The development of geochemical mapping progressed from local geochemical prospecting through regional geochemical exploration and regional geochemical mapping to national and global geochemical mapping. This paper dis...The development of geochemical mapping progressed from local geochemical prospecting through regional geochemical exploration and regional geochemical mapping to national and global geochemical mapping. This paper discusses the evolution of aims, ideas and methodology of geochemical mapping in Western countries, Russia and China. The sophistication of geochemical mapping methodology will make great contributions to solving resources and environmental problems in the 21^st century.展开更多
Gold geochemical provinces in China were delineated through stream sediment or catchment sediment sampling in this study.Each gold geochemical province delineated by a threshold value of 2.5 ng/g covers an area of tho...Gold geochemical provinces in China were delineated through stream sediment or catchment sediment sampling in this study.Each gold geochemical province delineated by a threshold value of 2.5 ng/g covers an area of thousands of kilometers.It is a dilemma that geochemists traditionally thought that gold could not migrate for a long distance in rivers or streams to form a large-scale geochemical anomaly due to its chemical inertness and high specific density.The quantitative spectroscopic analysis and observations under a scanning electron microscope （SEM） indicate the presence of submicroscopic gold particles （〈5 μm in diameter） in large quantities,and observations under a Transmission Electron Microscopy （TEM） further suggest the presence of nanoscale gold particles （several tens of nanometre in diameter） in ores,rocks,soils and stream sediments.Particularly,submicroscopic and nanoscale gold particles less than 5 μm were only found in samples having a low gold content （〈10ng/g）.This result shows that geochemical provinces,delineated by a threshold value of 2.5 ng/g,are formed by long-distance transport of ultrafine gold in streams.The findings may provide direct microscopic evidence for gold migration to form geochemical provinces.展开更多
Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELI...Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELIP)yielded timing of formation and post-eruption tectonothermal event.Holistic lithogeochemistry and elements mapping of basaltic rocks were further reevaluated to provide insights into crustal contamination and formation of the ELIP.A zircon U–Pb age of 251.3±2.0 Ma of the Wude basalt recorded the youngest volcanic eruption event and was consistent with the age span of 251-263 Ma for the emplacement of the ELIP.Such zircons hadε_(Hf)(t)values ranging from7.3 to+2.2,identical to those of magmatic zircons from the intrusive rocks of the ELIP,suggesting that crust-mantle interaction occurred during magmatic emplacement,or crust-mantle mixing existed in the deep source region prior to deep melting.The apatite U–Pb age at 53.6±3.4 Ma recorded an early Eocene magmatic superimposition of a regional tectonothermal event,corresponding to the Indian–Eurasian plate collision.Negative Nb,Ta,Ti and P anomalies of the Emeishan basalt may reflect crustal contamination.The uneven Nb/La and Th/Ta values distribution throughout the ELIP supported a mantle plume model origin.Therefore,the ELIP was formed as a result of a mantle plume which was later superimposed by a regional tectonothermal event attributed to the Indian–Eurasian plate collision during early Eocene.展开更多
Geochemical subsoil data obtained from China and European laboratories have been compared in this study. 787 C horizon subsoil samples from FOREGS （Forum of European Geological Surveys） geochemical baselines mapping...Geochemical subsoil data obtained from China and European laboratories have been compared in this study. 787 C horizon subsoil samples from FOREGS （Forum of European Geological Surveys） geochemical baselines mapping project were sent to China＇s IGGE （Institute of Geophysical and Geochemical Exploration） laboratory and composited to 190 samples according to the 160 kin x 160 km GNT （Global Terrestrial Network） cells. In addition to the FOREGS elemental analysis package, Au, Pt, Pd, B, Ge, Br, CI, Se, N, Li and F were also analyzed by using the IGGE＇s 76 element analytical scheme. Geochemical data statistics, scatter plotting, and geochemical map compilation tech- niques have been employed to investigate differences between FOREGS and IGGE analytical results. The results of two datasets, the IGGE＇s analysis data for composited samples, and the FOREGS average data of samples in each GNT cell, agree extremely well lor about 23 elements, viz： SiO2, St, Al2O3, Zr, Ba, Fe2O3, Ti, Rb, Mn, Gd, CaO, Ga, MgO, P, Pb, Na2O, Y, Th, As, U Sc, Cr, and Co. There are slight differences between-laboratory biases shown as proportional errors between the datasets for Ni, K2O, Tb, Tl, Cu, S, Sin, La, Ce, Pr, Nd, Eu, Ho, Er, Tin, Yb, Lu, Ta, Nb, HE and Dy. For Cd, Cs, Be, Sb, In, Mo, I, Sn, and Te, the correlation of the two datasets and the similarity of the geochemical maps are fairly good, but obvious biases exist between the two datasets at values near detection limits.展开更多
To understand the levels of potentially toxic elements(PTEs)contamination in soils and their effects on human health from different agricultural land use in Sanya,China.128 soil samples(64 topsoil samples and correspo...To understand the levels of potentially toxic elements(PTEs)contamination in soils and their effects on human health from different agricultural land use in Sanya,China.128 soil samples(64 topsoil samples and corresponding subsoil samples)were collected from the five representative land-use patterns.Inductively coupled plasma mass spectrometry(ICP-MS),Atomic fluorescence spectrometry(AFS),and Inductively coupled plasma optical emission spectrometry(ICP-OES)were used to determine the content of PTEs(As,Cd,Hg,Cu,Cr,Ni,Pb,Zn,Co,Mo,Sb,and V).Correlation analysis and factor analysis were used to determine the source of PTEs.Geo-accumulation index(I_(geo)),hazard quotient(HQ),and total carcinogenic risk index(TR)were used to measure the PTEs contamination and its relative health impacts.Results showed that the average values of 12 PTEs in topsoil were higher than the Hainan soil geochemical baseline,showing different degrees of PTEs accumulation effect.The concentration of PTEs in the topsoil was lower than those in the subsoil except for Cd and Hg.The I_(geo)revealed that the major accumulated element in soils was As followed by Mo.Source apportionment suggested that parent materials and agricultural practices were the dominant factors for PTEs accumulation in the topsoil.Noncarcinogenic risks of soil samples from five land-use patterns presented a trend of paddy field>dry field>woodland>orchard>garden plot.However,the HQ values of 12 PTEs were less than the recommended limit of HQ=1,representing that there are no non-carcinogenic risks of PTEs for children and adults in the study area.The TR values are within 6.95×10^(-6)-1.38×10^(-5),which corresponds to the low level.Therefore the PTEs in the agricultural soil of the study area show little influence on the health status of the local population.展开更多
