolution and maintain sufficient ion-accessible surface area during the assembling process.This makes the capacitance of stiffening activated graphene keep 98%when the electrode density increases by 769%to reach 1.13 g cm^(-3) after mechanical pressure,an excellent volumetric energy density of 98.7 Wh L^(-1) in an ionic-liquid electrolyte is achieved.Our results demonstrate the role of intrinsic material properties on the performance of carbon-based electrodes for capacitive energy storage.
基金supported by the National Natural Science Foundation of China(Grant No.52105577)the Natural Science Foundation of Zhejiang Province(Grant Nos.LQ22E050001 and LQ21E080007)+1 种基金the Natural Science Foundation of Ningbo(Grant Nos.2021J088 and 2023J376)the Ningbo Yongjiang Talent Introduction Program(Grant No.2021A-137-G).
文摘The development of tissue engineering and regeneration research has created new platforms for bone transplantation.However,the preparation of scaffolds with good fiber integrity is challenging,because scaffolds prepared by traditional printing methods are prone to fiber cracking during solvent evaporation.Human skin has an excellent natural heat-management system,which helps to maintain a constant body temperature through perspiration or blood-vessel constriction.In this work,an electrohydrodynamic-jet 3D-printing method inspired by the thermal-management system of skin was developed.In this system,the evaporation of solvent in the printed fibers can be adjusted using the temperature-change rate of the substrate to prepare 3D structures with good structural integrity.To investigate the solvent evaporation and the interlayer bonding of the fibers,finite-element analysis simulations of a three-layer microscale structure were carried out.The results show that the solvent-evaporation path is from bottom to top,and the strain in the printed structure becomes smaller with a smaller temperaturechange rate.Experimental results verified the accuracy of these simulation results,and a variety of complex 3D structures with high aspect ratios were printed.Microscale cracks were reduced to the nanoscale by adjusting the temperature-change rate from 2.5 to 0.5℃s-1.Optimized process parameters were selected to prepare a tissue engineering scaffold with high integrity.It was confirmed that this printed scaffold had good biocompatibility and could be used for bone-tissue regeneration.This simple and flexible 3D-printing method can also help with the preparation of a wide range of micro-and nanostructured sensors and actuators.
基金the financial support from National Natural Science Foundation of China (Grant Nos. 11302261 and 11972201)supported by the project of Key Laboratory of Impact and Safety Engineering (Ningbo University),Ministry of Education. The project number is CJ202011。
文摘High efficiency, environmental protection and sustainability have become the main theme of the development of the protection engineering, requiring that the components not only meet the basic functions, but also have chemical properties such as acid and alkali corrosion resistance and aging resistance. Polyisocyanate-oxazodone(POZD) polymer has the above characteristics, it also has the advantages of strong toughness, high strength and high elongation. The concrete slab sprayed with POZD material has excellent anti-blast performance. In order to explore the damage characteristics of POZD sprayed concrete slabs under the action of contact explosion thoroughly, the contact explosion test of POZD concrete slabs with different charges were carried out. On the basis of experimental verification,numerical simulation were used to study the influence of the thickness of the POZD on the blast resistance of the concrete slab. According to the test and numerical simulation results that as the thickness of the coating increases, the anti-blast performance of the concrete slab gradually increases,and the TNT equivalent required for critical failure is larger. Based on the above analysis, empirical expressions on normalized crater diameter, the normalized spall diameter and normalized spall diameter are obtained.
基金financial support from National Natural Science Foundation of China(Grant No.11302261 and No.11972201)supported by the project of Key Laboratory of Impact and Safety Engineering(Ningbo University),Ministry of Education.The project number is CJ202011.
文摘In this paper,UR50 ultra-early-strength cement-based self-compacting high-strength concrete slabs(URCS)have been subjected to contact explosion tests with different TNT charge quality,aiming to evaluate the anti-explosive performance of URCS.In the experiment,three kinds of ultra-early-strength cement-based reinforced concrete slabs with different reinforcement ratios and a normal concrete slab(NRCS)were used as the control specimen,the curing time of URCS is 28 days and 24 h respectively.The research results show that URCS has a stronger anti-explosion ability than NRCS.The failure mode of URCS under contact explosion is that the front of the reinforced concrete slab explodes into a crater,and the back is spall.With the increase of the charge,the failure mode of the reinforced concrete slab gradually changed to explosive penetration and explosive punching.The experiment results also show that the reinforcement ratio of URCS has little effect on the anti-blast performance,and URCS can reach its anti-blast performance at 28 days after curing for 24 h.On this basis,the damage parameters of URCS for different curing durations were quantified,and an empirical formula for predicting the diameter of the crater and spalling was established.
基金supported by the National Natural Science Foundation of China(22179094)the Tianjin Research Program of Application Foundation and Advanced Technology of China(15ZCZDGX00270)
文摘The ether electrolytes usually outperform ester electrolytes by evaluating sodium-ion batteries(SIBs)rate performance,which is a near-unanimous conclusion of previous studies based on an essential configuration of the half-cell test.However,here we find that contrary to consensus,the ester electrolyte shows better Na storage capability than the ether electrolyte in full cells.An in-depth analysis of three-electrode,symmetric cell,and in situ XRD tests indicates that traditional half-cell test results are unreliable due to interference from Na electrodes.In particular,Na electrodes show a huge stability difference in ester and ether electrolytes,and ester electrolytes suffer more severe interference than ether electrolytes,resulting in the belief that esters are far inferior to ether electrolytes.More seriously,the more accurate three-electrode test would also suffer from Na electrode interference.Thus,a“corrected half-cell test”protocol is developed to shield the Na electrode interference,revealing the very close super rate capability of hard carbon in ester and ether electrolytes.This work breaks the inherent perception that the kinetic properties of ester electrolytes are inferior to ethers in sodium-ion batteries,reveals the pitfalls of half-cell tests,and proposes a new test protocol for reliable results,greatly accelerating the commercialization of sodium-ion batteries.
