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A New Method for Determining Fluid Compositions in the H_2O-NaClCaCl_2 System with Cryogenic Raman Spectroscopy 被引量:8
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作者 CHI Guoxiang CHU Haixia +1 位作者 Ryan SCOTT CHOU I-Ming 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第4期1169-1182,共14页
Raman peaks of various hydrates in the H20-NaCl-CaCl2 system have been previously identified, but a quantitative relationship between the Raman peaks and XNaCl (i.e.,NaCl/ (NaCl+CaCl2)) has not been established, ... Raman peaks of various hydrates in the H20-NaCl-CaCl2 system have been previously identified, but a quantitative relationship between the Raman peaks and XNaCl (i.e.,NaCl/ (NaCl+CaCl2)) has not been established, mainly due to the difficulty to freeze the solutions. This problem was solved by adding alumina powder to the solutions to facilitate nucleation of crystals. Cryogenic (-185℃) Raman spectroscopic studies of alumina-spiced solutions indicate that XNaCl is linearly correlated with the total peak area fraction of hydrohalite. Capsules of solutions made from silica capillary were prepared to simulate fluid inclusions. Most of these artificial fluid inclusions could not be totally frozen even at temperatures as low as -185℃, and the total peak area fraction of hydrohalite is not correlated linearly with XNaCI. However, the degree of deviation (△XNaCl) from the linear correlation established earlier is related to the amount of residual solution, which is reflected by the ratio (r) of the baseline "bump" area, resulting from the interstitial unfrozen brine near 3435 cm^-1, and the total hydrate peak area between 3350 and 3600 cm^-1. A linear correlation between △XNaCl and r is established to estimate XNaCl from cryogenic Raman spectroscopic analysis for fluid inclusions. 展开更多
关键词 CRYOGENIC RAMAN H20-NaCl-CaCl2 XNaCI fluid inclusion
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Intercomparison of GPS radiosonde soundings during the eastern tropical Indian Ocean experiment 被引量:5
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作者 XIE Qiang HUANG Ke +5 位作者 WANG Dongxiao YANG Lei CHEN Ju WU Zewen LI Daning LIANG Zhiyan 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2014年第1期127-134,共8页
Temperature and relative humidity profiles derived from two China-made global positioning system(GPS) radiosondes(GPS-TK and CF-06-A) during the east tropical Indian Ocean(ETIO) experiment were compared with Vai... Temperature and relative humidity profiles derived from two China-made global positioning system(GPS) radiosondes(GPS-TK and CF-06-A) during the east tropical Indian Ocean(ETIO) experiment were compared with Vaisala RS92-SGP to assess the performances of China-made radiosondes over the tropical ocean.The results show that there have relative large biases in temperature observations between the GPSTK and the RS92-SGP in the low troposphere,with a warm bias of greater than 2 K in the day and a cooling bias of 0.6 K at night.The temperature differences of the CF-06-A were small in the troposphere both in daytime and nighttime,and became large peak-to-peak fluctuations in the stratosphere.The intercomparison of the relative humidity showed that the CF-06-A had large random errors due to the limitation of sensors and the lack of correction scheme,and the GPS-TK had large systematic biases in the low troposphere which might be related to the temperature impact.GPS height measurements are clearly suitable for China-made radiosonde systems operation.At night,the CF-06-A and the GPS-TK could provide virtual potential temperature and atmospheric boundary layer height measurements of suitable quality for both weather and climate research.As a result of the intercomparison experiment,major errors in the Chinamade radiosonde systems were well indentified and subsequently rectified to ensure improving accuracy for historical and future radiosondes. 展开更多
关键词 global positioning system radiosonde temperature and relative humidity profile systematic bias random error tropical ocean
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Mass transport deposits and processes in the north slope of the Xisha Trough,northern South China Sea 被引量:4
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作者 QIN Zhiliang WU Shiguo +4 位作者 WANG Dawei LI Wei GONG Shaojun MI Lijun SPENCE George 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2015年第9期117-125,共9页