Hot dry rock(HDR)is a kind of clean energy with significant potential.Since the 1970s,the United States,Japan,France,Australia,and other countries have attempted to conduct several HDR development research projects to...Hot dry rock(HDR)is a kind of clean energy with significant potential.Since the 1970s,the United States,Japan,France,Australia,and other countries have attempted to conduct several HDR development research projects to extract thermal energy by breaking through key technologies.However,up to now,the development of HDR is still in the research,development,and demonstration stage.An HDR exploration borehole(with 236℃ at a depth of 3705 m)was drilled into Triassic granite in the Gonghe Basin in northwest China in 2017.Subsequently,China Geological Survey(CGS)launched the HDR resources exploration and production demonstration project in 2019.After three years of efforts,a sequence of significant technological breakthroughs have been made,including the genetic model of deep heat sources,directional drilling and well completion in high-temperature hard rock,large-scale reservoir stimulation,reservoir characterization,and productivity evaluation,reservoir connectivity and flow circulation,efficient thermoelectric conversion,monitoring,and geological risk assessment,etc.Then the whole-process technological system for HDR exploration and production has been preliminarily established accordingly.The first power generation test was completed in November 2021.The results of this project will provide scientific support for HDR development and utilization in the future.展开更多
The Greenland–Iceland–Faroe Ridge,located between the central eastern part of Greenland and the northwestern edge of Europe,spans across the North Atlantic.As the core component of the Greenland–Iceland–Faroe Ridg...The Greenland–Iceland–Faroe Ridge,located between the central eastern part of Greenland and the northwestern edge of Europe,spans across the North Atlantic.As the core component of the Greenland–Iceland–Faroe Ridge,the Iceland is an alkaline basalt area,which belongs to the periodic submarine magmatism and submarine volcano eruption resulting from mantle plume upwelling(Jiang et al.,2020).For the oceanic plateaus,the characteristics of the Iceland are closest to the continental crust,so the Iceland is considered the most suitable for simulating the earliest continental crust on the Earth(Reimink et al.,2014).展开更多
Dongping Lake area,located in the lower reaches of Yellow River,is an ideal place to study the changes of modern river and lake sedimentary environment.The sediment samples of Dawen River,Yellow River,and Dongping Lak...Dongping Lake area,located in the lower reaches of Yellow River,is an ideal place to study the changes of modern river and lake sedimentary environment.The sediment samples of Dawen River,Yellow River,and Dongping Lake were collected,and the major elements,trace elements and organic matter geochemical composition of the samples were analyzed.Cluster analysis,characteristic element ratio method and graphic method were used to explore the geochemical characteristics of sediments and their environmental implication.The results show that the contents of SiO_(2),Na_(2)O,TiO_(2) and Zr in sediments of Dawen River and Yellow River are relatively high,and the contents of iron and manganese oxides,organic matter,CaO,P2O5 and Sr in lake sediments are relatively high.That reveals the differences of sedimentary environments between the rivers and the lake.The contents of Sr and Zr in Dawen River are affected by the rapid migration of clastic materials in the upstream carbonate source area during the flood season;the δCe,ΣREE and REE’s ratios in the sediments of the Yellow River reflect the influence of the Loess source;and the distribution of elements changes along the flow direction during the flood season.The characteristics of pH,element composition and LREE&HREE fractionation of the lake sediments indicate that the sediment source is complex,and the lake environment is affected by the flood season.The study shows that the geochemical content and its variation characteristics of sediments effectively reveal the sedimentary environment,material composition and characteristics of flood season of rivers and the lake in the study area.展开更多
The Caixiashan-Weiquan area is an important ore concentration area in the eastern Tianshan metallogenic belt. Firstly, this paper studies geochemical features of 1564 samples of 1：200000 stream sediments of the Matou...The Caixiashan-Weiquan area is an important ore concentration area in the eastern Tianshan metallogenic belt. Firstly, this paper studies geochemical features of 1564 samples of 1：200000 stream sediments of the Matoutan mapsheet, where the Caixiashan and Weiquan deposits are located. Processing, analysis and explanation of exploration geochemical data play an important role in the procedure of finding the ore, which are related to whether the measured elements content of geochemical samples can effectively guide the work of mineral exploration. As a highly nonlinear dynamical system, the neural network is more analogous to the human brains in terms of principles and features compared with conventional geochemical approaches. It can adapt itself to the environment, sum up laws, complete pattern recognition. Secondly, the authors used the Kohonen neural network to classify all samples based on 10 mineralization elements of stream sediment samples in order to determine possible mineral ores, reduce the scope of ore targets and study indicator elements of the ninth group of samples, which is the mostly closest to the deposit. The results show that the neural network can delineate metallogenic prospective areas and is effective in the discovery of deep geochemical information.展开更多
Various petrographic features and geochemical characteristics indicative of disequilibrium are preserved in plagioclase phenocrysts from basaltic to andesitic lavas in East Junggar, northwest China. These characterist...Various petrographic features and geochemical characteristics indicative of disequilibrium are preserved in plagioclase phenocrysts from basaltic to andesitic lavas in East Junggar, northwest China. These characteristics indicate that they crystallized in a magma chamber, which was replenished by less differentiated and high-temperature magmas. The petrographic and geochemical features of the plagioclase phenocrysts are interpreted to record responses to changes in temperature, composition and mechanical effect during magma replenishment. Distinct rare earth element(REE) patterns between cores and rims of the same plagioclase crystal suggest derivation from two end-member magmas. From core to rim, plagioclase phenocrysts commonly display sharp fluctuations of anorthite(An) content up to 20, which either correspond to reverse zoning associated with ovoidal cores and resorption surface(PI), or normal zoning with euhedral form and no resorption surface(P2). Plagioclase crystals with diverse textures and remarkably different An content coexist on the scale of a thin-section. Cores of these plagioclases in each sample display a bimodal distribution of An content. From core to rim in PI, concentrations o f FeOT and Sr increase remarkably as An content increases. During magma replenishment, pre-existing plagioclase phenocrysts in the andesitic magma, which were immersed into hotter and less differentiated magmas, were heated and resorbed to form ovoidal cores, and then were overgrown by a thin rim with much higher contents of An, FeO^T and Sr. However, pre-existing plagioclase phenocrysts in the basaltic magma were injected into cooler and more evolved magmas, and were remained as euhedral cores, which were later enclosed by oscillatory zoned rims with much lower contents of An, Sr and Ba.展开更多
