Eastern Qinling,China is one of the important rare metal metallogenic provinces with extensively distributed granite pegmatite dikes.The No.5 granite pegmatite intruded into the granitic gneiss of the Qinling Group,an...Eastern Qinling,China is one of the important rare metal metallogenic provinces with extensively distributed granite pegmatite dikes.The No.5 granite pegmatite intruded into the granitic gneiss of the Qinling Group,and the major minerals are quartz(39.8%),K-feldspar(18.8%),albite(36.3%),muscovite(3.4%),and garnet(1.1%).Monazite U–Pb isotopic dating indicates that the No.5 pegmatite from the Eastern Qinling was emplaced at ca.420.2±2.2 Ma,which confirms that highpurity quartz mineralization probably formed during the Early Devonian.In-situ laser ablation inductively coupled plasma mass spectrometry analysis of quartz show that quartz samples from Eastern Qinling have total trace element concentrations(Al,Ti,Sc,Li,B,Cr,Mn,and Fe)ranging from 23.2 to 52.8 ppm,slightly higher than the quartz(impurity element content from 13.4 to 25.9 ppm)of the Spruce Pine high-purity quartz deposit in western North Carolina.The No.5 pegmatite of Eastern Qinling could be defined as one high-purity quartz deposit of China.展开更多
Functionalized ionic liquids(FILs)as extractants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time.The effects of initial pH,extractant concentration,metal concentr...Functionalized ionic liquids(FILs)as extractants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time.The effects of initial pH,extractant concentration,metal concentrations in the feed were comprehensively investigated.The results showed that tricaprylmethylammonium bis(2,4,4-trimethylpentyl)phosphinate([A336][Cyanex272])could selectively extract W over Mo at an initial pH value of 5.5;the best separation factorβ_(W/Mo) of 25.61 was obtained for a solution with low metal concentrations(WO3:2.49 g/L,Mo:1.04 g/L).The[A336][Cyanex272]system performed effectively for solutions of different W/Mo molar ratios and different metal ion concentrations in the feed.The chemical reaction between[A336][Cyanex272]and W followed the ion association mechanism,which was further proved by the Fourier-transform infrared(FTIR)spectra of loaded[A336][Cyanex272]and the free extractant.The stripping experiments indicated that 95.48%W and 100.00%Mo were stripped using a 0.20 mol/L sodium hydroxide solution.Finally,the selective extractions of W and Mo from two synthetic solutions of different high metal concentrations were obtained;the separation factorβW/Mo reached 23.24 and 17.59 for the first and second solutions,respectively.The results suggest the feasibility of[A336][Cyanex272]as an extractant for the separation of tungsten and molybdenum.展开更多
The extraction kinetics of La(III) from aqueous chloride solutions into n-heptane solutions of bifunctional ionic liquid extractant [A336][CA-12](tricaprylmethylammonium sec-octylphenoxy acetic acid) was investigated ...The extraction kinetics of La(III) from aqueous chloride solutions into n-heptane solutions of bifunctional ionic liquid extractant [A336][CA-12](tricaprylmethylammonium sec-octylphenoxy acetic acid) was investigated using a constant interfacial cell with laminar flow. The effects of stirring speed, temperature and specific interfacial area on the extraction rate were examined. The results indicate that mass transfer kinetics of La(III) is a mixed-controlled process influenced by interfacial reaction. On the basis of mass transfer kinetic results in the extraction of La(III) by [A336][CA-12], the extraction rate equation of La(III) is proposed in terms of pseudo-firstorder constants, which is supported by the measured thermodynamic equations. The mass-transfer kinetic model deduced from the rate controlling step is adequate to interpret the experimental data qualitatively.展开更多
The flotation of diaspore and kaolinite by one of a series of tertiary amines（DRN,DEN,DPN and DBN） was investigated.The tertiary amines show better floating recovery for kaolinite compared to diaspore.The maximum re...The flotation of diaspore and kaolinite by one of a series of tertiary amines（DRN,DEN,DPN and DBN） was investigated.The tertiary amines show better floating recovery for kaolinite compared to diaspore.The maximum recovery D-value is 45%over a pH range from 3 to 8.FT-IR spectra confirm the presence of hydroxyl groups on the surface of kaolinite and diaspore.Zeta potential measurements show that the mineral surfaces are negatively charged over a wide pH range.Ionization of hydroxyl groups mainly accounts for the surface charging mechanism.The adsorption of tertiary amines onto the mineral surface is due mainly to electrostatic effects and the difference in electrostatic effect between a collector and the two minerals can explain the flotation separation.Inductive electronic and steric effects from the substituent groups result in different collecting powers for the four tertiary amines.展开更多