Triple mass-transport deposits (MTDs) with areas of 625, 494 and 902 km^2, respectively, have been identified on the north slope of the Xisha Trough, northern South China Sea margin. Based on high-resolution seismic... Triple mass-transport deposits (MTDs) with areas of 625, 494 and 902 km^2, respectively, have been identified on the north slope of the Xisha Trough, northern South China Sea margin. Based on high-resolution seismic reflection data and multi-beam bathymetric data, the Quaternary MTDs are characterized by typical geometric shapes and internal structures. Results of slope analysis showed that they are developed in a steep slope ranging from 5° to 35°. The head wall scarps of the MTDs arrived to 50 km in length (from headwall to termination). Their inner structures include well developed basal shear surface, growth faults, stepping lateral scarps, erosion grooves, and frontal thrust deformation. From seismic images, the central deepwater channel system of the Xisha Trough has been filled by interbedded channel-levee deposits and thick MTDs. Therefore, we inferred that the MTDs in the deepwater channel system could be dominated by far-travelled slope failure deposits even though there are local collapses of the trough walls. And then, we drew the two-dimensional process model and three- dimensional structure model diagram af the MTDs. Combined with the regional geological setting and previous studies, we discussed the trigger mechanisms of the triple MTDs. 展开更多
关键词 South China Sea mass transport deposits submarine slides gravity flow deepwater channel system
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Freshening of the intermediate water of the South China Sea between the 1960s and the 1980s 被引量:4
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作者 刘长建 王东晓 +2 位作者 陈举 杜岩 谢强 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2012年第6期1010-1015,共6页
Variation in intermediate water salinity in the South China Sea (SCS) between the 1960s and 1980s was studied using historical hydrographic data. The results demonstrate that the water was significantly fresher in the... Variation in intermediate water salinity in the South China Sea (SCS) between the 1960s and 1980s was studied using historical hydrographic data. The results demonstrate that the water was significantly fresher in the 1980s than in the 1960s, indicating that vertical mixing at intermediate water depth was reduced in the 1980s. This was partially because of the change of the SCS meridional overturning circulation (MOC) connecting local intermediate water with deep water. Data assimilation showed a 0.5Sv (1 Sv=10 6m 3/s) reduction in the strength of the MOC, which is about one third of the mean SCS MOC. Because the SCS MOC is linked to the Pacific Ocean, such an interdecadal variation in the intermediate water SCS may reflect anthropogenic climate change in the world ocean. 展开更多
关键词 decadal variability intermediate water meridional overturning circulation South China Sea (SCS)
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Relationship Between Upper-Ocean Heat Content in the Tropical Indian Ocean and Summer Precipitation in China 被引量:5
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作者 HUANG Ke ZHANG Qi-Long +1 位作者 XIE Qiang WANG Dong-Xiao 《Atmospheric and Oceanic Science Letters》 2012年第4期306-313,共8页
An analysis of the Ishii ocean heat content(OHC) in the tropical Indian Ocean from the surface to 700-m depth shows that the OHC changes dramatically on the interannual timescale in the Indian Ocean.The first mode of ... An analysis of the Ishii ocean heat content(OHC) in the tropical Indian Ocean from the surface to 700-m depth shows that the OHC changes dramatically on the interannual timescale in the Indian Ocean.The first mode of empirical orthogonal function(EOF1) of the OHC shows that there is a strong air-sea interaction pattern in the Indian Ocean with a positive(negative) loading in the east and a negative(positive) loading in the west.This seesaw oscillation pattern influences the summer precipitation in China with a North-South reversed distribution.Composite analysis shows that during a positive(negative) OHC episode,an anomalous cyclonic(anticyclonic) circulation over the western Pacific and South China weakens(enhances) the monsoonal northward flow in the lower troposphere;meanwhile,anomalous meridional circulation connects the descending(ascending) branch over the Southeast Indian Ocean and the ascending(descending) branch in South China as well as a descending(ascending) branch over North China.Analysis of the mechanism behind these features suggests that(1) the accumulation of OHC-induced vorticity is related to the wave activity over the mid-latitudes and that(2) the meridional teleconnection induced by the Indo-Pacific air-OHC interaction appears over East Asia and the western Pacific.Both of these patterns can cause summer precipitation anomalies in China. 展开更多