1 Introduction Geochemical mapping at national and continental scales continues to present challenges worldwide due to variations in geologic and geotectonic units.Use of the proper sampling media can provide rich inf...1 Introduction Geochemical mapping at national and continental scales continues to present challenges worldwide due to variations in geologic and geotectonic units.Use of the proper sampling media can provide rich information on展开更多
1 Introduction Although a mumerous of papers were reported for the chemcial or instrumental analysis of inorganic elements for the geocheical samples(Sun and Xie,2014;Sun et al.,2014;Rao et al.,2004).However,the analy...1 Introduction Although a mumerous of papers were reported for the chemcial or instrumental analysis of inorganic elements for the geocheical samples(Sun and Xie,2014;Sun et al.,2014;Rao et al.,2004).However,the analytical methods展开更多
The Yishui complex,located in the western Shandong area of the North China Craton,is representative of the Archean crystalline basement of the North China Craton to explore the early tectonic-thermal evolution history...The Yishui complex,located in the western Shandong area of the North China Craton,is representative of the Archean crystalline basement of the North China Craton to explore the early tectonic-thermal evolution history of the Earth.Detailed petrography,mineral chemistry,metamorphic evolution and zircon U-Pb dating are presented for felsic granulite and two-pyroxene granulite from the Yishui complex to contribute to new insights into the Neoarchean tectonic evolution of the North China Craton.Three mineral assemblages are recognized for these granulite samples,including the prograde(M1),peak(M2)and retrograde(M3)mineral assemblages.Conventional geothermobarometry and phase equilibrium modeling yield P-T conditions of 6.5-10.9 kbar/718-839℃ for the peak metamorphism,which define a medium-pressure granulite-facies metamorphism occurred at middle to lower crust.Anticlockwise P-T paths with near-isobaric cooling(IBC)retrograde segments were reconstructed.Zircon LA-ICP-MS U-Pb dating suggests that the protolith of the felsic granulite was emplaced at 2541±7 Ma and the subsequent medium-pressure granulite-facies metamorphism occurred at 2518-2494 Ma.A two-stage mantle plume related crustal-scale sagduction geodynamic regime is proposed in the western Shandong terrane in the Neoarchean.展开更多
Integrated gravitational, electrical-magnetic surveys and data processing carried out in the Sanshandao-Jiaojia area, Eastern Shandong Province, northeast China, aim to illuminate the geological characteristics of thi...Integrated gravitational, electrical-magnetic surveys and data processing carried out in the Sanshandao-Jiaojia area, Eastern Shandong Province, northeast China, aim to illuminate the geological characteristics of this shallow-covered area and delineate deep-seated gold prospecting targets. In this region, altogether 12 faults exert critical control on distribution of three types of Early Precambrian metamorphic rock series, i.e. those in the metamorphic rock area, in the granitic rock area underlying the metamorphic rock, and in the remnant metamorphic rock area in granites, respectively. Additionally, the faults have major effects on distribution of four Mesozoic Linglong rock bodies of granite, i.e. the Cangshang, Liangguo, Zhuqiao-Miaojia and Jincheng granites. The Sanshandao and Jiaojia Faults are two well-known regional ore-controlling faults; they have opposite dip direction, and intersect at a depth of 4500 m. Fracture alteration zones have striking geophysical differences relative to the surrounding county rocks. The two faults extend down along dip direction in a gentle wave form, and appear at some steps with different dips. These steps comprise favorable gold prospecting areas, consistent with a step metallogenic model. Six deep-seated gold-prospecting targets are delineated, i.e. Jincheng-Qianchenjia, Xiaoxizhuang-Zhaoxian, Xiyou-Wujiazhuangzi, Xiangyangling-Xinlicun, Panjiawuzi and Miaojia-Pinglidian.展开更多
This paper discusses the enrichment and depletion regularities for porphyry coppermolybdenum ore deposits in different regions and varied deposit genetic types in the same area, taking three porphyry copper-molybdenum...This paper discusses the enrichment and depletion regularities for porphyry coppermolybdenum ore deposits in different regions and varied deposit genetic types in the same area, taking three porphyry copper-molybdenum ore deposits （i.e., the Chengmenshan in Jiangxi, Wunugetushan in Inner Mongolia, Baishantang in Gansu） and two copper deposits in Gansu Province （the Huitongshan skarn deposit and Gongpoquan composite deposit） as case studies. The results show that porphyry Cu-Mo deposits or skarn copper deposits include both enrichment of the ore-forming elements and associated elements, and depletion of some lithophile dispersed elements, rare earth elements （REE） and some major elements. And the depleted elements vary with deposits, having generality and their own features. On a deposit scale, the positive anomalies of enriched elements and negative anomalies of depleted elements follow in a sequence to comprise regular anomaly models of spatial structures. The exploration in the Tongchang deposit in Jiangxi and Huitongshan deposit in Gansu suggests that anomaly models play a key role in the identification of mineral occurrences and deposits compared to one single enriched element anomaly. And the anomaly models exert a critical effect on the optimization of prospecting targets and their potential evaluation.展开更多
