Mine refuge chambers are used to shield miners who fail to escape from the mine when incidents occur. Environment maintaining system plays a key role in stabilizing thermal environment of a mine refuge chamber against...Mine refuge chambers are used to shield miners who fail to escape from the mine when incidents occur. Environment maintaining system plays a key role in stabilizing thermal environment of a mine refuge chamber against heat emitted from metabolism and transferred from outside. The safety and comfort of refugees are closely related to the environment maintaining system design. In order to improve the comfort of refugees, optimization on the environment maintaining system has been done based on the previous work. To evaluate the environment of the chamber, eight volunteers were involved into the experiment. Under close observation and safety protection, they lived in a heat-isolated test chamber for 106 hours. The volunteers were asked to maintain low level of activities to simulate refugees' situation. It shows that the environment maintaining system worked well and the temperature, relative humidity and emitted harmful air content such as CO2 and CO were all kept in the safety level, and no discomfort was felt by volunteers at all.展开更多
Multiwall carbon nanotube-supported Pt (Pt/MWNTs) catalysts with high dispersion and high loading of Pt were prepared by chemical reduction method and the loading of Pt got to 40 wt%. The average diameter of Pt nano...Multiwall carbon nanotube-supported Pt (Pt/MWNTs) catalysts with high dispersion and high loading of Pt were prepared by chemical reduction method and the loading of Pt got to 40 wt%. The average diameter of Pt nanoparticles on MWNTs was about 3.5 nm. When the hydrogen and air were used as reactant gases for PEMFC, Pt/MWNTs catalysts showed significantly higher performance than the Pt/XC-72 (carbon black) catalysts.展开更多
Mn-based zinc ion battery has the advantages of low cost and high performance,which makes it the promising energy storage system.However,the poor conductivity and the agglomeration in the synthesis process of manganes...Mn-based zinc ion battery has the advantages of low cost and high performance,which makes it the promising energy storage system.However,the poor conductivity and the agglomeration in the synthesis process of manganese-based materials restrict the performance of batteries.Herein,the Se-doped MnS/Ti_(3)C_(2)T_(x)(Se-MnS/Ti_(3)C_(2)T_(x))composite material derived from Mn-based metal-organic framework is reported.Electrochemical tests show that Se-doped could generate S defects and enhance the electrochemical activity of MnS.At the same time,the introduction of Ti_(3)C_(2)T_(x) substrate is conducive to exposing more sulfur defects and improving the utilization rate of defects.In the mechanism study,it is found that Se-MnS/Ti_(3)C_(2)T_(x) is transformed into S/Se co-doped Mn3O_(4) at the first charge,which innovatively elucidated the behavior of S/Se during activation.In the electrochemical performance test,the specific capacity can reach 74.7 mAh·g^(-1) at 5.0 A·g^(-1).In addition,the Zn-Ti_(3)C_(2)T_(x) membrane electrode is prepared by vacuum filtration as the zinc-poor anode,which is assembled into the rocking chair full battery to avoid dendrite growth and exhibit excellent rate performance.The addition of Zn2+weakens the electrostatic repulsion between the interlayers of MXene,and the formation of the folded morphology aids the penetration of the electrolyte.At 1.0 A·g^(-1),the capacity can reach 50.6 mAh·g^(-1).This work is helpful to promote the research and development of the reaction mechanism of manganese based rocking chair batteries.展开更多
Dy^3+-doped glass-ceramics containing NaCaPO4 crystals were successfully fabricated by heat treatment at base glass,and the luminescence properties were investigated for potential applications in radiation measurement...Dy^3+-doped glass-ceramics containing NaCaPO4 crystals were successfully fabricated by heat treatment at base glass,and the luminescence properties were investigated for potential applications in radiation measurements.The photo luminescence(PL)excitation and emission spectra exhibit transitions related to Dy^3+ions corresponding to the strongest excitation and emission wavelengths at 351 and 575 nm,respectively.The CW-OSL properties as a function of dopant concentration,pre-heating temperature,pre-heating time and signal fading were investigated.The most appropriate Dy^3+ion concentration was found to be 0.25 mol%.The TL glow curves have a broad peak feature peaking at 195±5℃.The fading of the OSL signal would keep stable in five days with the intensity value of about 76.11%.The samples also exhibit good signal reusability and a broad linear dose response range(0.02-1000 Gy).展开更多