关键词 oceanic heat content summer precipitation interannual variability tropical Indian Ocean
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A dipole wind curl pattern induced by Taiwan Island and its effect on upper stratification in the northeastern South China Sea 被引量:2
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作者 邓奕 施平 +4 位作者 周文 杜岩 谢强 庄伟 王东晓 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2012年第6期944-952,共9页
Using hydrographic data sampled during four successive late summer-early autumn cruises in 2004-2007, vertical stratification along transects in the lee of Taiwan Island was analyzed to investigate upper ocean respons... Using hydrographic data sampled during four successive late summer-early autumn cruises in 2004-2007, vertical stratification along transects in the lee of Taiwan Island was analyzed to investigate upper ocean responses to orographically induced dipole wind stress curl (WSC). Results indicate that mixed-layer depth (MLD) and its relationship with thermocline depth varied under different local wind forcings. Average MLD along the transects from the 2004 to 2007 cruises were 18.5,30.7,39.2 and 24.5m, respectively. The MLD along the transects deepened remarkably and resulted in thermocline ventilation in 2005 and 2006, whereas ventilation did not occur in 2004 and 2007. Estimates indicate that frictional wind speed was the major factor in MLD variations. To a large degree, the combined effects of frictional wind speed and Ekman pumping are responsible for the spatial pattern of MLD during the cruises. 展开更多
关键词 Taiwan Island dipole wind stress curl mixed layer depth THERMOCLINE
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The South China Sea throughflow: linkage with local monsoon system and impact on upper thermal structure of the ocean 被引量:2
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作者 刘钦燕 王东晓 谢强 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2012年第6期1001-1009,共9页
The tendency of South China Sea throughflow (SCSTF) variation associated with the local monsoon system, and its impact on upper-layer thermal structure, are studied using the Simple Ocean Data Assimilation (SODA) data... The tendency of South China Sea throughflow (SCSTF) variation associated with the local monsoon system, and its impact on upper-layer thermal structure, are studied using the Simple Ocean Data Assimilation (SODA) dataset, combined with Ishii reanalysis data. Luzon Strait Transport (LST) is measured and used as an index for studying the SCSTF variation. Results show that LST had an increasing tendency over the last 50 years, mainly in summer and fall. The increasing tendency was 0.017 1 Sv/a in summer and 0.027 4 Sv/a in fall, as estimated by SODA, and 0.018 0Sv/a in summer and 0.018 9 Sv/a in fall, as estimated by "Island Rule" theory. LST increased by 0.53Sv in JJA (June-July-August) and 0.98Sv in SON (September-October-November) after climate shift, as inferred by SODA data. The average LST anomaly in JJA and SON is strongly related to the local monsoon system, especially to variability of the meridional wind stress anomaly after application of a 3-year running mean, with correlation coefficients 0.57 and 0.51, respectively. In addition to the basin-scale wind forcing, the local northeasterly wind stress anomaly in the SCS can push Pacific water entering the SCS more readily in JJA and SON after climate shift, and an SCSTF-associated cooling effect may favor subsurface cooling more frequently after climate shift. 展开更多
关键词 South China Sea throughflow (SCSTF) local monsoon system subsurface temperature cooling
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The upper-ocean response to typhoons as measured at a moored acoustic Doppler current profiler 被引量:1
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作者 刘泽 侯一筠 +2 位作者 谢强 胡珀 刘亚豪 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2015年第5期1256-1264,共9页