The Panxi region is located in the frontal zone of positive squeezing subduction and side squeezing shearing between the Indian plate and the Eurasian plate. The long-period magnetotelluric （LMT） and broadband magne...The Panxi region is located in the frontal zone of positive squeezing subduction and side squeezing shearing between the Indian plate and the Eurasian plate. The long-period magnetotelluric （LMT） and broadband magnetotelluric （MT） techniques are both used to study the deep electrical conductivity structure in this region; magnetic and gravity surveys are also performed along the profile. According to the 2-D resistivity model along the Yanyuan-Yongshan profile, a high- conductivity layer （HCL） exists widely in the crust, and a high-resistivity block （HRB） exists widely in the upper mantle in general, as seen by the fact that a large HCL exists from the western Jinpingshan tectonic zone to the eastern Mabian tectonic zone in the crust, while the HRB found in the Panxi tectonic zone is of abnormally high resistivity in that background compared to both sides of Panxi tectonic zone. In addition, the gravity and magnetic field anomalies are of high value. Combined with geological data, the results indicate that there probably exists basic or ultrabasic rock with a large thickness in the lithosphere in the Panxi axial region, which indicates that fracture activity once occurred in the lithosphere. As a result, we can infer that the high-resistivity zone in the Panxi lithosphere is the eruption channel for Permian Emeishan basalt and the accumulation channel for basic and ultrabasic rock. The seismic sources along the profile are counted according to seismic record data. The results indicate that the most violent earthquake sources are located at the binding site of the HRB and the HCL, where the tectonic activity zone is generally acknowledged to be; however, the earthquakes occurring in the HCL are not so violent, which reflects the fact that the HCL is a plastic layer, and the fracture threshold of a plastic layer is low generally, making high stress difficult to accumulate but easy to release in the layer. As a result, a higher number of smaller earthquakes occurred in the HCL at Daliangshan tectonic zone, and violent earthquakes occurred at the binding site of high- and low-resistivity blocks at the Panxi tectonic zone.展开更多
A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sedim...A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）.展开更多
To illuminate the migration and transformation of selenium(Se)in the igneous rock-soil-rice system,285 pairs of rhizosphere soil and rice samples were collected from the granitoid and basalt areas in Hainan Province,S...To illuminate the migration and transformation of selenium(Se)in the igneous rock-soil-rice system,285 pairs of rhizosphere soil and rice samples were collected from the granitoid and basalt areas in Hainan Province,South China.The contents of Se in soils derived from granitoid and basalt are,respectively,0.19±0.12 mg/kg and 0.34±0.39 mg/kg,which are much higher than Se contents in granitoid and basalt.Selenium shows remarkable enrichment from granitoid and basalt to soils.The mobile fraction of Se in soils derived from granitoid is 0.0100±0.0034 mg/kg,which is significantly higher than that of basalt(0.0058±0.0039 mg/kg).Although soil derived from basalt shows higher Se contents,Se contents in rice samples,mobile fractions of Se in soils,and biological concentration factor(BCF)is similar or even lower than that from granitoid.Basalt consist of calcic plagioclase and pyroxene,and are much richer in Fe,Al,and Ca than granitoid.Correspondingly,the basalt-derived soils have higher goethite,hematite,kaolinite,cation exchange capacity(CEC)content,and higher p H than the granitoid-derived soils,which result in higher adsorption capacity for Se and relatively lower Se bioavailability.Soils derived from granitoid and basalt in tropical regions are beneficial to produce Se-rich rice.展开更多
Actual granitoid analytical data of 767 composited samples are presented here. The data source is 6080 samples collected mainly from 750 large- to middle-sized granitoid bodies across China. Data from the composited s...Actual granitoid analytical data of 767 composited samples are presented here. The data source is 6080 samples collected mainly from 750 large- to middle-sized granitoid bodies across China. Data from the composited samples, which includes that of 70 elements, is analyzed according to geological age - Archeozoic （Ar）, Proterozoic （Pt）, Eopaleozoic （PZl）, Neopaleozoic （Pz2）, Mesozoic （Mz）, and Cenozoic （Cz） - and three major compositional varieties, e.g. alkali-feldspar granite, syenogranite and adamellite. Petrochemical parameters, trace-element content and rare-earth element （REE） distribu- tions of the different rock types and geological ages are characterized, and change tendencies through Archean to Cenozoic time are recorded. The comprehensive analytical data presented here has not been previously published. This significant data set can be used as fundamental information in studies of basic China geology, magma petrogenesis, ore exploration and geochemistry.展开更多
Gas hydrate, mainly composed of hydrocarbon gas and water, is considered to be a clean energy in the 21st century. Many indicators such as BSRs （Bottom-Simulating Reflections）, which are thought to be related to gas...Gas hydrate, mainly composed of hydrocarbon gas and water, is considered to be a clean energy in the 21st century. Many indicators such as BSRs （Bottom-Simulating Reflections）, which are thought to be related to gas hydrate, are found in the South China Sea （SCS） in recent years. The northeastern part of the SCS is taken as one of the most potentials in the area by many scientists. It is situated in the conjunction of the northern divergent continental margin and the eastern convergent island margin, whose geological settings are much preferable for gas hydrate to occur. Through this study, brightness temperature anomalies recorded by satellite-based thermal infrared remotely sensed images before or within the imminent earthquake, the high content of hydrocarbon gas acid-degassed from subsurface sediment and the high radioactive thermoluminescence value of subsurface sediment were found in the region. Sometimes brightness temperature anomalies alone exist in the surrounding of the Dongsha Islands. The highest content of hydrocarbon gas amounts to 393 μL methane per kilogram sediment and the highest radioactive thermoluminescence value is 31752 unit; their geometric averages are 60.5 μL/kg and 2688.9 unit respectively. What is more inspiring is that there are three sites where the methane contents are up to 243, 268 and 359μL/kg and their radioactive thermoluminescence values are 8430, 9537 and 20826 unit respectively. These three locations are just in the vicinity of one of the highest confident BSRs identified by predecessors. Meanwhile, the anomalies are generally coincident with other results such as headspace gas anomaly in the sediment and chloride anomaly in the interstitial water in the site 1146 of Leg 184. The above-mentioned anomalies are most possibly to indicate the occurrence of gas hydrate in the northeastern SCS.展开更多
文摘The development of geochemical mapping progressed from local geochemical prospecting through regional geochemical exploration and regional geochemical mapping to national and global geochemical mapping. This paper discusses the evolution of aims, ideas and methodology of geochemical mapping in Western countries, Russia and China. The sophistication of geochemical mapping methodology will make great contributions to solving resources and environmental problems in the 21^st century.
