By dynamical simulations, we show a transforming process between neutral soliton （spin carrier） and charged soliton （charge carrier） in polymers via photo-excitation, taking a polaron as the transitional bridge. I...By dynamical simulations, we show a transforming process between neutral soliton （spin carrier） and charged soliton （charge carrier） in polymers via photo-excitation, taking a polaron as the transitional bridge. It is photoinduced transformation between spin carrier and charge carrier. In this way, we demonstrate an access for polymers to be applied to spintronics.展开更多
A model to describe the main features of conjugated polymers with ring structures, such as polythiophene and polypyrrole, is constructed. It is shown that the origin of the symmetry breaking and confinement of a solit...A model to describe the main features of conjugated polymers with ring structures, such as polythiophene and polypyrrole, is constructed. It is shown that the origin of the symmetry breaking and confinement of a soliton and anti-soliton pair is branch hopping in the polymer rings.展开更多
We investigate the bipolaron channel B＋＋ ＋ B-- → BX. The dynamical evolutions and transition probabilities of this bipolaron luminescence channel are studied. It is found that this channel avoids the triplet and i...We investigate the bipolaron channel B＋＋ ＋ B-- → BX. The dynamical evolutions and transition probabilities of this bipolaron luminescence channel are studied. It is found that this channel avoids the triplet and is able to enhance the efficiency. We suggest that choosing certain polymers and injection structures, in which B is easily formed, can improve the luminescence efficiency. It is believed that these results will motivate further experimental studies about the function of bipolarons in electroluminescence.展开更多
基金Supported by the National Natural Science Foundation of China under Grant 90403110, and the Doctoral Foundation of the Ministry of Education of China.
文摘By dynamical simulations, we show a transforming process between neutral soliton （spin carrier） and charged soliton （charge carrier） in polymers via photo-excitation, taking a polaron as the transitional bridge. It is photoinduced transformation between spin carrier and charge carrier. In this way, we demonstrate an access for polymers to be applied to spintronics.
基金The project supported by National Natural Science Foundation of China under Grant Nos. 20674010 and 90403110, the Doctoral Foundation of the Education Ministry of China, and the U,S, Army Research 0ffice under Contract W911NF-04-1-0383
文摘A model to describe the main features of conjugated polymers with ring structures, such as polythiophene and polypyrrole, is constructed. It is shown that the origin of the symmetry breaking and confinement of a soliton and anti-soliton pair is branch hopping in the polymer rings.
基金Supported by the National Natural Science Foundation of China under Grant Nos 20674010 and 20804039, the Doctoral Foundation Program of the Ministry of Education of China, and the Zhejiang Provincial Natural Science Foundation under Grant No Y4080300.
文摘We investigate the bipolaron channel B＋＋ ＋ B-- → BX. The dynamical evolutions and transition probabilities of this bipolaron luminescence channel are studied. It is found that this channel avoids the triplet and is able to enhance the efficiency. We suggest that choosing certain polymers and injection structures, in which B is easily formed, can improve the luminescence efficiency. It is believed that these results will motivate further experimental studies about the function of bipolarons in electroluminescence.