A moored acoustic Doppler current profiler(ADCP) data,satellite-derived sea surface wind data,and the chlorophyll-a concentration were used to examine the influence of typhoon events on the upper ocean in the central ... A moored acoustic Doppler current profiler(ADCP) data,satellite-derived sea surface wind data,and the chlorophyll-a concentration were used to examine the influence of typhoon events on the upper ocean in the central Luzon Strait. The data were collected between August 27 and October 6,2011. Large changes in ocean dynamics and marine life were recorded in the upper layers over the short term during the transit of each of the three violent typhoons that passed over the region during the study period. The geostrophic flow during the period of ADCP monitoring was comparable to the Ekman flow,recently shown to be prominent in the upper layer. Based on the influence of the three typhoon events that swept the Luzon Strait or traversed Luzon Island on their way to the South China Sea,we postulated a typhoon-induced upwelling around the ADCP and found that upward isothermal displacements reached 11.8–39.0 m,which was confirmed by the sea-level anomaly data recorded at the same time. This variability in the upper ocean may play an important role in biological activity,especially in offshore deep-sea regions. 展开更多
关键词 TYPHOONS moored ADCP data satellite-derived data Luzon Strait
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A Remotely Operated Serial Sampler for Collecting Gas-Tight Fluid Samples 被引量:1
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作者 吴世军 杨灿军 +1 位作者 丁抗 谭春阳 《China Ocean Engineering》 SCIE EI CSCD 2015年第5期783-792,共10页
This paper describes the design, construction and preliminary test results for a gas-tight serial sampler intended to be deployed at seafloor for long-term operation to take time-series fluid samples from deep-sea env... This paper describes the design, construction and preliminary test results for a gas-tight serial sampler intended to be deployed at seafloor for long-term operation to take time-series fluid samples from deep-sea environments such as cold seeps, water column and hydrothermal vents. The serial sampler is a modular system that is based on independent and identical sampling modules, which are designed to collect six 160 ml gas-tight fluid samples maintained at high pressure to a depth of 4000 meters. With two working modes, the sampler can be deployed either with seafloor cabled observatory for remote control or as a stand-alone device for autonomous operation. A prototype of the instrument has been constructed and tested on the MARS cabled observatory for two months. The laboratory and field tests proved the success of the design and construction of the serial sampler, and indicated the potential for future ocean sciences. 展开更多
关键词 serial sampler gas tight seafloor cabled observatory
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Eddy formation and surface flow field in the Luzon Strait area during the summer of 2009
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作者 刘泽 侯一筠 谢强 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2015年第5期1320-1333,共14页
The formation of mesoscale eddies and the structure of the surface flow field in the Luzon Strait area were examined using in-situ CTD data, Argo float data, and multi-satellite remote sensing data collected from May ... The formation of mesoscale eddies and the structure of the surface flow field in the Luzon Strait area were examined using in-situ CTD data, Argo float data, and multi-satellite remote sensing data collected from May to August 2009. The results show that vigorous water exchange between Kuroshio water and South China Sea (SCS) water began to emerge over the 200 m water column throughout the strait. Based on an objective definition of surface currents, float A69 tracked an anti-cyclonic eddy southwest of Taiwan Island under a Lagrangian current measurement. The salinity inside the anti-cyclonic eddy was higher than in typical SCS water but lower than in Kuroshio mainstream water, indicating that this eddy was induced by Kuroshio frontal intrusion through the Luzun Strait and into the SCS. From hydrographic data, we propose that continuous horizontal diffusion with high-salinity characteristics in the subsurface layer could extend to 119°E or even further west. The high-temperature filament, large positive sea level anomaly and clockwise geostrophic current all confirmed the existence of this warm eddy in May and June. A strongly negative wind stress curl maintained the eddy until it died. The surface flow field during July and August was rather complicated. Float A83 described an east-west orientated shuttle run in the 20°N section that was not reported by previous studies. At the same time, float A80 indicated a Kuroshio bend into the north-central region of Luzon Strait but it did not cross 120.5°E. The water mass rejoining the Kuroshio mainstream from the southern tip of Taiwan Island was less saline, indicating an entrainment of water from SCS by the Kuroshio bend. 展开更多
关键词 mesoscale eddy surface flow field hydrographic data Argo trajectory Argo profile Luzon Strait
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Redox Control and Measurements in Hydrothermal Experiments