To improve the oxidation and graphitization resistances of the polycrystalline diamond(PCD), Ti coating was deposited on the diamond powders via magnetic sputtering method, which achieved a uniform Ti C protection bar...To improve the oxidation and graphitization resistances of the polycrystalline diamond(PCD), Ti coating was deposited on the diamond powders via magnetic sputtering method, which achieved a uniform Ti C protection barrier in PCD during the sintering process. The phase compositions, microstructures and thermal stability of Ti-PCD were characterized by X-ray diffraction(XRD), Auger electron spectroscopy(AES),scanning electron microscopy(SEM) and thermal gravimetric-differential scanning calorimetry(TG-DSC).The results demonstrate that the oxidation and graphitization resistances of PCD are strengthened due to the existence of Ti C phase, which acts as an effective inhibitor. The as-received inhibitor delays the oxidation and graphitization of PCD, elevating their initial temperature by ~50°C and ~100°C, respectively. During the annealing treatment of Ti-PCD, the priory oxidation of Ti C, which produces Ti O2 as an oxygen barrier, postpones the diamond oxide. Moreover, the Ti C barrier also protects diamond grains from direct contact with cobalt, thus a lower cobalt-catalytic graphitization, and yields to an improved graphitization resistance of PCD. The enhanced oxidation and graphitization resistances of PCD are of significant importance for practical applications to elevated temperatures.展开更多
The giant Dahutang tungsten(W)deposit has a total reserve of more than 1.31 Mt WO3.Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit,which are related to Late Mesozoi...The giant Dahutang tungsten(W)deposit has a total reserve of more than 1.31 Mt WO3.Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit,which are related to Late Mesozoic biotite granite.Four major types of alterations,which include albitization,potassic-alteration,and greisenization,and overprinted silicification developed in contact zone.The mass balance calculate of the four alteration types were used to further understanding of the mineralization process.The fresh porphyritic biotite granite has high Nb,Ta,and W,but low Ca and Sr while the Jiuling granodiorite has high Ca and Sr,but low Nb,Ta,and W concentrations.The altered porphyritic biotite granite indicated that the Nb,Ta,and W were leached out from the fresh porphyritic biotite granite,especially by sodic alteration.The low Ca and Sr contents of the altered Neoproterozoic Jiuling granodiorite indicate that Ca and Sr had been leached out from the fresh granodiorite by the fluid from Mesozoic porphyritic biotite granites.The metal W of the Dahutang deposit was mainly derived from the fluid exsolution from the melt and alteration of W-bearing granites.This study of alteration presents a new hydrothermal circulation model to understand tungsten mineralization in the Dahutang deposit.展开更多
1.Objective Rhenium is a dissipated metal with the second highest melting point of 3180℃in periodic table.In the aerospace field,rhenium plays an indispensable role in the nickel superalloys for the production of air...1.Objective Rhenium is a dissipated metal with the second highest melting point of 3180℃in periodic table.In the aerospace field,rhenium plays an indispensable role in the nickel superalloys for the production of aircraft engine and turbine engine.Since very few amount of rhenium resource is existed as independent ore deposit,most rhenium resource is distributed within the porphyry copper and molybdenite ores,consequently rhenium is often recovered as a by-product from the waste acid in copper smelting process.In this paper,an innovative technique with low cost,high recovery rate and non-pollution for recycling dissipated metal rhenium from the waste acid in copper smelting process is introduced(Zhang B et al.,2017;Liu HZ et al.,2018).展开更多
Sphericity is an important indicator of particle flow properties in rotary granulation. Here, a dynamic simulation approach is proposed to study the formation of particle sphericity during agglomeration by investigati...Sphericity is an important indicator of particle flow properties in rotary granulation. Here, a dynamic simulation approach is proposed to study the formation of particle sphericity during agglomeration by investigating both the orbit and attitude of non-spherical particles in a rotary drum. First, geometric crite- ria are presented to substitute a dual-sphere particle model for the commonly encountered ellipsoidal particle model assuming the long radius of the dual-sphere particle is equal to that of the ellipsoidal particle. Next, a discrete element method is applied to calculate the positions and orientations of dual- sphere particles during granulation. The relationship between shape and attitude in the dual-sphere model is then analyzed by comparing the obtained orientation angle-oblateness curves. A conclusion can be drawn that the particle orientation angle decreases with increasing particle oblateness within a certain range.展开更多