基金supported by the program of Deep Exploration in China (Sinoprobe)the projects of China Geochemical Baselines (Sinoprobe-04-01)Deeppenetrating Geochemical Exploration (Sinoprobe-04-03).
文摘Gold geochemical provinces in China were delineated through stream sediment or catchment sediment sampling in this study.Each gold geochemical province delineated by a threshold value of 2.5 ng/g covers an area of thousands of kilometers.It is a dilemma that geochemists traditionally thought that gold could not migrate for a long distance in rivers or streams to form a large-scale geochemical anomaly due to its chemical inertness and high specific density.The quantitative spectroscopic analysis and observations under a scanning electron microscope （SEM） indicate the presence of submicroscopic gold particles （〈5 μm in diameter） in large quantities,and observations under a Transmission Electron Microscopy （TEM） further suggest the presence of nanoscale gold particles （several tens of nanometre in diameter） in ores,rocks,soils and stream sediments.Particularly,submicroscopic and nanoscale gold particles less than 5 μm were only found in samples having a low gold content （〈10ng/g）.This result shows that geochemical provinces,delineated by a threshold value of 2.5 ng/g,are formed by long-distance transport of ultrafine gold in streams.The findings may provide direct microscopic evidence for gold migration to form geochemical provinces.
基金the National Natural Science Foundation of China(91962106,41702069)the National Key Research Program(2019YFA0708603)+4 种基金the Fundamental Research Funds for the Central Universities,China(2652018125)the 111 Project of the Ministry of Science and Technology,China(BP0719021)the China International Science and Technology Cooperation Award and the Overseas Experts Exchange Project of the Ministry of Science and Technology,China(G20190001257)the Beijing Nova Program(No.Z201100006820097)the National Natural Science Foundation of China.
文摘Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELIP)yielded timing of formation and post-eruption tectonothermal event.Holistic lithogeochemistry and elements mapping of basaltic rocks were further reevaluated to provide insights into crustal contamination and formation of the ELIP.A zircon U–Pb age of 251.3±2.0 Ma of the Wude basalt recorded the youngest volcanic eruption event and was consistent with the age span of 251-263 Ma for the emplacement of the ELIP.Such zircons hadε_(Hf)(t)values ranging from7.3 to+2.2,identical to those of magmatic zircons from the intrusive rocks of the ELIP,suggesting that crust-mantle interaction occurred during magmatic emplacement,or crust-mantle mixing existed in the deep source region prior to deep melting.The apatite U–Pb age at 53.6±3.4 Ma recorded an early Eocene magmatic superimposition of a regional tectonothermal event,corresponding to the Indian–Eurasian plate collision.Negative Nb,Ta,Ti and P anomalies of the Emeishan basalt may reflect crustal contamination.The uneven Nb/La and Th/Ta values distribution throughout the ELIP supported a mantle plume model origin.Therefore,the ELIP was formed as a result of a mantle plume which was later superimposed by a regional tectonothermal event attributed to the Indian–Eurasian plate collision during early Eocene.
基金given to the Ministry of Land and Resources and the Ministry of Science and Technology for the research funding of the projects: SinoProbe 04 and 863 Project 2007AA06Z133
文摘Geochemical subsoil data obtained from China and European laboratories have been compared in this study. 787 C horizon subsoil samples from FOREGS （Forum of European Geological Surveys） geochemical baselines mapping project were sent to China＇s IGGE （Institute of Geophysical and Geochemical Exploration） laboratory and composited to 190 samples according to the 160 kin x 160 km GNT （Global Terrestrial Network） cells. In addition to the FOREGS elemental analysis package, Au, Pt, Pd, B, Ge, Br, CI, Se, N, Li and F were also analyzed by using the IGGE＇s 76 element analytical scheme. Geochemical data statistics, scatter plotting, and geochemical map compilation tech- niques have been employed to investigate differences between FOREGS and IGGE analytical results. The results of two datasets, the IGGE＇s analysis data for composited samples, and the FOREGS average data of samples in each GNT cell, agree extremely well lor about 23 elements, viz： SiO2, St, Al2O3, Zr, Ba, Fe2O3, Ti, Rb, Mn, Gd, CaO, Ga, MgO, P, Pb, Na2O, Y, Th, As, U Sc, Cr, and Co. There are slight differences between-laboratory biases shown as proportional errors between the datasets for Ni, K2O, Tb, Tl, Cu, S, Sin, La, Ce, Pr, Nd, Eu, Ho, Er, Tin, Yb, Lu, Ta, Nb, HE and Dy. For Cd, Cs, Be, Sb, In, Mo, I, Sn, and Te, the correlation of the two datasets and the similarity of the geochemical maps are fairly good, but obvious biases exist between the two datasets at values near detection limits.