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作者 CHOU I-Ming 《矿物学报》 CAS CSCD 北大核心 2013年第S2期561-561,共1页
For minerals containing multivalent elements,their stabilities depend not only on pressure(P),temperature(T),and bulk chemical composition,but also the redox state.This applies to many ore forming minerals,such that t... For minerals containing multivalent elements,their stabilities depend not only on pressure(P),temperature(T),and bulk chemical composition,but also the redox state.This applies to many ore forming minerals,such that the redox state and its fluctuations in hydrothermal systems have long been considered as important controlling factors for the transport and deposition of ores. 展开更多
关键词 redox MINERALS HYDROTHERMAL KINETICS sealed PERMEATION DISSOCIATION mentioned CAPSULE adding
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Characteristics of the Bohai Sea oil spill and its impact on the Bohai Sea ecosystem 被引量:11
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作者 GUO Jie LIU Xin XIE Qiang 《Chinese Science Bulletin》 SCIE EI CAS 2013年第19期2276-2281,共6页
In this paper, ENVISAT ASAR data and the Estuary, Coastal and Ocean Model was used to analyze and compare characteristics of the Bohai Sea oil spill. The oil slicks have spread from the point of the oil spill to the e... In this paper, ENVISAT ASAR data and the Estuary, Coastal and Ocean Model was used to analyze and compare characteristics of the Bohai Sea oil spill. The oil slicks have spread from the point of the oil spill to the east and north-western Bohai Sea. We make a comparison between the changes caused by the oil spill on the chlorophyll concentration and the sea surface temperature using MODIS data, which can be used to analyze the effect of the oil spill on the Bohai Sea ecosystem. We found that the Bohai Sea oil spill caused abnormal chlorophyll concentration distributions and red tide nearby area of oil spill. 展开更多
关键词 漏油事件 生态系统 渤海 ENVISAT MODIS数据 叶绿素浓度 海洋表面温度 SAR数据
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Progress of regional oceanography study associated with western boundary current in the South China Sea 被引量:11
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作者 WANG DongXiao LIU QinYan +7 位作者 XIE Qiang HE ZhiGang ZHUANG Wei SHU YeQiang XIAO XianJun HONG Bo WU XiangYu SUI DanDan 《Chinese Science Bulletin》 SCIE EI CAS 2013年第11期1205-1215,共11页
Recent progress of physical oceanography in the South China Sea (SCS) associated with the western boundary current (WBC) and eddies is reviewed in this paper. It includes Argo observations of the WBC, eddy detection i... Recent progress of physical oceanography in the South China Sea (SCS) associated with the western boundary current (WBC) and eddies is reviewed in this paper. It includes Argo observations of the WBC, eddy detection in the WBC based on satellite images, cross-continental shelf exchange in the WBC, eddy-current interaction, interannual variability of the WBC, air-sea interaction, the SCS throughflow (SCSTF), among others. The WBC in the SCS is strong, and its structure, variability and dynamic processes on seasonal and interannual time scales are yet to be fully understood. In this paper, we summarize progresses on the variability of the WBC, eddy-current interaction, air-sea interaction, and the SCSTF achieved in the past few years. Firstly, using the drifting buoy observations, we point out that the WBC becomes stronger and narrower after it reaches the central Vietnam coast. The possible mechanisms influencing the ocean circulation in the northern SCS are discussed, and the dynamic mechanisms that induce the countercurrent in the region of northern branch of WBC in winter are also studied quantitatively using momentum balance. The geostropic component of the WBC was diagnosed using the ship observation along 18°N, and we found that the WBC changed significantly on interannual time scale. Secondly, using the ship observations, two anti-cyclonic eddies in the winter of 2003/2004 in the northern SCS, and three anti-cyclonic eddies in the summer of 2007 along 18°N were studied. The results show that the two anti-cyclonic eddies can propagate southwestward along the continental shelf at the speed of first Rossby wave (~0.1 ms-1 ) in winter, and the interaction between the three anti-cyclonic eddies in summer and the WBC in the SCS is preliminarily revealed. Eddies on the continental shelf of northern SCS propagated southeastward with a maximum speed of 0.09 ms-1 , and those to the east of Vietnam coast had the largest kinetic energy, both of which imply strong interaction between eddy activity and WBC in the SCS. Thirdly, strong intraseasonal variability (ISV) of sea surface temperature (SST) near the WBC regions was found, and the ISV signal of SST in winter weakens the ISV signal of latent heat flux by 20%. Fourthly, the long-term change of SCSTF volume transport and its connection with the ocean circulation in the Pacific were discussed. 展开更多