A new process is proposed for refining niobite ore that is found in Jiangxi province of China. Niobite, also known as columbite or niobite-tantalite, is a mineral that contains tantalum and niobium. The separation pro...A new process is proposed for refining niobite ore that is found in Jiangxi province of China. Niobite, also known as columbite or niobite-tantalite, is a mineral that contains tantalum and niobium. The separation process includes two-stage grinding, gravity concentration, magnetic separation, and flotation. The tan- talum/niobium concentrate obtained had a grade of Ta2O5 18.28%, Nb2O5 41.62% at a recovery rate of Ta2O5 49.08%, Nb205 70.77%. Other minerals occurring along with the niobite, such as zinnwaldite, feld- spar, and quartz, were also recovered to comprehensively utilize this ore.展开更多
The Bancheng Formation exposed along the Shift Reservoir nearby Bancheng Town, Qinfang Basin, southern Guangxi, is mainly composed of thin-bedded chert. The radiolarian assemblages in the studied section suggest it wa...The Bancheng Formation exposed along the Shift Reservoir nearby Bancheng Town, Qinfang Basin, southern Guangxi, is mainly composed of thin-bedded chert. The radiolarian assemblages in the studied section suggest it was a pelagic setting and the age of the Bancheng Formation is Late Carboniferous to Early Permian. The detrital zircon U-Pb ages from the section are characterized by a Permian peak at -282 Ma. Detrital zircon provenance analysis suggests that the Permian detrital zircons in the Bancheng Formation were likely from volcanic-magmatic arc rocks related to the subducfton of the Paleo-Tethyan Ocean. The long-lived deposition （from Upper Devonian to Middle Permian, about 125 Ma） of the radiolarian cherts in the Qinfang Basin was comparable with that deposited in Ailaoshan Ocean. The radiolarian assemblages in Qinfang Basin show a Tethyan affinity. Together with the Permian subduction-related arc volcanic rocks and the E-MORB type basalts to the northwest of the study area, our data support the existence of a Permian arc-related basin in the Qinfang area.展开更多
基金the National Natural Science Foundation of China(42062006 and 41962007)the National Key Research and Development Program of China(2016YFC0600207)+1 种基金the Project of China Geological Survey(DD20190186 and 12120114034501)the science and technology research project of Jiangxi Provincial Department of Education(GJJ190379)。
文摘Eastern Qinling,China is one of the important rare metal metallogenic provinces with extensively distributed granite pegmatite dikes.The No.5 granite pegmatite intruded into the granitic gneiss of the Qinling Group,and the major minerals are quartz(39.8%),K-feldspar(18.8%),albite(36.3%),muscovite(3.4%),and garnet(1.1%).Monazite U–Pb isotopic dating indicates that the No.5 pegmatite from the Eastern Qinling was emplaced at ca.420.2±2.2 Ma,which confirms that highpurity quartz mineralization probably formed during the Early Devonian.In-situ laser ablation inductively coupled plasma mass spectrometry analysis of quartz show that quartz samples from Eastern Qinling have total trace element concentrations(Al,Ti,Sc,Li,B,Cr,Mn,and Fe)ranging from 23.2 to 52.8 ppm,slightly higher than the quartz(impurity element content from 13.4 to 25.9 ppm)of the Spruce Pine high-purity quartz deposit in western North Carolina.The No.5 pegmatite of Eastern Qinling could be defined as one high-purity quartz deposit of China.
基金financially supported by the National Natural Science Foundation of China(No.51504225).
文摘Functionalized ionic liquids(FILs)as extractants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time.The effects of initial pH,extractant concentration,metal concentrations in the feed were comprehensively investigated.The results showed that tricaprylmethylammonium bis(2,4,4-trimethylpentyl)phosphinate([A336][Cyanex272])could selectively extract W over Mo at an initial pH value of 5.5;the best separation factorβ_(W/Mo) of 25.61 was obtained for a solution with low metal concentrations(WO3:2.49 g/L,Mo:1.04 g/L).The[A336][Cyanex272]system performed effectively for solutions of different W/Mo molar ratios and different metal ion concentrations in the feed.The chemical reaction between[A336][Cyanex272]and W followed the ion association mechanism,which was further proved by the Fourier-transform infrared(FTIR)spectra of loaded[A336][Cyanex272]and the free extractant.The stripping experiments indicated that 95.48%W and 100.00%Mo were stripped using a 0.20 mol/L sodium hydroxide solution.Finally,the selective extractions of W and Mo from two synthetic solutions of different high metal concentrations were obtained;the separation factorβW/Mo reached 23.24 and 17.59 for the first and second solutions,respectively.The results suggest the feasibility of[A336][Cyanex272]as an extractant for the separation of tungsten and molybdenum.