基金supported by Open Foundation of the Key Laboratory of Coupling Process and Effect of Natural Resources Elements(No.2023KFKTB001)the Science&Technology Fundamental Resources Investigation Program(2022FY101800)+2 种基金the National Nonprofit Institute Research Grant of IGGE(AS2023D01)the projects of the China Geological Survey(DD20230309 and DD20190305)the National Natural Science Foundation of China(42002105)。
文摘To understand the levels of potentially toxic elements(PTEs)contamination in soils and their effects on human health from different agricultural land use in Sanya,China.128 soil samples(64 topsoil samples and corresponding subsoil samples)were collected from the five representative land-use patterns.Inductively coupled plasma mass spectrometry(ICP-MS),Atomic fluorescence spectrometry(AFS),and Inductively coupled plasma optical emission spectrometry(ICP-OES)were used to determine the content of PTEs(As,Cd,Hg,Cu,Cr,Ni,Pb,Zn,Co,Mo,Sb,and V).Correlation analysis and factor analysis were used to determine the source of PTEs.Geo-accumulation index(I_(geo)),hazard quotient(HQ),and total carcinogenic risk index(TR)were used to measure the PTEs contamination and its relative health impacts.Results showed that the average values of 12 PTEs in topsoil were higher than the Hainan soil geochemical baseline,showing different degrees of PTEs accumulation effect.The concentration of PTEs in the topsoil was lower than those in the subsoil except for Cd and Hg.The I_(geo)revealed that the major accumulated element in soils was As followed by Mo.Source apportionment suggested that parent materials and agricultural practices were the dominant factors for PTEs accumulation in the topsoil.Noncarcinogenic risks of soil samples from five land-use patterns presented a trend of paddy field>dry field>woodland>orchard>garden plot.However,the HQ values of 12 PTEs were less than the recommended limit of HQ=1,representing that there are no non-carcinogenic risks of PTEs for children and adults in the study area.The TR values are within 6.95×10^(-6)-1.38×10^(-5),which corresponds to the low level.Therefore the PTEs in the agricultural soil of the study area show little influence on the health status of the local population.
基金funded by the“Hot Dry Rock Resources Exploration and Production Demonstration Project”of the China Geological Survey(DD20190131,DD20190135,DD20211336).
文摘Hot dry rock(HDR)is a kind of clean energy with significant potential.Since the 1970s,the United States,Japan,France,Australia,and other countries have attempted to conduct several HDR development research projects to extract thermal energy by breaking through key technologies.However,up to now,the development of HDR is still in the research,development,and demonstration stage.An HDR exploration borehole(with 236℃ at a depth of 3705 m)was drilled into Triassic granite in the Gonghe Basin in northwest China in 2017.Subsequently,China Geological Survey(CGS)launched the HDR resources exploration and production demonstration project in 2019.After three years of efforts,a sequence of significant technological breakthroughs have been made,including the genetic model of deep heat sources,directional drilling and well completion in high-temperature hard rock,large-scale reservoir stimulation,reservoir characterization,and productivity evaluation,reservoir connectivity and flow circulation,efficient thermoelectric conversion,monitoring,and geological risk assessment,etc.Then the whole-process technological system for HDR exploration and production has been preliminarily established accordingly.The first power generation test was completed in November 2021.The results of this project will provide scientific support for HDR development and utilization in the future.
基金granted by National Natural Science Foundation of China(Grant No.42172224)。
文摘The Greenland–Iceland–Faroe Ridge,located between the central eastern part of Greenland and the northwestern edge of Europe,spans across the North Atlantic.As the core component of the Greenland–Iceland–Faroe Ridge,the Iceland is an alkaline basalt area,which belongs to the periodic submarine magmatism and submarine volcano eruption resulting from mantle plume upwelling(Jiang et al.,2020).For the oceanic plateaus,the characteristics of the Iceland are closest to the continental crust,so the Iceland is considered the most suitable for simulating the earliest continental crust on the Earth(Reimink et al.,2014).
基金This study was supported by Opening Fund of Provincial Key Lab of Applied Nuclear Techniques in Geosciences(No.201904)Key Scientific and Technological Project(No.KY201957)of Shandong Bureau of Geology and Mineral Resources.
文摘Dongping Lake area,located in the lower reaches of Yellow River,is an ideal place to study the changes of modern river and lake sedimentary environment.The sediment samples of Dawen River,Yellow River,and Dongping Lake were collected,and the major elements,trace elements and organic matter geochemical composition of the samples were analyzed.Cluster analysis,characteristic element ratio method and graphic method were used to explore the geochemical characteristics of sediments and their environmental implication.The results show that the contents of SiO_(2),Na_(2)O,TiO_(2) and Zr in sediments of Dawen River and Yellow River are relatively high,and the contents of iron and manganese oxides,organic matter,CaO,P2O5 and Sr in lake sediments are relatively high.That reveals the differences of sedimentary environments between the rivers and the lake.The contents of Sr and Zr in Dawen River are affected by the rapid migration of clastic materials in the upstream carbonate source area during the flood season;the δCe,ΣREE and REE’s ratios in the sediments of the Yellow River reflect the influence of the Loess source;and the distribution of elements changes along the flow direction during the flood season.The characteristics of pH,element composition and LREE&HREE fractionation of the lake sediments indicate that the sediment source is complex,and the lake environment is affected by the flood season.The study shows that the geochemical content and its variation characteristics of sediments effectively reveal the sedimentary environment,material composition and characteristics of flood season of rivers and the lake in the study area.
基金granted by the basic scientific research fund of Institute of Mineral Resources,Chinese Academy of Geological Sciences(Grant No.K1103)the National Natural Science Foundation of China(Grant No. 41002119)
文摘The Caixiashan-Weiquan area is an important ore concentration area in the eastern Tianshan metallogenic belt. Firstly, this paper studies geochemical features of 1564 samples of 1：200000 stream sediments of the Matoutan mapsheet, where the Caixiashan and Weiquan deposits are located. Processing, analysis and explanation of exploration geochemical data play an important role in the procedure of finding the ore, which are related to whether the measured elements content of geochemical samples can effectively guide the work of mineral exploration. As a highly nonlinear dynamical system, the neural network is more analogous to the human brains in terms of principles and features compared with conventional geochemical approaches. It can adapt itself to the environment, sum up laws, complete pattern recognition. Secondly, the authors used the Kohonen neural network to classify all samples based on 10 mineralization elements of stream sediment samples in order to determine possible mineral ores, reduce the scope of ore targets and study indicator elements of the ninth group of samples, which is the mostly closest to the deposit. The results show that the neural network can delineate metallogenic prospective areas and is effective in the discovery of deep geochemical information.