A novel random walk coefficient(RWC) model of the interferometric fiber optic gyroscope(IFOG) to decompose fundamental noise sources, namely the shot noise, the excess noise, the thermal noise, and the detection circu...A novel random walk coefficient(RWC) model of the interferometric fiber optic gyroscope(IFOG) to decompose fundamental noise sources, namely the shot noise, the excess noise, the thermal noise, and the detection circuit noise, from the overall noise was developed. The coefficients of the model were extracted from the measured RWC instead of by calculating the accurate IFOG parameters, which is simpler and more accurate. The correctness and the accuracy of the model were verified by experiments. Using this model, the RWC of the experimental IFOG was predicted and the quantitative contributions of the noise sources were determined. According to the predicted results, the parameters of the IFOG were optimized. Finally, based on the model, a noise decomposition and parameter optimization method was proposed for high sensitivity IFOG design.展开更多
Designing hybrid materials with numerous catalytic active sites,high specific surface area,and interfacial interactions is an effective strategy to improve electrocatalytic performance.In this work,iron-based metal or...Designing hybrid materials with numerous catalytic active sites,high specific surface area,and interfacial interactions is an effective strategy to improve electrocatalytic performance.In this work,iron-based metal organic frameworks(Fe-MOFs)@(Co,Ni)Fe-layered double hydroxide(LDH)is successfully constructed using the similar"MOF growing on LDH"strategy for oxygen evolution reaction and hydrogen evolution reaction in the alkaline electrolyte.The synthesized hybrid materials in this particular way show excellent electrochemical overall water-splitting performance with the cell voltage of 1.62 V at10 mA·cm^(-2) in the alkaline environment due to the optimized adsorption/desorption properties of metal ions on oxygencontaining species and interfacial effects of hybrid materials.Fe-MOFs@(Co,Ni)Fe-LDH also exhibits excellent hydrogen and oxygen production efficiency of 370 and 175μL·min^(-1),respectively.This work draws on an effective approach to the fabrication of MOF@LDH structures and provides new insights into overall water-splitting in alkaline conditions.展开更多
文摘Mine refuge chambers are used to shield miners who fail to escape from the mine when incidents occur. Environment maintaining system plays a key role in stabilizing thermal environment of a mine refuge chamber against heat emitted from metabolism and transferred from outside. The safety and comfort of refugees are closely related to the environment maintaining system design. In order to improve the comfort of refugees, optimization on the environment maintaining system has been done based on the previous work. To evaluate the environment of the chamber, eight volunteers were involved into the experiment. Under close observation and safety protection, they lived in a heat-isolated test chamber for 106 hours. The volunteers were asked to maintain low level of activities to simulate refugees' situation. It shows that the environment maintaining system worked well and the temperature, relative humidity and emitted harmful air content such as CO2 and CO were all kept in the safety level, and no discomfort was felt by volunteers at all.
文摘Multiwall carbon nanotube-supported Pt (Pt/MWNTs) catalysts with high dispersion and high loading of Pt were prepared by chemical reduction method and the loading of Pt got to 40 wt%. The average diameter of Pt nanoparticles on MWNTs was about 3.5 nm. When the hydrogen and air were used as reactant gases for PEMFC, Pt/MWNTs catalysts showed significantly higher performance than the Pt/XC-72 (carbon black) catalysts.
基金supported by the National Natural Science Foundation of China(No.51962032)the program for Strong Youth Technology Leading Talents in Bingtuan Technological Innovation Talents(No.2023CB00811)+2 种基金Youth Innovation Promotion Association CAS(No.2021433)the Youth Innovative Top Talents Fund,Shihezi University(No.CXBJ202203)Youth Science and Technology Innovation Leading Talent Fund,Bashi Shihezi(No.2023RC02).