基金Supported by the National Natural Science Foundation of China(51174184)National Basic Research Program of China(2012CBA01202)+3 种基金the Key Research Programof the Chinese Academy of Sciences(KGZD-EW-201-1)the Science and Technology Planof Nantong City(BK2013030)the University Science Research Project of Jiangsu Province(14KJB150019)Open Subject of Changchun Institute of Applied Chemistry,Chinese Academy of Sciences(RERU2014016)
文摘The extraction kinetics of La(III) from aqueous chloride solutions into n-heptane solutions of bifunctional ionic liquid extractant [A336][CA-12](tricaprylmethylammonium sec-octylphenoxy acetic acid) was investigated using a constant interfacial cell with laminar flow. The effects of stirring speed, temperature and specific interfacial area on the extraction rate were examined. The results indicate that mass transfer kinetics of La(III) is a mixed-controlled process influenced by interfacial reaction. On the basis of mass transfer kinetic results in the extraction of La(III) by [A336][CA-12], the extraction rate equation of La(III) is proposed in terms of pseudo-firstorder constants, which is supported by the measured thermodynamic equations. The mass-transfer kinetic model deduced from the rate controlling step is adequate to interpret the experimental data qualitatively.
基金supported by the National Key Fundamental Research and Development Program(No.2005CB623701)the National Department Public Benefit Research Foundation from Ministry of Land and Resources(No.201011031 )the Foundation for the Author of Zhengzhou Institute of Multipurpose Utilization of Mineral Resources CAGS(No.2935)
文摘The flotation of diaspore and kaolinite by one of a series of tertiary amines（DRN,DEN,DPN and DBN） was investigated.The tertiary amines show better floating recovery for kaolinite compared to diaspore.The maximum recovery D-value is 45%over a pH range from 3 to 8.FT-IR spectra confirm the presence of hydroxyl groups on the surface of kaolinite and diaspore.Zeta potential measurements show that the mineral surfaces are negatively charged over a wide pH range.Ionization of hydroxyl groups mainly accounts for the surface charging mechanism.The adsorption of tertiary amines onto the mineral surface is due mainly to electrostatic effects and the difference in electrostatic effect between a collector and the two minerals can explain the flotation separation.Inductive electronic and steric effects from the substituent groups result in different collecting powers for the four tertiary amines.
基金financially supported by the National Natural Science Foundation of China(Nos.51875537,41572359 and 51375466)the Beijing Natural Science Foundation(No.3172026)+2 种基金the Beijing Nova program(No.Z171100001117059)the Fundamental Research Funds for the Central University(No.2652018094)the Natural Science Foundation of Ningxia Province(No.2018AAC03200)。
文摘To improve the oxidation and graphitization resistances of the polycrystalline diamond(PCD), Ti coating was deposited on the diamond powders via magnetic sputtering method, which achieved a uniform Ti C protection barrier in PCD during the sintering process. The phase compositions, microstructures and thermal stability of Ti-PCD were characterized by X-ray diffraction(XRD), Auger electron spectroscopy(AES),scanning electron microscopy(SEM) and thermal gravimetric-differential scanning calorimetry(TG-DSC).The results demonstrate that the oxidation and graphitization resistances of PCD are strengthened due to the existence of Ti C phase, which acts as an effective inhibitor. The as-received inhibitor delays the oxidation and graphitization of PCD, elevating their initial temperature by ~50°C and ~100°C, respectively. During the annealing treatment of Ti-PCD, the priory oxidation of Ti C, which produces Ti O2 as an oxygen barrier, postpones the diamond oxide. Moreover, the Ti C barrier also protects diamond grains from direct contact with cobalt, thus a lower cobalt-catalytic graphitization, and yields to an improved graphitization resistance of PCD. The enhanced oxidation and graphitization resistances of PCD are of significant importance for practical applications to elevated temperatures.
基金This research is jointly funded by the Project of China Geological Survey(DD20190186 and 12120114034501)National Natural Science Foundation of China(42062006 and 41962007).