基金financial support by the Natural Science Foundation of China (41573030, 41503024)the Geological Survey Program from China Geological Survey (No. DD20190518)
文摘Various petrographic features and geochemical characteristics indicative of disequilibrium are preserved in plagioclase phenocrysts from basaltic to andesitic lavas in East Junggar, northwest China. These characteristics indicate that they crystallized in a magma chamber, which was replenished by less differentiated and high-temperature magmas. The petrographic and geochemical features of the plagioclase phenocrysts are interpreted to record responses to changes in temperature, composition and mechanical effect during magma replenishment. Distinct rare earth element(REE) patterns between cores and rims of the same plagioclase crystal suggest derivation from two end-member magmas. From core to rim, plagioclase phenocrysts commonly display sharp fluctuations of anorthite(An) content up to 20, which either correspond to reverse zoning associated with ovoidal cores and resorption surface(PI), or normal zoning with euhedral form and no resorption surface(P2). Plagioclase crystals with diverse textures and remarkably different An content coexist on the scale of a thin-section. Cores of these plagioclases in each sample display a bimodal distribution of An content. From core to rim in PI, concentrations o f FeOT and Sr increase remarkably as An content increases. During magma replenishment, pre-existing plagioclase phenocrysts in the andesitic magma, which were immersed into hotter and less differentiated magmas, were heated and resorbed to form ovoidal cores, and then were overgrown by a thin rim with much higher contents of An, FeO^T and Sr. However, pre-existing plagioclase phenocrysts in the basaltic magma were injected into cooler and more evolved magmas, and were remained as euhedral cores, which were later enclosed by oscillatory zoned rims with much lower contents of An, Sr and Ba.
基金supported by the Special Scientific Research Fund of Public Welfare Profession of Ministry of Land and Resources of the People’s Republic of China (No. 201011057)
文摘1 Introduction Geochemical mapping at national and continental scales continues to present challenges worldwide due to variations in geologic and geotectonic units.Use of the proper sampling media can provide rich information on
基金Financial support from the Special Fundamental Scientific Research Fund for the National Public Welfare Institutes (AS2010J03)
文摘1 Introduction Although a mumerous of papers were reported for the chemcial or instrumental analysis of inorganic elements for the geocheical samples(Sun and Xie,2014;Sun et al.,2014;Rao et al.,2004).However,the analytical methods
基金supported by the Natural Science Foundation of Shandong Provence(Grant No.ZR2023MD058)National Natural Science Foundation of China(Grant Nos.42072219,41802201)。
文摘The Yishui complex,located in the western Shandong area of the North China Craton,is representative of the Archean crystalline basement of the North China Craton to explore the early tectonic-thermal evolution history of the Earth.Detailed petrography,mineral chemistry,metamorphic evolution and zircon U-Pb dating are presented for felsic granulite and two-pyroxene granulite from the Yishui complex to contribute to new insights into the Neoarchean tectonic evolution of the North China Craton.Three mineral assemblages are recognized for these granulite samples,including the prograde(M1),peak(M2)and retrograde(M3)mineral assemblages.Conventional geothermobarometry and phase equilibrium modeling yield P-T conditions of 6.5-10.9 kbar/718-839℃ for the peak metamorphism,which define a medium-pressure granulite-facies metamorphism occurred at middle to lower crust.Anticlockwise P-T paths with near-isobaric cooling(IBC)retrograde segments were reconstructed.Zircon LA-ICP-MS U-Pb dating suggests that the protolith of the felsic granulite was emplaced at 2541±7 Ma and the subsequent medium-pressure granulite-facies metamorphism occurred at 2518-2494 Ma.A two-stage mantle plume related crustal-scale sagduction geodynamic regime is proposed in the western Shandong terrane in the Neoarchean.
基金the Geological Science and technology foundation of Shandong Provincial Bureau of Geology and Mineral Resources (Grant No. 20080037)
文摘Integrated gravitational, electrical-magnetic surveys and data processing carried out in the Sanshandao-Jiaojia area, Eastern Shandong Province, northeast China, aim to illuminate the geological characteristics of this shallow-covered area and delineate deep-seated gold prospecting targets. In this region, altogether 12 faults exert critical control on distribution of three types of Early Precambrian metamorphic rock series, i.e. those in the metamorphic rock area, in the granitic rock area underlying the metamorphic rock, and in the remnant metamorphic rock area in granites, respectively. Additionally, the faults have major effects on distribution of four Mesozoic Linglong rock bodies of granite, i.e. the Cangshang, Liangguo, Zhuqiao-Miaojia and Jincheng granites. The Sanshandao and Jiaojia Faults are two well-known regional ore-controlling faults; they have opposite dip direction, and intersect at a depth of 4500 m. Fracture alteration zones have striking geophysical differences relative to the surrounding county rocks. The two faults extend down along dip direction in a gentle wave form, and appear at some steps with different dips. These steps comprise favorable gold prospecting areas, consistent with a step metallogenic model. Six deep-seated gold-prospecting targets are delineated, i.e. Jincheng-Qianchenjia, Xiaoxizhuang-Zhaoxian, Xiyou-Wujiazhuangzi, Xiangyangling-Xinlicun, Panjiawuzi and Miaojia-Pinglidian.
基金financially supported by the research special fund of public service sector from the Ministry of Land and Resources (No. 201111008)
文摘This paper discusses the enrichment and depletion regularities for porphyry coppermolybdenum ore deposits in different regions and varied deposit genetic types in the same area, taking three porphyry copper-molybdenum ore deposits （i.e., the Chengmenshan in Jiangxi, Wunugetushan in Inner Mongolia, Baishantang in Gansu） and two copper deposits in Gansu Province （the Huitongshan skarn deposit and Gongpoquan composite deposit） as case studies. The results show that porphyry Cu-Mo deposits or skarn copper deposits include both enrichment of the ore-forming elements and associated elements, and depletion of some lithophile dispersed elements, rare earth elements （REE） and some major elements. And the depleted elements vary with deposits, having generality and their own features. On a deposit scale, the positive anomalies of enriched elements and negative anomalies of depleted elements follow in a sequence to comprise regular anomaly models of spatial structures. The exploration in the Tongchang deposit in Jiangxi and Huitongshan deposit in Gansu suggests that anomaly models play a key role in the identification of mineral occurrences and deposits compared to one single enriched element anomaly. And the anomaly models exert a critical effect on the optimization of prospecting targets and their potential evaluation.