文摘Mn-based zinc ion battery has the advantages of low cost and high performance,which makes it the promising energy storage system.However,the poor conductivity and the agglomeration in the synthesis process of manganese-based materials restrict the performance of batteries.Herein,the Se-doped MnS/Ti_(3)C_(2)T_(x)(Se-MnS/Ti_(3)C_(2)T_(x))composite material derived from Mn-based metal-organic framework is reported.Electrochemical tests show that Se-doped could generate S defects and enhance the electrochemical activity of MnS.At the same time,the introduction of Ti_(3)C_(2)T_(x) substrate is conducive to exposing more sulfur defects and improving the utilization rate of defects.In the mechanism study,it is found that Se-MnS/Ti_(3)C_(2)T_(x) is transformed into S/Se co-doped Mn3O_(4) at the first charge,which innovatively elucidated the behavior of S/Se during activation.In the electrochemical performance test,the specific capacity can reach 74.7 mAh·g^(-1) at 5.0 A·g^(-1).In addition,the Zn-Ti_(3)C_(2)T_(x) membrane electrode is prepared by vacuum filtration as the zinc-poor anode,which is assembled into the rocking chair full battery to avoid dendrite growth and exhibit excellent rate performance.The addition of Zn2+weakens the electrostatic repulsion between the interlayers of MXene,and the formation of the folded morphology aids the penetration of the electrolyte.At 1.0 A·g^(-1),the capacity can reach 50.6 mAh·g^(-1).This work is helpful to promote the research and development of the reaction mechanism of manganese based rocking chair batteries.
基金Project supported by the National Natural Science Foundation of China(11675260)。
文摘Dy^3+-doped glass-ceramics containing NaCaPO4 crystals were successfully fabricated by heat treatment at base glass,and the luminescence properties were investigated for potential applications in radiation measurements.The photo luminescence(PL)excitation and emission spectra exhibit transitions related to Dy^3+ions corresponding to the strongest excitation and emission wavelengths at 351 and 575 nm,respectively.The CW-OSL properties as a function of dopant concentration,pre-heating temperature,pre-heating time and signal fading were investigated.The most appropriate Dy^3+ion concentration was found to be 0.25 mol%.The TL glow curves have a broad peak feature peaking at 195±5℃.The fading of the OSL signal would keep stable in five days with the intensity value of about 76.11%.The samples also exhibit good signal reusability and a broad linear dose response range(0.02-1000 Gy).
基金supported by the National Natural Science Foundation of China(Grant No.61201314)
文摘A novel random walk coefficient(RWC) model of the interferometric fiber optic gyroscope(IFOG) to decompose fundamental noise sources, namely the shot noise, the excess noise, the thermal noise, and the detection circuit noise, from the overall noise was developed. The coefficients of the model were extracted from the measured RWC instead of by calculating the accurate IFOG parameters, which is simpler and more accurate. The correctness and the accuracy of the model were verified by experiments. Using this model, the RWC of the experimental IFOG was predicted and the quantitative contributions of the noise sources were determined. According to the predicted results, the parameters of the IFOG were optimized. Finally, based on the model, a noise decomposition and parameter optimization method was proposed for high sensitivity IFOG design.
基金supported by the Natural Science Foundation of China(51962032)the program for Strong Youth Technology Leading Talents in Bingtuan Technological Innovation Talents(2023CB008-11)+1 种基金the Youth Innovative Top Talents Fund,Shihezi University(CXBJ202203)the Youth Innovation Promotion Association CAS(2021433)。
文摘Designing hybrid materials with numerous catalytic active sites,high specific surface area,and interfacial interactions is an effective strategy to improve electrocatalytic performance.In this work,iron-based metal organic frameworks(Fe-MOFs)@(Co,Ni)Fe-layered double hydroxide(LDH)is successfully constructed using the similar"MOF growing on LDH"strategy for oxygen evolution reaction and hydrogen evolution reaction in the alkaline electrolyte.The synthesized hybrid materials in this particular way show excellent electrochemical overall water-splitting performance with the cell voltage of 1.62 V at10 mA·cm^(-2) in the alkaline environment due to the optimized adsorption/desorption properties of metal ions on oxygencontaining species and interfacial effects of hybrid materials.Fe-MOFs@(Co,Ni)Fe-LDH also exhibits excellent hydrogen and oxygen production efficiency of 370 and 175μL·min^(-1),respectively.This work draws on an effective approach to the fabrication of MOF@LDH structures and provides new insights into overall water-splitting in alkaline conditions.