关键词 南海区域 物理海洋学 西边界流 中国南海 南海北部大陆架 海气相互作用 年际时间尺度 ROSSBY波
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Hydrographic field investigations in the Northern South China Sea by open cruises during 2004-2013 被引量:11
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作者 Lili Zeng Qiang Wang +8 位作者 Qiang Xie Ping Shi Lei Yang Yeqiang Shu Ju Chen Dandan Sui Yunkai He Rongyu Chen Dongxiao Wang 《Science Bulletin》 SCIE EI CAS CSCD 2015年第6期607-615,M0003,共10页
In the past 10 years (2004-2013), annual open cruise during late summer provided new opportunities for comprehensive studies in the Northern South China Sea (NSCS). The 10-year field investigation program was carr... In the past 10 years (2004-2013), annual open cruise during late summer provided new opportunities for comprehensive studies in the Northern South China Sea (NSCS). The 10-year field investigation program was carried out by the South China Sea Institute of Oceanology, Chinese Academy of Sciences (SCSIO, CAS). Measurements inclu- ded water mass property, ocean circulation, atmospheric structure, and chemical and biological elements. The observation data collected during these open cruises have been intensively used in the studies of marine oceanographic, meteorological, chemical, and biological processes in the NSCS. In this study, comprehensive assessment of data application in oceanographic and meteorological studies is provided: (1) the property and variability of water masses in different layers; (2) the distribution of main currents and three-dimensional structure of mesoscale eddies; and (3) atmospheric structure and its feedback to the ocean. With the continuance of open cruises, it is feasible to construct high- quality, gridded climatological marine meteorological datasets in the NSCS in the near future. 展开更多
关键词 Northern South China Sea Dataapplication Water mass property Ocean circulation Atmospheric structure
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Saturation evaluation for fine-grained sediments
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作者 Linqi Zhu Shiguo Wu +1 位作者 Xueqing Zhou Jianchao Cai 《Geoscience Frontiers》 SCIE CAS CSCD 2023年第4期57-71,共15页
Accurate quantification of the gas hydrate content in the deep sea is useful for assessing the resource potential and understanding the role of gas hydrates in the global carbon cycle.Resistivity logging data combined... Accurate quantification of the gas hydrate content in the deep sea is useful for assessing the resource potential and understanding the role of gas hydrates in the global carbon cycle.Resistivity logging data combined with Archie’s equation are often used to calculate gas hydrate saturation,but the reliability is dependent on the rationality of the empirical parameter cementation factor and saturation index.At present,an increasing number of fine-grained hydrate-rich sediment regions have been discovered worldwide through drilling efforts,and the reservoir types and hydrate distribution are diverse,which differs greatly from that of coarse-grained reservoirs of hydrate-bearing sediment.This results in vertical variations in m and n through stratigraphy.At present,the saturation evaluation effect of these reservoirs cannot be improved.In this work,a theory for the determination of the cementation factor and saturation index was first proposed to obtain reliable and variable values of the empirical parameters.Then,a hydrate saturation evaluation technique with variables m and n was formed based on the well logging data.This technique was used to evaluate complex fine-grained hydrate-bearing reservoirs in several regions worldwide.It was found that the highest n could be 16,and the log calculation results were more consistent with the core hydrate saturation.Additionally,the cause of the excessively high n values was explained from physical principles,and the result was verified with actually well log data.In future evaluations of the amount of hydrate resources in fine-grained sediment reservoirs worldwide,new saturation estimation methods should be taken into account to advance hydrate research. 展开更多
关键词 HYDRATE FINE-GRAINED Cementation factor Saturation index ARCHIE PETROPHYSICS
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