文摘The giant Dahutang tungsten(W)deposit has a total reserve of more than 1.31 Mt WO3.Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit,which are related to Late Mesozoic biotite granite.Four major types of alterations,which include albitization,potassic-alteration,and greisenization,and overprinted silicification developed in contact zone.The mass balance calculate of the four alteration types were used to further understanding of the mineralization process.The fresh porphyritic biotite granite has high Nb,Ta,and W,but low Ca and Sr while the Jiuling granodiorite has high Ca and Sr,but low Nb,Ta,and W concentrations.The altered porphyritic biotite granite indicated that the Nb,Ta,and W were leached out from the fresh porphyritic biotite granite,especially by sodic alteration.The low Ca and Sr contents of the altered Neoproterozoic Jiuling granodiorite indicate that Ca and Sr had been leached out from the fresh granodiorite by the fluid from Mesozoic porphyritic biotite granites.The metal W of the Dahutang deposit was mainly derived from the fluid exsolution from the melt and alteration of W-bearing granites.This study of alteration presents a new hydrothermal circulation model to understand tungsten mineralization in the Dahutang deposit.
基金This technology has been granted a national patent for invention(ZL 201710434010.X)which is shown as Fig.4.This study was funded by the Natural Science Foundation of China(51404220).
文摘1.Objective Rhenium is a dissipated metal with the second highest melting point of 3180℃in periodic table.In the aerospace field,rhenium plays an indispensable role in the nickel superalloys for the production of aircraft engine and turbine engine.Since very few amount of rhenium resource is existed as independent ore deposit,most rhenium resource is distributed within the porphyry copper and molybdenite ores,consequently rhenium is often recovered as a by-product from the waste acid in copper smelting process.In this paper,an innovative technique with low cost,high recovery rate and non-pollution for recycling dissipated metal rhenium from the waste acid in copper smelting process is introduced(Zhang B et al.,2017;Liu HZ et al.,2018).
文摘Sphericity is an important indicator of particle flow properties in rotary granulation. Here, a dynamic simulation approach is proposed to study the formation of particle sphericity during agglomeration by investigating both the orbit and attitude of non-spherical particles in a rotary drum. First, geometric crite- ria are presented to substitute a dual-sphere particle model for the commonly encountered ellipsoidal particle model assuming the long radius of the dual-sphere particle is equal to that of the ellipsoidal particle. Next, a discrete element method is applied to calculate the positions and orientations of dual- sphere particles during granulation. The relationship between shape and attitude in the dual-sphere model is then analyzed by comparing the obtained orientation angle-oblateness curves. A conclusion can be drawn that the particle orientation angle decreases with increasing particle oblateness within a certain range.
基金the Geological Survey Program fromthe Ministry of Land and Resources of China (No. 1212010816036)and the National Department Public Benefit Research Foundation from Ministry of Land and Resources of China (No. 201011031)Zhengzhou Institute of Multipurpose Utilization of Mineral Resources CAGS,for financial support and approval of this paper for publication
文摘A new process is proposed for refining niobite ore that is found in Jiangxi province of China. Niobite, also known as columbite or niobite-tantalite, is a mineral that contains tantalum and niobium. The separation process includes two-stage grinding, gravity concentration, magnetic separation, and flotation. The tan- talum/niobium concentrate obtained had a grade of Ta2O5 18.28%, Nb2O5 41.62% at a recovery rate of Ta2O5 49.08%, Nb205 70.77%. Other minerals occurring along with the niobite, such as zinnwaldite, feld- spar, and quartz, were also recovered to comprehensively utilize this ore.
基金supported by the National Natural Science Foundation of China(No.41772016)the China Geological Survey(Nos.1212011220529,121201004000150021,and 121201017000172004)the Key Research and Development Project of the Ministry of Science and Technology(No.2016YFC0601005)
文摘The Bancheng Formation exposed along the Shift Reservoir nearby Bancheng Town, Qinfang Basin, southern Guangxi, is mainly composed of thin-bedded chert. The radiolarian assemblages in the studied section suggest it was a pelagic setting and the age of the Bancheng Formation is Late Carboniferous to Early Permian. The detrital zircon U-Pb ages from the section are characterized by a Permian peak at -282 Ma. Detrital zircon provenance analysis suggests that the Permian detrital zircons in the Bancheng Formation were likely from volcanic-magmatic arc rocks related to the subducfton of the Paleo-Tethyan Ocean. The long-lived deposition （from Upper Devonian to Middle Permian, about 125 Ma） of the radiolarian cherts in the Qinfang Basin was comparable with that deposited in Ailaoshan Ocean. The radiolarian assemblages in Qinfang Basin show a Tethyan affinity. Together with the Permian subduction-related arc volcanic rocks and the E-MORB type basalts to the northwest of the study area, our data support the existence of a Permian arc-related basin in the Qinfang area.