基金supported by National High-Tech R&D Program of China (Grant 2014AA06A612)the project of the China Geological Survey (Grants 1212011220263,1212010914049 and 1212011121273)
文摘The Panxi region is located in the frontal zone of positive squeezing subduction and side squeezing shearing between the Indian plate and the Eurasian plate. The long-period magnetotelluric （LMT） and broadband magnetotelluric （MT） techniques are both used to study the deep electrical conductivity structure in this region; magnetic and gravity surveys are also performed along the profile. According to the 2-D resistivity model along the Yanyuan-Yongshan profile, a high- conductivity layer （HCL） exists widely in the crust, and a high-resistivity block （HRB） exists widely in the upper mantle in general, as seen by the fact that a large HCL exists from the western Jinpingshan tectonic zone to the eastern Mabian tectonic zone in the crust, while the HRB found in the Panxi tectonic zone is of abnormally high resistivity in that background compared to both sides of Panxi tectonic zone. In addition, the gravity and magnetic field anomalies are of high value. Combined with geological data, the results indicate that there probably exists basic or ultrabasic rock with a large thickness in the lithosphere in the Panxi axial region, which indicates that fracture activity once occurred in the lithosphere. As a result, we can infer that the high-resistivity zone in the Panxi lithosphere is the eruption channel for Permian Emeishan basalt and the accumulation channel for basic and ultrabasic rock. The seismic sources along the profile are counted according to seismic record data. The results indicate that the most violent earthquake sources are located at the binding site of the HRB and the HCL, where the tectonic activity zone is generally acknowledged to be; however, the earthquakes occurring in the HCL are not so violent, which reflects the fact that the HCL is a plastic layer, and the fracture threshold of a plastic layer is low generally, making high stress difficult to accumulate but easy to release in the layer. As a result, a higher number of smaller earthquakes occurred in the HCL at Daliangshan tectonic zone, and violent earthquakes occurred at the binding site of high- and low-resistivity blocks at the Panxi tectonic zone.
基金Supported by China Ministry of Science and Technology (2000DEB20081)China Ocean Mineral Resources R&D Association (COMRA) (No.DY105-05-01-05)+1 种基金China Ministry of Education(No.205089)China National Natural Science Foundation (No.40076015)
文摘A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）.
基金financially supported by the projects of the China Geological Survey(DD20190518,DD20190527)。
文摘To illuminate the migration and transformation of selenium(Se)in the igneous rock-soil-rice system,285 pairs of rhizosphere soil and rice samples were collected from the granitoid and basalt areas in Hainan Province,South China.The contents of Se in soils derived from granitoid and basalt are,respectively,0.19±0.12 mg/kg and 0.34±0.39 mg/kg,which are much higher than Se contents in granitoid and basalt.Selenium shows remarkable enrichment from granitoid and basalt to soils.The mobile fraction of Se in soils derived from granitoid is 0.0100±0.0034 mg/kg,which is significantly higher than that of basalt(0.0058±0.0039 mg/kg).Although soil derived from basalt shows higher Se contents,Se contents in rice samples,mobile fractions of Se in soils,and biological concentration factor(BCF)is similar or even lower than that from granitoid.Basalt consist of calcic plagioclase and pyroxene,and are much richer in Fe,Al,and Ca than granitoid.Correspondingly,the basalt-derived soils have higher goethite,hematite,kaolinite,cation exchange capacity(CEC)content,and higher p H than the granitoid-derived soils,which result in higher adsorption capacity for Se and relatively lower Se bioavailability.Soils derived from granitoid and basalt in tropical regions are beneficial to produce Se-rich rice.
基金sponsored by a project of the Special Society Commonwealth research funds of the Ministry of Science and Technology,P.R.China(No.2001DIB10076)
文摘Actual granitoid analytical data of 767 composited samples are presented here. The data source is 6080 samples collected mainly from 750 large- to middle-sized granitoid bodies across China. Data from the composited samples, which includes that of 70 elements, is analyzed according to geological age - Archeozoic （Ar）, Proterozoic （Pt）, Eopaleozoic （PZl）, Neopaleozoic （Pz2）, Mesozoic （Mz）, and Cenozoic （Cz） - and three major compositional varieties, e.g. alkali-feldspar granite, syenogranite and adamellite. Petrochemical parameters, trace-element content and rare-earth element （REE） distribu- tions of the different rock types and geological ages are characterized, and change tendencies through Archean to Cenozoic time are recorded. The comprehensive analytical data presented here has not been previously published. This significant data set can be used as fundamental information in studies of basic China geology, magma petrogenesis, ore exploration and geochemistry.
文摘Gas hydrate, mainly composed of hydrocarbon gas and water, is considered to be a clean energy in the 21st century. Many indicators such as BSRs （Bottom-Simulating Reflections）, which are thought to be related to gas hydrate, are found in the South China Sea （SCS） in recent years. The northeastern part of the SCS is taken as one of the most potentials in the area by many scientists. It is situated in the conjunction of the northern divergent continental margin and the eastern convergent island margin, whose geological settings are much preferable for gas hydrate to occur. Through this study, brightness temperature anomalies recorded by satellite-based thermal infrared remotely sensed images before or within the imminent earthquake, the high content of hydrocarbon gas acid-degassed from subsurface sediment and the high radioactive thermoluminescence value of subsurface sediment were found in the region. Sometimes brightness temperature anomalies alone exist in the surrounding of the Dongsha Islands. The highest content of hydrocarbon gas amounts to 393 μL methane per kilogram sediment and the highest radioactive thermoluminescence value is 31752 unit; their geometric averages are 60.5 μL/kg and 2688.9 unit respectively. What is more inspiring is that there are three sites where the methane contents are up to 243, 268 and 359μL/kg and their radioactive thermoluminescence values are 8430, 9537 and 20826 unit respectively. These three locations are just in the vicinity of one of the highest confident BSRs identified by predecessors. Meanwhile, the anomalies are generally coincident with other results such as headspace gas anomaly in the sediment and chloride anomaly in the interstitial water in the site 1146 of Leg 184. The above-mentioned anomalies are most possibly to indicate the occurrence of gas hydrate in the northeastern SCS.
